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21.
Shigeru Sugiyama Kiyozumi Sato Seiji Yamasaki Katsuhiro Kawashiro Hiromu Hayashi 《Catalysis Letters》1992,14(1):127-133
Silica-supported alkaline earth oxides revealed excellent activity to convert acetic acid selectively into acetone in a vapor-phase fixed-bed flow system. Acetone was obtained through the cyclic formation of alkaline earth acetate followed by decomposition. Magnesium oxide should be supported on the silica surface without formation of magnesium silicate, which was inactive for the present reaction. Attempted syntheses of benzophenone and acetophenone are also described. 相似文献
22.
A series of organic-soluble naphthalocyanine derivatives (YmMNcX4) have been synthesized. Their spectroscopic properties in organic solutions and in thin films were studied. MNcX4 such as MNc(t-Bu)4 (5a-5c) and MNc(On-Bu)4 (5j) formed H-aggregates even in dilute solutions. MNc(CO2R')4 (5d-5i) had much stronger H-aggregation properties compared with those ofMNc(t-Bu)4 and MNc(On-Bu)4. Especially, MNc(CO2R')7 complexes (M=Cu, Pd and Ni) existed exclusively without monomers in the aggregated state even in highly dilute solutions. MNcX4, which has strong H-aggregation properties, showed merely H- aggregate absorption maxima in thin films. In contrast, Y2MNcX4 (4), which has sterically hindered Y groups, showed monomerically pure characteristics in solution. However, thin films of Y2MNcX4 have a J-type molecular arrangement, exhibiting a red shift of Q-band absorption. The monomeric properties of Y2MNcX4 in solutions and J-type molecular arrangement in thin films arise from steric hindrance of two Y groups, such as R3SiO-in Y2MNcX4, which prevents strong H-aggregation of naphthalocyanine. 相似文献
23.
Some mechanical properties of styrene and acrylonitrile copolymers grafted onto acrylic rubber are investigated. The impact strength of graft polymers depended upon the nature and the concentration of the catalyst, the composition and the intrinsic viscosity of the rubber, and the acrylonitrile content in the rigid matrix. The most desirable result was obtained when benzoyl peroxide as the catalyst, n-butyl acrylate–acrylonitrile copolymer of 7–10% acrylonitrile content, and about 0–5% acrylonitrile in the rigid matrix were used. Dynamic mechanical tests show the increase in efficiency of rubber modification by the grafted chains. The better weathering resistance of these graft polymers, as compared with commercial ABS plastics, was confirmed. 相似文献
24.
C4+ and S4+-codoped titanium dioxide (TiO2) having a rutile phase was prepared. By doping C4+ and S4+ ions into a TiO2 lattice, the absorption edge of rutile TiO2 powder was largely shifted from 400 to 700 nm. 2-Methylpyridine and methyleneblue were photocatalytically oxidized at high efficiency on C4+ and S4+-doped TiO2 under visible light at a wavelength longer than 5 nm. 相似文献
25.
Tsunehiro Aki Kazutaka Hachida Megumi Yoshinaga Yuko Katai Takashi Yamasaki Seiji Kawamoto Toshihide Kakizono Takashi Maoka Seiko Shigeta Osamu Suzuki Kazuhisa Ono 《Journal of the American Oil Chemists' Society》2003,80(8):789-794
Thraustochytrids, marine protists whose dominant genera are Thraustochytrium and Schizochytrium, belong to the kingdom Chromista and are known as an industrial source of DHA. We describe here that thraustochytrid strain
KH105, isolated as a DHA producer, also accumulates significant levels of β-carotene and xanthophylls including canthaxanthin
and astaxanthin. A4-d cultivation using a medium composed of 10% glucose and less than 0.3% of nitrogen sources in a half-concentration
of seawater gave an astaxanthin production up to 6.1 mg/L, and canthaxanthin content reached more than 10 mg/L under conditions
where a higher concentration of nitrogen sources (6%) was employed. It might be advantageous in mass production systems for
these carotenoids to be extracted readily by simply suspending the cells with organic solvents such as acetone and chloroform.
