Experimental investigation of green brick shrinkage behavior with Bigot’s curves

The objective of this work is to define the convenient drying parameters such that the energy consumption in the brick drying process is minimized. This is an experimental study where the challenge lies in the mechanical resistance of the dried bricks which must satisfy the quality standards despite the reduction of energy consumption and the drying time. Firstly, we run multiple drying process tests and gather experimental data, and then discover the most suitable drying conditions. Secondly, the overall drying rate is improved using a Bigot’s curve analysis on the most suitable drying conditions. The results show that the drying rate increases significantly in conjunction with shorter drying time and lower energy consumption.     

Evaluation of the Substrate Scope of Benzoic Acid (De)carboxylases According to Chemical and Biochemical Parameters

The enzymatic carboxylation of phenolic compounds has been attracting increasing interest in recent years, owing to its regioselectivity and technical potential as a biocatalytic equivalent for the Kolbe–Schmitt reaction. Mechanistically the reaction was demonstrated to occur through electrophilic aromatic substitution/water elimination with bicarbonate as a cosubstrate. The effects of the substituents on the phenolic ring have not yet been elucidated in detail, but this would give detailed insight into the substrate–activity relationship and would provide predictability for the acceptance of future substrates. In this report we show how the kinetic and (apparent) thermodynamic behavior can be explained through the evaluation of linear free energy relationships based on electronic, steric, and geometric parameters and through the consideration of enzyme–ligand interactions. Moreover, the similarity between the benzoic acid decarboxylases and the amidohydrolases superfamily is investigated, and promiscuous hydrolytic activity of the decarboxylase in the context of the hydrolysis of an activated ester bond has been established.     

Housing price dynamics and bubble risk: the case of Turkey

Abstract

Housing prices have increased substantially in some emerging markets in recent years. Turkish housing market has also experienced a boom over the last decade with rapid house price appreciations. This study is the first to employ two different house price indexes to analyze housing bubble in Turkey in two different time periods, 2010:M1–2014:M12 and 2007:M6–2014:M12. We first capture the determinants of housing price by employing Bounds test and then examine whether rising house prices have been justified by fundamentals by employing OLS/FMOLS/DOLS, Kalman filter and ARIMA models. The Bounds test results suggest that there is a long-term cointegration among house price indexes and housing rent, construction cost and real mortgage interest rate. The results imply that the Turkish housing market has experienced some cases of overvaluation, but not bubble formation. This evidence has several implications for house price dynamics and risks in the Turkish housing market. Based on Turkish experience, the study also draws policy implications for emerging housing markets.     

An evaluation of image reproduction algorithms for high contrast scenes on large and small screen display devices

Rendering high contrast scenes on display devices with limited dynamic range is a challenging task. Two groups of algorithms have emerged to take up this challenge: tone mapping operators (TMOs) and more recently exposure fusion (EF) techniques. While several formal evaluation studies comparing TMOs exist, no formal evaluation has yet been performed that compares EF techniques with each other or compares them against TMOs. Moreover, with the advancements in hand-held devices and programmable digital cameras it became possible to directly capture and view high dynamic range (HDR) content on these devices which are characterized by their small screens. However, currently very little is known about how to best visualize a high contrast scene on a small screen. Thus the primary goal of this paper is to provide answers to both of these questions by conducting a series of rigorous psychophysical experiments. Our results suggest that the best tone mapping algorithms are generally superior to EF algorithms except for the reproduction of colors. Furthermore, contrary to some previous work, we find that the differences between algorithms are barely perceptible on small screens and therefore one can opt for a simpler solution than a more complex and accurate one.     

Determination of the principal parameter of ultrasonic pulse velocity and compressive strength of lightweight concrete by using variance method

Experiments are usually made to finding maximum ultrasonic pulse velocity and compressive strength of lightweight concrete. In this study, ultrasonic pulse velocity and compressive strength of lightweight concrete made with scoria aggregate, silica fume and fly ash was investigated experimentally and statistically. This article adopts Taguchi approach. The Taguchi method has been used to determine the optimum conditions and to reduce the numbers of experiments. Four control factors (maximum size of aggregate, curing conditions, mineral admixtures and curing time) for this study were used. The level of importance of these parameters on ultrasonic pulse velocity and compressive strength was determined by using analysis of variance (Anova) method. The text was submitted by the authors in English.     

Water recovery from treated urban wastewater by ultrafiltration and reverse osmosis for landscape irrigation

Techno-economic feasibility of water recovery from secondary effluents of an urban wastewater treatment plant (WWTP) for landscape irrigation was investigated considering two distinctive strategies: ultrafiltration (UF)/chlorination and UF/reverse osmosis (RO). Experimental performance evaluations were conducted separately for UF membranes and for different RO trans-membrane pressures. The quality of the effluent recovered by the UF/RO system was in accordance with the national and international guidelines. The produced reuse water was first class quality according to the national guideline for all parameters except sodium adsorption ratio (SAR), which can be eliminated readily by direct addition of KCl into the recovered water. Estimated field-scale costs indicated that UF/RO yielded a total cost of US$12,500,000–13,600,000 with annual operating cost being US$482,000–533,000 at 5–20 bar. The economic estimations guaranteed reimbursement with US$7,600,000–7,400,000 net present value, 0.22–0.39 year payback time, US$0.44–0.49/m³ treatment cost, and a benefit/cost ratio of 0.57.     

