Feedback control of tri-layer polymer actuators to improve their positioning ability and speed of response

Improving positioning ability of electroactive polymer actuators typified by polypyrrole (PPy) through feedback control of their position has been considered. The actuators operate in air, as opposed to their predecessors. One of the problems associated with the actuators is the forward relaxation/creep or drift, which occurs after the full reduction and oxidation processes are completed. A high-resolution laser displacement sensor was used to detect the position of the cantilever-type polymer actuators and the classical, yet effective, Proportional, Integral and Derivative (PID) control method has been employed to generate the appropriate control input in order to make sure that no drift occurs in the user-specified position of the actuators. A set of experimental results with and without feedbacking the position data are presented to demonstrate the efficacy of the control method for improving the positioning ability and the speed of response. The rise time is reduced by more than 500 times and the position tracking error is less than 10% for a time-varying user-specified position command.     

Investigation of mechanical and creep properties of polypyrrole by depth-sensing indentation

In this study, we used depth-sensing indentation (DSI) technique to investigate some mechanical properties (reduced elastic modulus, indentation hardness, and creep) of polypyrrole (PPy) conducting polymer obtained with different support electrolyte concentration. The influence of support electrolyte concentration on these parameters was also determined. The order of doping degree of the samples was determined by cyclic voltammetry. The indentation load–displacement curves of the samples were obtained under different peak load levels with a 70 s holding time at maximum load. Reduced elastic modulus and hardness values were determined by analysis of these curves using the Feng–Ngan (F–N) and Tang–Ngan (T–N) methods, respectively. Both reduced elastic modulus (E _r) and indentation hardness (H) exhibited significant peak load dependence, i.e., indentation size effect (ISE). It was found that both E _r and H values decreased as the support electrolyte concentration was increased. This was explained by an increase in the free volume as the doping degree was raised. The creep behavior of the samples was monitored from the load holding segment of the load–unload curves. It was found that creep increases with the increasing support electrolyte concentration.     

Polyethylene glycol‐sugar composites as shape stabilized phase change materials for thermal energy storage

Polyethylene glycol (PEG)‐sugar composites have been investigated as cost effective shape‐stabilized phase change materials for thermal energy storage. PEGs form internal hydrogen bonds stabilizing their chains at solid state. However low molecular weight PEGs are liquid due to short chains as high molecular weight PEGs have too little concentration of hydroxyl groups. Therefore, glucose, fructose, and lactose are used as hydrogen bond source in this study. Consequently it is found that sugars stabilized PEGs up to 90% PEG constitution in solid state except for 90%PEG10,000/10% fructose blend. Fourier transform‐infrared (FT‐IR) analysis revealed considerable interactions between PEGs. The maximum changes in the spectra were observed in the OH stretching region as band broadening due to increasing hydrogen bonding interactions. Differential scanning calorimetry (DSC) analysis are used to determine phase change temperatures and enthalpy of the shape‐stabilized composites that are slightly lower than those of PEG precursors due to the interference effect of sugar in crystallization process. The enthalpies of the blends are 89%, 95%, and 94% of expected from 90%PEG/10% glucose blends, 93%, 94%, and 93% of expected from 90% PEG/10% fructose blends, and 99%, 96%, and 96% of expected from 90% PEG/10% lactose blends respectively when PEGs with 1,000; 6,000; and 10,000 g/mol average molecular weights are used respectively. The diameter of the spherulitic crystals of PEGs decreases with the addition of any of sugar derivatives and spherulites of the composites turns to semi‐amorphous solid structures at temperatures above melting point of PEG precursor. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers     

Effects of moisture content on formaldehyde emission and mechanical properties of plywood

Wood is a hygroscopic material and has ability to exchange its moisture content with air. Many mechanical properties are affected by changes in moisture content below the fiber saturation point of wood. This study evaluates the formaldehyde emission and some mechanical properties of poplar and spruce plywood panels manufactured from rotary cut veneers having different moisture content by using urea–formaldehyde (UF) and modified urea formaldehyde by melamine (M+UF). Rotary cut veneers obtained from poplar and spruce logs were classified into three groups and veneers in each group were then conditioned in a climate chamber to either 4–6%, 10–12% or 16–18% moisture content. Plywood panels with three plies and in 6 mm thickness were manufactured for each group. Formaldehyde emission, shear strength, bending strength and modulus of elasticity values of plywood panels were determined. Best bonding results were obtained in plywood panels with veneers having 4–6% moisture content. Lowest mechanical properties were found for plywood panels manufactured from veneers conditioned to 16–18% moisture content. Formaldehyde emission values of poplar and spruce plywood panels decreased with increasing veneer moisture content for both glue types. Formaldehyde emission content of panels decreased with melamine addition into the urea formaldehyde glue mixture.     

