Superparamagnetic latex synthesized by a new route of emulsifier‐free emulsion polymerization

The aim of this study was to design polymeric nanospheres containing magnetic nanoparticle which could display superparamagnetic behavior and thus find application in allied fields. First magnetite nanoparticles were synthesized with coprecipitation method and then their stable acidic dispersion was prepared without surfactant and dropped into the polymerization system during a certain time interval after the polymerization started. The effects of time at which the magnetic sol was added into polymerization system on latex size and stability, average molecular weight of polymer were examined in the case of two different monomer concentrations. Extensive characterization by transmission electron microscopy, dynamic light scattering, thermal gravimetric analysis and magnetic measurements shows that when the magnetic sol was dropped during earlier time of polymerization at stage 1, the latex size, average molecular weight of polymer, thermal stability of polymeric composite, and saturation magnetization reduced, whereas polydispersity of size and molecular weight increased because of the reaction between persulfate and naked surface of magnetite at the aqueous phase. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Quick-boiling noodle production by using infrared drying

In this study, infrared treatment at different powers was used at drying stage of noodle production. Drying time was reduced to 3 min 30 s and 50% reduction in cooking time was obtained at the highest power. Lower cooking loss and total organic matter values, higher maximum force values were obtained for noodles dried by using infrared, indicating improved quality. Infrared treatment generally caused an increase in Rapid ViscoAnalyzer viscosity values of the noodles. Starch granules of the noodles dried by using infrared retained their birefringence to a large extent and increase in intensity of some peaks and formation of a new peak at 2θ = 20° (V-type diffraction pattern) were observed in X-ray diffraction patterns. Relative intensities of some protein bands in SDS-PAGE patterns decreased, total dietary fiber and enzyme resistant starch contents increased slightly. Starch digestibility (in vitro) values increased gradually as the infrared power applied increased.     

Investigation of temperature,thermodynamic parameters and dielectrical properties of poly(vinylimidazole)–Na–bentonite nanocomposite

The adsorption of poly(vinylimidazole) (PVI) onto Na–Bentonite from aqueous solutions has been investigated as a function of temperature. According to the experimental results, the adsorption of PVI decreases with temperature from 25 to 55°C. The study of temperature effect has been quantified by calculating various thermodynamic parameters such as Gibbs free energy, enthalpy and entropy changes. The electrical and dielectrical properties of PVI–Na–Bentonite composite have been investigated. The current‐voltage studies show that conductivity was increased at T = 25°C. The dc conductivity was calculated at T = 25°C. The samples show typical dielectric behavior from capacitive measurements. Depending on maximum interactions at 25°C, ac conductivity and loss factors are also in high values. Especially, at frequencies over 1.5 kHz, it was seen completely clay behavior. Variation of tangent loss factor‐frequency shows decreasing of polarization density in structure in high frequency. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Effects of ammonium polyphosphate and triphenyl phosphate on the flame retardancy,thermal, and mechanical properties of glass fiber–reinforced PLA/PC composites

The purpose of this study is to increase of the flammability properties of the glass fiber (GF)–reinforced poly (lactic acid)/polycarbonate (PLA/PC) composites. Ammonium polyphosphate (APP) and triphenyl phosphate (TPP) were used as flame retardants that are including the organic phosphor to increase flame retardancy of GF‐reinforced composites. APP, TPP, and APP‐TPP mixture flame retardant including composites were prepared by using extrusion and injection molding methods. The properties of the composites were determined by the tensile test, limiting oxygen index (LOI), differential scanning calorimetry (DSC), and heat release rate (HRR) test. The minimum T_g value was observed for the TPP including PLA/PC composites in DSC analysis. The highest tensile strength was observed in GF‐reinforced PLA/PC composites. In the LOI test, GF including composite was burned with the lowest concentration of oxygen, and burning time was the longest of this composite. However, the shortest burning time was obtained by using the mixture flame retardant system. The flame retardancy properties of GF‐reinforced PLA/PC composite was improved by using mixture flame retardant. When analyzed the results of HRR, time to ignition (TTI), and mass loss rate together, the best value was obtained for the composite including APP.     

