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51.
52.
Passerone Roberto Hafaiedh Imene Ben Graf Susanne Benveniste Albert Cancila Daniela Cuccuru Arnaud Gerard Sebastien Terrier Francois Damm Werner Ferrari Alberto Mangeruca Leonardo Josko Bernhard Peikenkamp Thomas Sangiovanni-Vincentelli Alberto 《Design & Test of Computers, IEEE》2009,26(3):38-53
Editor's note:This article provides an overview of current efforts in Europe for using metamodeling in the integrated development of critical systems such as automotive electronics. It distinguishes between lightweight versus heavyweight approaches, surveys a number of related current European projects, and gives details about the Speeds project to illustrate the role of metamodeling-driven system engineering.—Sandeep Shukla, Virginia Tech 相似文献
53.
Peter Sjvall Sebastien Gregoire William Wargniez Lisa Skedung Gustavo S. Luengo 《International journal of molecular sciences》2022,23(22)
The crucial barrier properties of the stratum corneum (SC) depend critically on the design and integrity of its layered molecular structure. However, analysis methods capable of spatially resolved molecular characterization of the SC are scarce and fraught with severe limitations, e.g., regarding molecular specificity or spatial resolution. Here, we used 3D time-of-flight secondary ion mass spectrometry to characterize the spatial distribution of skin lipids in corneocyte multilayer squams obtained by tape stripping. Depth profiles of specific skin lipids display an oscillatory behavior that is consistent with successive monitoring of individual lipid and corneocyte layers of the SC structure. Whereas the most common skin lipids, i.e., ceramides, C24:0 and C26:0 fatty acids and cholesteryl sulfate, are similarly organized, a distinct 3D distribution was observed for cholesteryl oleate, suggesting a different localization of cholesteryl esters compared to the lipid matrix separating the corneocyte layers. The possibility to monitor the composition and spatial distribution of endogenous lipids as well as active drug and cosmetic substances in individual lipid and corneocyte layers has the potential to provide important contributions to the basic understanding of barrier function and penetration in the SC. 相似文献
54.
Kaune G Metwalli E Meier R Körstgens V Schlage K Couet S Röhlsberger R Roth SV Müller-Buschbaum P 《ACS applied materials & interfaces》2011,3(4):1055-1062
Growth and morphology of an aluminum (Al) contact on a poly(3-hexylthiophene) (P3HT) thin film are investigated with X-ray methods and related to the interactions at the Al:P3HT interface. Grazing incidence small-angle scattering (GISAXS) is applied in situ during Al sputter deposition to monitor the growth of the layer. A growth mode is found, in which the polymer surface is wetted and rapidly covered with a continuous layer. This growth type results in a homogeneous film without voids and is explained by the strong chemical interaction between Al and P3HT, which suppresses the formation of three-dimensional cluster structures. A corresponding three stage growth model (surface bonding, agglomeration, and layer growth) is derived. X-ray reflectivity shows the penetration of Al atoms into the P3HT film during deposition and the presence of a 2 nm thick intermixing layer at the Al:P3HT interface. 相似文献
55.
We present the psychological theory of action identification as a framework for a more in-depth understanding of a human operator's cognitive activity in the scope of cognitive engineering. A comparison of theoretical models and findings shows that both frameworks are founded on a similar theory of cognitive control based on an ontological viewpoint of means–ends relationships with the proposal that an individual mentally ‘navigates’ or ‘moves’ through a hierarchical arrangement of these relationships. However, whilst cognitive engineering begins the analysis from a viewpoint on affordances coming from the external work domain, the action identification theory starts from a viewpoint on action identities internally attributed to actions by individuals. We show that the conceptual articulation of these two approaches leads to confirming qualitative findings on an agent's cognitive activity and to proposing general cognitive principles that would explain a single agent's mental navigation through the abstraction hierarchy. 相似文献
56.
The creative class thesis of economic development has been influential in analyzing the mobility of human capital. The thesis has also had a major influence on the orientation of policies in North American cities regarding urban development aspects. Our aim is not to test this thesis of economic development as a whole but rather to use its quality of place criteria to evaluate how students enrolled in science and technology university programs decide where to live upon graduation. Using quantitative and qualitative material, this paper examines the influence of criteria related to quality of place and also to career opportunities concerning the mobility of students in science and technology who will soon be part of the professional category of the knowledge workers. Our hypothesis is that knowledge workers would be much more attracted by urban environments having more potential in terms of creativity, corresponding to the criterion emphasised in the creative class thesis. However, our results suggest that the quality of place is not as important as career opportunities. This does not lead us to refute the relevance of the creative class thesis but to nuance the relevance of various factors of location. It appears that the two cities in our study achieve different results on only one major point: the quality of life of Ottawa is a more powerful criterion of attraction/retention than in Montreal. 相似文献
57.