Analyses on the morphological and life history features of the KH105 strain revealed that it belongs to the genus Schizochytrium. This particular species of thraustochytrids is thus considered to be a promising source of xanthophylls as well as DHA for
use in the food industry. 相似文献
26.
Ryu Komatsu Ryo Nakazato Takeru Sasaki Akio Suzuki Naoyuki Senda Takuya Kawata Yasuhiro Jimbo Tomoya Aoyama Naoto Ohno Susumu Kawashima Hisao Ikeda Shingo Eguchi Yoshiharu Hirakata Shunpei Yamazaki Takashi Shiraishi Seiji Yasumoto Masataka Nakada Masataka Sato Chris Bower Darryl Cotton Andrew Matthews Piers Andrew Catalin Gheorghiu Johan Bergquist 《Journal of the Society for Information Display》2015,23(2):41-49
In this study, a 5.9‐inch foldable active‐matrix organic light emitting diode (AMOLED) display was developed. A folding test was performed repeatedly. The display survived the folding test (100,000 folds) with a curvature radius of 2 mm. To protect an organic light emitting diode (OLED) against moisture, inorganic passivation layers are provided on the upper and lower sides of the flexible display. Using our transfer technology, high density passivation layers can be obtained. The measured water vapor transmission rate of the layer is 7 × 10?6 g/m2?day or less, which improves OLED reliability. With these techniques, we have developed a book‐type display, which is repeatedly foldable like a book, and a tri‐fold display including a display area, which is foldable in three. 相似文献
27.
Yoshiaki Ukita Toshifumi Asano Kuniyo Fujiwara Katsuhiro Matsui Masahiro Takeo Seiji Negoro Yuichi Utsumi 《Microsystem Technologies》2008,14(9-11):1573-1579
The advantages of vertical microreactor stack with three-dimensional (3D) structure for immunoassay are discussed. The vertical microreactor stack uses vertical fluid flow operation with multifunctional fluid filters. The multi function of fluid filter is very effective for micromixing and passive valve operation. The mechanism of micromixing is discussed by using computational fluid dynamics (CFD), and we know that the mixing mechanism based on Coanda effect. To evaluate the micromixing performance of fluid filter, we demonstrated enzyme reaction with unique repeat mixing operation. As the results, we proved that the fluid filter has very effective mixing performance. The detection limit, which demonstrated by competition enzyme-linked immunosorvent assay (ELISA), is comparable with recommended detection limit, which suggested by Japanese ministry for the environment. 相似文献
28.
We report the use of extreme broadband, high reflectivity >99.5%, optical parametric oscillator (OPO) cavity mirrors. A continuous-wave, doubly resonant, OPO demonstrated tuning over a range of 791-1620 nm with a single mirror set. Wavelength tuning was performed by temperature tuning the nonlinear material of lithium triborate. Narrow linewidth oscillation was confirmed throughout the tuning range, and threshold pump power increased gradually from 50 mW near the degeneracy to 800 mW at the tuning band edge in a double-pass pumping configuration. 相似文献
29.
A computer-based spatial-filtering velocimeter to measure the surface velocity of natural debris flow is described. This is a simple and interesting technique implemented with a spatial filter constructed as a software program that processes the video image of debris flow instead of a hardware implementation. The surface velocity of the debris flow at the Mt. Yakedake Volcano, Japan, was estimated by this computer-based spatial-filtering method, and the results were compared with those obtained by a hardware-based spatial-filtering method. Computer-based spatial filtering has the important advantage of a capability for tuning the spatial-filter parameters to the target flow. 相似文献
30.
K Tanaka T Miyairi J Matsumoto H Inaba A Mizuno 《Canadian Metallurgical Quarterly》1996,49(7):552-556
Between September 1994 and January 1995, the inferior epigastric artery (IEA) was used as a free graft for direct coronary artery bypass grafting in 4 patients. The IEA is excised from its origin from the external iliac artery as a pedicle with an "oval cuff" of 3 mm in diameter to facilitate the direct anastomosis with the aorta. The 4-week postoperative angiographic study showed that the IEA grafts were patent in all patients. We found that the IEA varies in length, diameter, and the pattern of branching between patients and between the right and left sides in the same patient. The preoperative digital subtraction angiography was useful for evaluating the suitability of IEA. 相似文献