Epindolidiones—Versatile and Stable Hydrogen‐Bonded Pigments for Organic Field‐Effect Transistors and Light‐Emitting Diodes

Hydrogen‐bonded pigments are remarkably stable high‐crystal lattice energy organic solids. Here a lesser‐known family of compounds, the epindolidiones, which demonstrates electronic transport with extraordinary stability, even in highly demanding aqueous environments, is reported. Hole mobilities in the range 0.05–1 cm² V^–1 s^–1 can be achieved, with lower electron mobilities of up to 0.1 cm² V^–1 s^–1. To help understand charge transport in epindolidiones, X‐ray diffraction is used to solve the crystal structure of 2,8‐difluoroepindolidione and 2,8‐dichloroepindolidione. Both derivatives crystallize with a linear‐chain H‐bonding lattice featuring two‐dimensional π–π stacking. Powder diffraction indicates that the unsubstituted epindolidione has very similar crystallinity. All types of epindolidiones measured here display strong low‐energy optical emission originating from excimeric states, which coexists with higher‐energy fluorescence. This can be exploited in light‐emitting diodes, which show the same hybrid singlet and low‐energy excimer electroluminescence. Low‐voltage FETs are fabricated with epindolidione, which operate reliably under repeated cyclic tests in different ionic solutions within the pH range 3–10 without degradation. Finally, in order to overcome the insolubility of epindolidiones in organic solvents, a chemical procedure is devised to allow solution‐processing via the introduction of suitable thermolabile solubilizing groups. This work shows the versatile potential of epindolidione pigments for electronics applications.     

A new approach for simplifying the calculation of flue gas specific heat and specific exergy value depending on fuel composition

In this paper, a new approach is proposed for simplifying the calculation of flue gas specific heat and specific exergy value in one formulation depending on fuel chemical composition. Combustion products contain different gases such as CO₂, SO₂, N₂, O₂, H₂O and etc., depending on the burning process. Specific heat and exergy of the flue gas differ depending on the chemical composition of fuels, excess air ratio and gas temperature. Through this new approach, specific heat and specific exergy value of combustion products can be estimated accurately in one formulation by entering the chemical composition of fuels, excess air ratio and gas temperature. The present approach can be applied to all carbon based fuels, especially biomass, fossil fuels and fuel mixtures for co-combustion and is so suitable for practical estimation of flue gas specific heat and specific exergy values provided that the fuel chemical composition is given.     

Highly efficient recovery of bioactive ingredients from solid waste of onions onto functionalized SWCNTs supported on amberlite nanocomposite

Preparation of single-walled carbon nanotubes (SWCNTs) with carboxylic (–COOH) acid was executed by functionalization with amine functional groups (–NH2). The obtained functionalized SWCNTs were supported by macroporous resin (amberlite XAD-7HP). The synthesized nanocomposite has been characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) methods. FTIR analysis indicates that functionalized SWCNTs supported onto the amberlite resin were synthesized successfully. The surface morphology of the nanomaterial was also successfully embedded into the amberlite of the functionalized SWCNTs. Huge solid residues of onions are produced as agricultural and food wastes each year. The related biowaste includes biologically active phenolic compounds which have positive effects with strong antioxidant properties on human health when properly isolated and concentrated. In the present research, functionalized SWCNTs have been utilized for the separation of bioactive phenolics from onion waste extracts. Equilibrium (Langmuir, Freundlich and Toth) and kinetic (pseudo-first order, pseudo-second order, intraparticular diffusion and Elovich) models have been applied for analysis and representation of data. Pseudo-second-order model is in good agreement with the experimental data. On the other hand, the equilibrium findings were represented best with Freundlich isotherm model. Additionally, thermodynamic indicators have also demonstrated that the current system is a spontaneous and exothermic chemisorption process.     

Functionalization of halloysite nanotubes with polyethyleneimine and various ionic liquid forms with antimicrobial activity

Halloysite nanotube (HNT), a natural clay, was modified with branched polyethyleneimine (PEI) to form PEI-HNT using epichlorohydrin (ECH) as coupling agent, then protonated with HCl to obtain H-PEI-HNTs providing [NH₃]⁺[Cl]⁻ functionality for potential antimicrobial properties. Upon PEI modification, zeta potential value of HNTs was increased to +37.3 mV from −34.5 mV and to +41.1 mV for H-PEI-HNTs. Only 1.87 wt % H-element in HNT was increased to 3.03 wt % upon PEI modification along with newly generated elements of N and C at 2.99 and 9.93 wt %, respectively. Moreover, ionic liquid (IL) forms of HNTs with [NH₃]⁺[N(CN)₂]⁻, [NH₃]⁺[PF₆]⁻ and [NH₃]⁺[BF₄]⁻ functionality were generated via anion exchange of H-PEI-HNTs with sodium dicyanamide (SDC), ammonium hexafluorophosphate (AHFP), and sodium tetrafluoroborate (STFB). The antimicrobial properties of the modified, protonated, and IL forms of HNTs were determined via macro dilution, diffusion and agar screening tests against Escherichia coli ATCC 8739, Pseudomonas aeruginosa ATCC 10145, Bacillus subtilis ATCC 6633, Staphylococcus aureus ATCC 6538 strains, and Candida albicans ATCC 10231 strains. It was found that H-PEI-HNTs possesses potent antimicrobial effect compared with the other forms of HNTs with 2–4 mg mL⁻¹ MIC and 8–16 mg mL⁻¹ MBC values via the macro dilution method. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48352.