A scalable model for trilayer conjugated polymer actuators and its experimental validation

Conjugated polymers are promising actuation materials for bio/micromanipulation systems, biomimetic robots, and biomedical devices. For these applications, it is highly desirable to have predictive models available for feasibility study and design optimization. In this paper a scalable model is presented for trilayer conjugated polymer actuators based on J. Madden's diffusive-elastic-metal model. The proposed model characterizes actuation behaviors in terms of intrinsic material parameters and actuator dimensions. Experiments are conducted on polypyrrole actuators of different dimensions to validate the developed scaling laws for quasi-static force and displacement output, electrical admittance, and dynamic displacement response.     

Preparation and characterization of sepiolite‐poly(ethyl methacrylate) and poly(2‐hydroxyethyl methacrylate) nanocomposites

Poly(ethyl methacrylate) (PEMA) and poly(2‐hydroxyethyl methacrylate) (PHEMA) nanocomposites with sepiolite in pristine and silylated form were prepared using the solution intercalation method and characterized by the measurements of XRD, TEM, FTIR‐ATR, TG/DTG, and DSC. The TEM analysis indicated that the volume fraction of fibers in sepiolite decreased and the fiber bundles dispersed in PEMA and PHEMA at a nanometer scale. These results regarding TEM micrographs were in agreement with the data obtained by XRD. The increase in thermal stability of nanocomposites of PEMA is higher than that of PHEMA according to the data obtained from TG curves. The DTG analysis revealed that sepiolite/modified sepiolite caused some changes, as confirmed by FTIR in the thermal degradation mechanism of the polymers. T_g temperatures of PEMA and PHEMA usually increased upon the addition of sepiolite/modified sepiolite. In addition, modification of sepiolite with 3‐APTS had a slight influence on thermal properties of the nanocomposites. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers     

Poly(styrene‐co‐maleic anhydride)‐graft‐fatty acids as novel solid–solid PCMs for thermal energy storage

A solid–solid phase change material (S‐SPCM) can store and release a specific amount of latent heat during its phase transition. In this regard, poly(styrene‐co‐maleic anhydride) (SMA)‐graft‐fatty acids (FA) copolymers were synthesized as novel S‐SPCMs for thermal energy storage (TES). The chemical structures of the SMA‐g‐FA copolymers were characterized by proton nuclear magnetic resonance (¹H NMR) and Fourier transform infrared (FT‐IR) spectroscopy techniques. The phase transformations of the copolymers form crystalline phase to amorphous phase were monitored using polarized optical microscopy (POM). The latent heat TES (LHTES) properties, thermal cycling reliability, and thermal stability of the S‐SPCMs were investigated by differential scanning calorimetry and thermogravimetric analysis methods. The SMA‐g‐FA copolymers produced as S‐SPCMs showed solid–solid phase transitions at about 40°C–60 °C range and had latent heat storage and release ability between 84 and 127 J/g, respectively. The S‐SPCMs had stable chemical structures and reliable LHTES characteristics even after 5,000 thermal cycling. They had reasonable thermal conductivity value changed in the range of 0.15–0.19 W/mK. Furthermore, it was concluded that the SMA‐g‐FA copolymers can be considered as promising S‐SPCMs for TES utilizations. POLYM. ENG. SCI., 59:E337–E347, 2019. © 2019 Society of Plastics Engineers     

A cellular neural network methodology for deformable object simulation.

This paper presents a new methodology to simulate soft object deformation by drawing an analogy between a cellular neural network (CNN) and elastic deformation. The potential energy stored in an elastic body as a result of a deformation caused by an external force is propagated among mass points by a nonlinear CNN. The novelty of the methodology is that: 1) CNN techniques are established to describe the potential energy distribution of the deformation for extrapolating internal forces and 2) nonlinear materials are modeled with nonlinear CNNs rather than geometric nonlinearity. Integration with a haptic device has been achieved for deformable object simulation with force feedback. The proposed methodology not only predicts the typical behaviors of living tissues, but it also accommodates isotropic, anisotropic, and inhomogeneous materials, as well as local and large-range deformation.