Comparing the Effects of Microwave and Conventional Heating Methods on the Evaporation Rate and Quality Attributes of Pomegranate (<Emphasis Type="Italic">Punica granatum</Emphasis> L.) Juice Concentrate

Pomegranate juice was concentrated by conventional heating and microwave heating at different operational pressures (12, 38.5, and 100 kPa), and their effects on evaporation rate and quality attributes of concentrated juice were investigated. The final juice concentration of 40° Brix was achieved in 140, 127, and 109 min at 100, 38.5, and 12 kPa, respectively, by using conventional heating. Applying microwave energy decreased required times to 118, 95, and 75 min. The changes in color, anthocyanin content, and antioxidant capacity during concentration processes were investigated. L*, a*, and b* parameters were measured to estimate the intensity of color loss. All Hunter color parameters decreased with time. Results showed that the degradation of color, anthocyanins, and antioxidant activity were more important in conventional heating compared to microwave heating method. Degradation rates increases by increasing process pressure. A first-order kinetics model was applied to modeling changes in total solid content, anthocyanin content, and antioxidant capacity.     

Corrosion inhibition of steel by hydrazine

The corrosion inhibition of steel in a closed system containing hydrazine at room temperature has been established. The steady-state potential measurements as well as weight loss measurements agree in indicating that hydrazine was found to behave in a similar manner to anodic inhibitors. A sharp ennoblement of potential occurs at concentration of 10^?2M accompanied by complete protection. The mechanism of inhibition by hydrazine is assumed to be due to its preferential adsorption on the local anodes inducing anodic polarization. After a certain critical concentration of hydrazine is reached complete blocking of the pores occurs which causes complete inhibition. For hydrazine-sulphate or hydrazine-chloride mixtures, a linear relationship is found between log hydrazine concentration and log maximum tolerated concentration of the aggressive ion. For hydrazine-sulphide mixtures, a concentration of 5 × 10^?2M hydrazine could tolerate a wide range of concentrations of sulphide ions.     

Calculation of maximum surface settlement induced by EPB shield tunnelling and introducing most effective parameter

This study aims to predict ground surface settlement due to shallow tunneling and introduce the most affecting parameters on this phenomenon.Based on data collected from Shanghai LRT Line 2 project undertaken by TBM-EPB method,this research has considered the tunnel's geometric,strength,and operational factors as the dependent variables.At first,multiple regression(MR) method was used to propose equations based on various parameters.The results indicated the dependency of surface settlement on many parameters so that the interactions among different parameters make it impossible to use MR method as it leads to equations of poor accuracy.As such,adaptive neuro-fuzzy inference system(ANFIS),was used to evaluate its capabilities in terms of predicting surface settlement.Among generated ANFIS models,the model with all input parameters considered produced the best prediction,so as its associated R~2 in the test phase was obtained to be 0.957.The equations and models in which operational factors were taken into consideration gave better prediction results indicating larger relative effect of such factors.For sensitivity analysis of ANFIS model,cosine amplitude method(CAM) was employed; among other dependent variables,fill factor of grouting(n) and grouting pressure(P) were identified as the most affecting parameters.     

Integrated standalone hybrid solar PV,fuel cell and diesel generator power system for battery or supercapacitor storage systems in Khorfakkan,United Arab Emirates

Renewable energy resources play a very important rule these days to assist the conventional energy systems for doing its function in the UAE due to high greenhouse gas (GHG) emissions and energy demand. In this paper, the analysis and performance of integrated standalone hybrid solar PV, fuel cell and diesel generator power system with battery energy storage system (BESS) or supercapacitor energy storage system (SCESS) in Khorfakkan city, Sharjah were presented. HOMER Pro software was used to model and simulate the hybrid energy system (HES) based on the daily energy consumption for Khorfakkan city. The simulation results show that using SCESS as an energy storage system will help the performance of HES based on the Levelized cost of energy (LCOE) and greenhouse gas (GHG) emissions. The HES with SCESS has renewable fraction (68.1%) and 0.346 $/kWh LCOE. The HES meets the annual AC primary load of the city (13.6 GWh) with negligible electricity excess and with an unmet electrical load of 1.38%. The reduction in GHG emissions for HES with SCESS was 83.2%, equivalent to saving 814,428 gallons of diesel.     

