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111.
A 4‐Fold‐Symmetry Hexagonal Ruthenium for Magnetic Heterostructures Exhibiting Enhanced Perpendicular Magnetic Anisotropy and Tunnel Magnetoresistance 下载免费PDF全文
112.
Seiji Yamashita Hideo Watanabe Takashi Shirai Masayoshi Fuji Minoru Takahashi 《Advanced Powder Technology》2011,22(2):271-276
We have successfully synthesized zinc oxide microrods perpendicularly oriented on hexagonal ZnO sheets by a simple heat treatment approach using LDH (layered double hydroxide) precursor in an aqueous solution. The synthesized ZnO microrods have an average diameter of 500 nm and length of 2–3 μm, and form highly-oriented array. In this work, the effect of heating temperature and time on morphology and orientation of ZnO microrods was studied experimentally and the formation mechanism was discussed in detail. Transformation from hexagonal precursor to ZnO microrods can be attributed to dissolution and re-precipitation of the precursor, which should be caused by its thermal unstability under heating temperature. 相似文献
113.
Four-terminal electrical measurement is realized on a microscopic structure in air, without a lithographic process, using a home-built quadruple-scanning-probe force microscope (QSPFM). The QSPFM has four probes whose positions are individually controlled by obtaining images of a sample in the manner of atomic force microscopy (AFM), and uses the probes as contacting electrodes for electrical measurements. A specially arranged tuning fork probe (TFP) is used as a self-detection force sensor to operate each probe in a frequency modulation AFM mode, resulting in simultaneous imaging of the same microscopic feature on an insulator using the four TFPs. Four-terminal electrical measurement is then demonstrated in air by placing each probe electrode in contact with a graphene flake exfoliated on a silicon dioxide film, and the sheet resistance of the flake is measured by the van der Pauw method. The present work shows that the QSPFM has the potential to measure the intrinsic electrical properties of a wide range of microscopic materials in situ without electrode fabrication. 相似文献
114.
Pattanayak DK Yamaguchi S Matsushita T Kokubo T 《Journal of materials science. Materials in medicine》2011,22(8):1803-1812
Nanometer-scale roughness was generated on the surface of titanium (Ti) metal by NaOH treatment and remained after subsequent
acid treatment with HCl, HNO3 or H2SO4 solution, as long as the acid concentration was not high. It also remained after heat treatment. Sodium hydrogen titanate
produced by NaOH treatment was transformed into hydrogen titanate after subsequent acid treatment as long as the acid concentration
was not high. The hydrogen titanate was then transformed into titanium oxide (TiO2) of anatase and rutile by heat treatment. Treated Ti metals exhibited high apatite-forming abilities in a simulated body
fluid especially when the acid concentration was greater than 10 mM, irrespective of the type of acid solutions used. This
high apatite-forming ability was maintained in humid environments for long periods. The high apatite-forming ability was attributed
to the positive surface charge that formed on the TiO2 layer and not to the surface roughness or a specific crystalline phase. This positively charged TiO2 induced apatite formation by first selectively adsorbing negatively charged phosphate ions followed by positively charged
calcium ions. Apatite formation is expected on the surfaces of such treated Ti metals after short periods, even in living
systems. The bonding of metal to living bone is also expected to take place through this apatite layer. 相似文献
115.
Shiho Kuwashiro Yoshiro Hatanaka Kousaku Tao Seiji Higashi Keitaro Kago Hiroshi Hirano Hajime Kishi 《应用聚合物科学杂志》2024,141(19):e55315
Amorphous polymer/crystalline polymer blends can be prepared via the simultaneous polymerization of polymethacrylate/polyurethane combinations. The relationship between higher order structures and fracture mechanisms in these blends must be uncovered to elucidate the source of the increased fracture toughness of such materials. The present work involves the production of blended polymethacrylate/polyurethane and assess the internal structures of these specimens using optical and electron microscopy. These observations reveal the presence of both spherulites and elastomeric phases. The spherulites consisting of the polyurethane and are several micrometers in diameter whereas the phase-separated polyurethane elastomeric domains are approximately 100 nm in size. Multiple cracks, crack bridging and plastic deformation around the precrack tips of loaded specimens are evidently responsible for the increased toughness of these blends. The former two phenomena are attributed to the presence of spherulites while the plastic deformation of the methacrylate matrix is ascribed to cavitation of the polyurethane elastomeric phases in response to loading. 相似文献
116.
