Synthesis and characterization of polyurethane – Treated waste milled light bulbs composites

In this study, polyurethane (PU)-milled light bulbs glass composites were synthesized and characterized. The main interest in this study that the polyurethane derived from renewable resources and waste glass are used to form the composite constituents as an attempt towards environmental preservation. Castor oil and polymeric diphenyl methane di-isocyanates (PMDI) were used in NCO/OH ratio = 2 for polyurethane synthesis. Milled glass with average particles size less than 300 μm were prepared based on waste light bulbs. Silane A1100 (as a compatibilizer) was used in order to improve the value of recycled milled glass beads. The adhesion force between polyurethane matrix and milled glass beads was evaluated using mechanical and physical tests. Scanning electron microscopy (SEM) was used to investigate dispersion and fracture surfaces of the composites. Infrared spectrum (IR), Differential scanning calorimetry (DSC) behavior, and Thermogravimetric analysis (TGA), were employed to characterize the developed composite materials in details. Chemical resistance (weight change, thickness swelling) was measured in oil, water and dilute acetic acid media. Furthermore, tensile strength and hardness were investigated using universal materials testing machines. A slight increase in the hardness values was reported along with the increasing in particulate fillers loading up to 10% as a considerable improvement has been detected when milled glass reached 20%. The DSC analysis showed the presence of treated milled glass beads influences the thermal behavior of pure PU and composites. This can be attributed to enhancing the physical bonding between PU and silica group. Waste milled glass showed a significant effect on the thermal degradation of the composites in the presence of coupling agent. Further analysis on the tensile strength of the composites indicated that such improved mechanical properties may be attributed to the presence of coupling agent.     

Molecular simulation study of water transport through aquaporin-inspired pore geometry

Journal of Mechanical Science and Technology - Water permeation dynamics through hourglass-shaped nanopore is addressed by using Molecular dynamics (MD) simulations. The objective of this research...     

A hybrid chaotic blowfish encryption for high-resolution satellite imagery

Multimedia Tools and Applications - In this article, we have designed a new information confidentiality mechanism based on the combination of Blowfish encryption algorithm along with Henon and Chen...     

No-chatter model-free sliding mode control for synchronization of chaotic fractional-order systems with application in image encryption

Multimedia Tools and Applications - Synchronization of different Chaotic dynamical systems is one of the main issues in engineering which has a lot of applications in applied sciences like secure...     

Nitrogen-doped graphene-supported zinc sulfide nanorods as efficient Pt-free for visible-light photocatalytic hydrogen production

Nitrogen-doped graphene-ZnS composite (NG-ZnS) was synthesized by thermal treatment of graphene-ZnS composite (G-ZnS) in NH₃ medium. In the second step, the as-synthesized samples were deposited on indium tin oxide glass (ITO) by electrophoretic deposition for photocatalytic hydrogen evolution reaction. The as-prepared NG-ZnS-modified ITO electrode displayed excellent photocatalytic activity, rapid transient photocurrent response, superior stability and high recyclability compared to the pure ZnS and G-ZnS-modified ITO electrode due to the synergy between the photocatalytic activity of ZnS nanorods and the large surface area and high conductivity of N-graphene.     

Pure Hydrogen and Propylene Coproduction in Catalytic Membrane Reactor-Assisted Propane Dehydrogenation

Propane dehydrogenation on a commercial Pt-Sn/Al₂O₃ catalyst in a Pd-Ag membrane reactor is considered. A mathematical model is developed to evaluate the performance of the catalytic membrane reactor for the process of propane dehydrogenation. Design and operating conditions are systematically evaluated for key performance metrics such as propane conversion, propylene selectivity, hydrogen selectivity, and hydrogen recovery under different operating conditions. The results confirm that the high performance of the membrane reactor is related to the continuous removal of hydrogen from the reaction zone to shift the reaction equilibrium towards the formation of more propylene and hydrogen.     

Clean low-temperature in situ synthesis of durable silver nanoparticles along with aminolysis of polyester fabric using dopamine hydrochloride

Clean Technologies and Environmental Policy - In this study, aminolysis of polyester fabric was carried out along with in situ synthesis of silver nanoparticles in a single-step processing at room...     

Vibrational investigation of the spinning bi-dimensional functionally graded (2-FGM) micro plate subjected to thermal load in thermal environment

Microsystem Technologies - This article presented a numerical method for discovering the free vibration of a spinning bi-dimensional functionally graded materials (FGM) micro circular plate exposed...