Species distribution,molecular characteristics and vancomycin resistance gene profiles of Enterococcus sp. isolates from farmhouse cheeses in western Turkey

Species distribution, virulence traits and vancomycin resistance gene profiles of Enterococcus isolated from 43 home‐made artisan cheese samples collected from open markets, located in Aydin region of Turkey, were investigated. Of the 129 isolates, 95 were identified as Enterococcus sp.; Enterococcus faecium being the most prevalent species (82.1%), followed by Enterococcus faecalis (13.6%) and Enterococcus durans (1.0%). None of the enterococci were harbouring vanA or vanC, while seven isolates (7.3%) were shown to harbour vanB gene by multiplex PCR. gelE (49.4%) being the most prevalent virulence factor was followed by asa1 (27.3%), esp (22.1%), cylA (4.2%) and hyl (3.1%).     

Cell-laden microengineered pullulan methacrylate hydrogels promote cell proliferation and 3D cluster formation

The ability to encapsulate cells in three-dimensional (3D) environments is potentially of benefit for tissue engineering and regenerative medicine. In this paper, we introduce pullulan methacrylate (PulMA) as a promising hydrogel platform for creating cell-laden microscale tissues. The hydration and mechanical properties of PulMA were demonstrated to be tunable through modulation of the degree of methacrylation and gel concentration. Cells encapsulated in PulMA exhibited excellent viability. Interestingly, while cells did not elongate in PulMA hydrogels, cells proliferated and organized into clusters, the size of which could be controlled by the hydrogel composition. By mixing with gelatin methacrylate (GelMA), the biological properties of PulMA could be enhanced as demonstrated by cells readily attaching to, proliferating, and elongating within the PulMA/GelMA composite hydrogels. These data suggest that PulMA hydrogels could be useful for creating complex, cell-responsive microtissues, especially for applications that require controlled cell clustering and proliferation.     

Synthesis and characterization of poly(p‐phenylene)‐graft‐poly(ε‐caprolactone) copolymers by combined ring‐opening polymerization and cross‐coupling processes

2,5‐Dibromo‐1,4‐(dihydroxymethyl)benzene was used as initiator in ring‐opening polymerization of ε‐caprolactone in the presence of stannous octoate (Sn(Oct)₂) catalyst. The resulting poly(ε‐caprolactone) (PCL) macromonomer, with a central 2,5‐dibromo‐1,4‐diphenylene group, was used in combination with 1,4‐dibromo‐2,5‐dimethylbenzene for a Suzuki coupling in the presence of Pd(PPh₃)₄ as catalyst or using the system NiCl₂/bpy/PPh₃/Zn for a Yamamoto‐type polymerization. The poly(p‐phenylenes) (PPP) obtained, with PCL side chains, have solubility properties similar to those of the starting macromonomer, ie soluble in common organic solvents at room temperature. The new polymers were characterized by ¹H and ¹³C NMR and UV spectroscopy and also by GPC measurements. The thermal behaviour of the precursor PCL macromonomer and the final poly(p‐phenylene)‐graft‐poly(ε‐caprolactone) copolymers were investigated by thermogravimetric analysis and differential scanning calorimetry analyses and compared. Copyright © 2004 Society of Chemical Industry     

Effect of fabrication parameters on the pore concentration of the aluminum metal foam, manufactured by powder metallurgy process

In this paper, the effect of fabrication parameters on the pore concentration of aluminum metal foam manufactured by powder metallurgy process is studied. Aluminum metal foam specimens were fabricated from the mixture of aluminum powders (mean particle size 60 μm) and NaCl at 10,20,30,40(wt) % content under 200, 250, 300, MPa Pressures. All specimens were then sintered at 630°C for 2.5 hours in an argon atmosphere. For pore formation (foaming), sintered specimens were immersed into 70°C hot running water. Finally the pore concentration of specimens was recorded to analyze the effect of fabrication parameters (namely NaCl ratio, NaCl particle size and compacting pressure) on the foaming behavior of compacted specimens. As a result of the study, it has been recorded that the above mentioned fabrication parameters are effective on pore concentration profile while pore diameters remained unchanged.