Deokho Lee Yohei Tomita Yukihiro Miwa Heonuk Jeong Ari Shinojima Norimitsu Ban Shintaro Yamaguchi Ken Nishioka Kazuno Negishi Jun Yoshino Toshihide Kurihara 《International journal of molecular sciences》2022,23(23)
Cardiovascular abnormality-mediated retinal ischemia causes severe visual impairment. Retinal ischemia is involved in enormous pathological processes including oxidative stress, reactive gliosis, and retinal functional deficits. Thus, maintaining retinal function by modulating those pathological processes may prevent or protect against vision loss. Over the decades, nicotinamide mononucleotide (NMN), a crucial nicotinamide adenine dinucleotide (NAD+) intermediate, has been nominated as a promising therapeutic target in retinal diseases. Nonetheless, a protective effect of NMN has not been examined in cardiovascular diseases-induced retinal ischemia. In our study, we aimed to investigate its promising effect of NMN in the ischemic retina of a murine model of carotid artery occlusion. After surgical unilateral common carotid artery occlusion (UCCAO) in adult male C57BL/6 mice, NMN (500 mg/kg/day) was intraperitoneally injected to mice every day until the end of experiments. Electroretinography and biomolecular assays were utilized to measure ocular functional and further molecular alterations in the retina. We found that UCCAO-induced retinal dysfunction was suppressed, pathological gliosis was reduced, retinal NAD+ levels were preserved, and the expression of an antioxidant molecule (nuclear factor erythroid-2-related factor 2; Nrf2) was upregulated by consecutive administration of NMN. Our present outcomes first suggest a promising NMN therapy for the suppression of cardiovascular diseases-mediated retinal ischemic dysfunction. 相似文献
117.
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119.
To improve nuclear fuel utilization efficiency and prolong fuel cycle burn-up,a tight ptich lattice pressured heavy water reactor was investigated as an alternative of next generation of power reactors.It is shown that the high conversion ratio and negative coolant void reactivity coefficient are challenges in the reactor core physics designs.Various techniques were proposed to solve these problems.In this work.a tight pitch lattice and mixed fuel assemblies pressured heavy water reactor concept was investigated.BY utilizing numerical simulation technique,it is demonstrated that reactor core mixed with Pu/U and Th/U assemblies can achieve high conversion ratio(0.98) ,long burn-up(60GWD/t)and negative void reactivity coefficients. 相似文献
120.
Taro Kimura Masayuki Takeuchi Itaru Hamachi Seiji Shinkai 《Israel journal of chemistry》1996,36(4):379-388
A boronic-acid-appended amphiphile bearing an azobenzene chromophore in the chain center ( 3 ) was synthesized. Although 3 could not form the membrane-like, ordered aggregate by itself, it formed a phase-separated aggregate in a dipalmitoylphosphatidylcholine (DPPC) matrix membrane. When saccharides were added, the boronic acid group reversibly formed the saccharide complexes, and 3 in the DPPC matrix membrane became CD-active with the appearance of exciton-coupling bands. Comparison of the saccharide absolute configuration with the CD intensity established that the saccharide possessing the OH group (as 3-OH, 4-OH, and 5-CH2OH) in the same side as the cis-1,2-diol gives the strong CD band. Judging from the structure of 3 –saccharide complexes, these “same-side” OH groups can enjoy intermolecular hydrogen-bonding interactions, which eventually induce the chiral orientation of azobenzene chromophores. This is a novel membrane system useful to read out the information stored in the saccharide structure and to create novel membrane structures by added saccharides. 相似文献