Synthesis and characterization of polyurethane – Treated waste milled light bulbs composites

In this study, polyurethane (PU)-milled light bulbs glass composites were synthesized and characterized. The main interest in this study that the polyurethane derived from renewable resources and waste glass are used to form the composite constituents as an attempt towards environmental preservation. Castor oil and polymeric diphenyl methane di-isocyanates (PMDI) were used in NCO/OH ratio = 2 for polyurethane synthesis. Milled glass with average particles size less than 300 μm were prepared based on waste light bulbs. Silane A1100 (as a compatibilizer) was used in order to improve the value of recycled milled glass beads. The adhesion force between polyurethane matrix and milled glass beads was evaluated using mechanical and physical tests. Scanning electron microscopy (SEM) was used to investigate dispersion and fracture surfaces of the composites. Infrared spectrum (IR), Differential scanning calorimetry (DSC) behavior, and Thermogravimetric analysis (TGA), were employed to characterize the developed composite materials in details. Chemical resistance (weight change, thickness swelling) was measured in oil, water and dilute acetic acid media. Furthermore, tensile strength and hardness were investigated using universal materials testing machines. A slight increase in the hardness values was reported along with the increasing in particulate fillers loading up to 10% as a considerable improvement has been detected when milled glass reached 20%. The DSC analysis showed the presence of treated milled glass beads influences the thermal behavior of pure PU and composites. This can be attributed to enhancing the physical bonding between PU and silica group. Waste milled glass showed a significant effect on the thermal degradation of the composites in the presence of coupling agent. Further analysis on the tensile strength of the composites indicated that such improved mechanical properties may be attributed to the presence of coupling agent.     

Tracking Performance of an Adaptive MIMO-OFDM LS Estimator via MSE Criterion Over a Wireless Time Correlated Fading Channel

In this contribution, the performance of an adaptive least squares channel estimator for a time correlated MIMO-OFDM channel is presented in a closed form relation. As a criterion for performance evaluation, the well-known mean square error (MSE) is employed. The pilot aided channel estimation is used to extract the channel coefficients. To minimize the MSE and arrange phase shift orthogonally, the pilots are constructed with equal power and space. The model of the channel is developed by implementing a first order Markov model, and it is proved that the performance of the system is dependent upon the defined forgetting factor, the number of transmit antennas, the number of multipath channel taps, transmitted power, and Doppler shift. The effect of each parameter on the performance of the system is discussed separately. The computer simulation results follow with the analytical results comprehensively.     

Removal of toxic aqueous ions using amorphous AlPO4

Aluminium phosphate (AlPO₄) was characterized using X-ray diffractometry (XRD), Fourier Transform infrared (FTIR), point of zero charge (PZC) and dissolution studies. XRD showed the sample to be amorphous, FTIR confirmed the presence of OH groups on the surface and PZC was determined at pH 3.45. The dissolution study illustrated a decrease in dissolution with an increase in the pH. Potentiometric titration data were fit to the Gaines–Thomas equation, which showed that AlPO₄ is a weakly acidic ion exchanger. Sorption studies were carried out at pH 4–6 and temperatures 293–323 K. The uptake of metal ions was observed to increase with an increase in the pH and temperature. The surface selectivity towards metal ions was found in the order Pb²⁺> Cu²⁺> Cd²⁺. Sorption data were fit to the new equation derived from the proposed mechanism for metal ion uptake. Various parameters such as stoichiometry of the surface H⁺ ion release, equilibrium constant, standard enthalpy, entropy and free energy changes were evaluated from the plots. The values of all these parameters were found to be closely related to the values reported in the literature.