Ion Iliuta Raul Tahoces Gregory S. Patience Sebastien Rifflart Francis Luck 《American Institute of Chemical Engineers》2010,56(4):1063-1079
Chemical Looping Combustion technology involves circulating a metal oxide between a fuel zone where methane reacts under anaerobic conditions to produce a concentrated stream of CO2 and water and an oxygen rich environment where the metal is reoxidized. Although the needs for electrical power generation drive the process to high temperatures, lower temperatures (600–800°C) are sufficient for industrial processes such as refineries. In this paper, we investigate the transient kinetics of NiO carriers in the temperature range of 600 to 900°C in both a fixed bed microreactor (WHSV = 2‐4 g CH4/h/g oxygen carrier) and a fluid bed reactor (WHSV = 0.014‐0.14 g CH4/h per g oxygen carrier). Complete methane conversion is achieved in the fluid bed for several minutes. In the microreactor, the methane conversion reaches a maximum after an initial induction period of less than 10 s. Both CO2 and H2O yields are highest during this induction period. As the oxygen is consumed, methane conversion drops and both CO and H2 yields increase, whereas the CO2 and H2O concentrations decrease. The kinetics parameter of the gas–solids reactions (reduction of NiO with CH4, H2, and CO) together with catalytic reactions (methane reforming, methanation, shift, and gasification) were estimated using experimental data obtained on the fixed bed microreactor. Then, the kinetic expressions were combined with a detailed hydrodynamic model to successfully simulate the comportment of the fluidized bed reactor. © 2010 American Institute of Chemical Engineers AIChE J, 2010 相似文献
58.
Christina Rosman Sebastien Pierrat Andreas Henkel Marco Tarantola David Schneider Eva Sunnick Andreas Janshoff Carsten Sönnichsen 《Small (Weinheim an der Bergstrasse, Germany)》2012,8(23):3683-3690
Toxicological effects of nanoparticles are associated with their internalization into cells. Hence, there is a strong need for techniques revealing the interaction between particles and cells as well as quantifying the uptake at the same time. For that reason, herein optical dark‐field microscopy is used in conjunction with transmission electron microscopy to investigate the uptake of gold nanoparticles into epithelial cells with respect to shape, stabilizing agent, and surface charge. The number of internalized particles is strongly dependent on the stabilizing agent, but not on the particle shape. A test of metabolic activity shows no direct correlation with the number of internalized particles. Therefore, particle properties besides coating and shape are suspected to contribute to the observed toxicity. 相似文献
59.
Mandin Philippe Hamburger Jérôme Bessou Sebastien Picard Gérard 《Electrochimica acta》2005,51(6):1140-1156
During industrial electrolysis, for hydrogen, dichloride or aluminium production, there is bubbles creation at one or two electrodes which imply a great hydrodynamic acceleration but also a quite important electrical field disturbance. This disturbance can lead to the modification of the local current density and to anode effects for example. There is few works concerning the local modelling of coupled electro active species transport and electrochemical processes in a biphasic electrolyte. There are also few local experimental measurements in term of chemical composition, temperature or current density which would allow the numerical calculations validation. Nevertheless, effects like the anode effect, particularly expensive on the point of the process efficiency, should need a better understanding. Nowadays, the respective roles of the local temperature increases, the electro active specie composition or the transport properties modification due to bubbles are not known.The goal of the present work is the modelling and the numerical simulation of the vertical electrode configuration for a biphasic electrolysis process. Bubbles presence is supposed to modify the electrical properties, and then the electro active species diffusive transport and the current density. Bubbles are also motion sources for the electrolysis cell flow, and then hydrodynamic properties are strongly coupled with species transport and electrical field. The present work shows hydrodynamic and electrical properties in a laboratory scale electrolysis cell with a vertical electrode. The numerical algorithm used was the finite volume used in the computational fluid dynamic software Fluent®. 相似文献
60.
Mahdi Zamani Giulio Imbalzano Nicolas Tappy Duncan T. L. Alexander Sara Martí-Sánchez Lea Ghisalberti Quentin M. Ramasse Martin Friedl Gözde Tütüncüoglu Luca Francaviglia Sebastien Bienvenue Cécile Hébert Jordi Arbiol Michele Ceriotti Anna Fontcuberta i Morral 《Advanced materials (Deerfield Beach, Fla.)》2020,32(38):2001030
The nature of the liquid–solid interface determines the characteristics of a variety of physical phenomena, including catalysis, electrochemistry, lubrication, and crystal growth. Most of the established models for crystal growth are based on macroscopic thermodynamics, neglecting the atomistic nature of the liquid–solid interface. Here, experimental observations and molecular dynamics simulations are employed to identify the 3D nature of an atomic-scale ordering of liquid Ga in contact with solid GaAs in a nanowire growth configuration. An interplay between the liquid ordering and the formation of a new bilayer is revealed, which, contrary to the established theories, suggests that the preference for a certain polarity and polytypism is influenced by the atomic structure of the interface. The conclusions of this work open new avenues for the understanding of crystal growth, as well as other processes and systems involving a liquid–solid interface. 相似文献