Insulating and Other Physical Properties of CoO‐Doped Zinc Oxyfluoride‐Borate Glass‐Ceramics

Zinc oxy fluoro borate glasses mixed with different concentrations of CoO (ranging from 0 to 2.0 mol%) are synthesized and subsequently crystallized. The scanning electron microscopy pictures have exhibited crystallinity. Differential scanning calorimetric studies have indicated that the prepared samples consist of multiple crystal phases. The X‐ray diffraction patterns have indicated that the glass‐ceramic samples are composed of αZn(BO₂)_2, (Zn)₃(BO₃)_2, CoF₂, CoF₃, Co₃FB₇O₁₃, ZnCo₂O₄, Co₃O₄ crystalline phases. The optical absorption and photoluminescence studies have indicated that there is a gradual increase of tetrahedral cobalt ion concentration with increase of CoO concentration in the glass network. IR spectroscopic studies have pointed out increased degree of polymerization of the zinc oxy fluoro borate glass network with increase of CoO content. The analysis of results of dielectric properties indicated increase of insulating strength of the glass‐ceramics with increase of CoO content. Finally, the dielectric breakdown strength of the samples is measured at room temperature in air medium and it is found to increase from 12.9 to 19.2 kV/cm with increase of CoO from 0.2 to 2.0 mol%. The reasons for such increase of breakdown strength are discussed quantitatively in terms of dielectric parameters with aid of data on spectroscopic properties.     

Effectiveness of sodium silicate as gangue depressants in iron ore slimes flotation

The recovery of iron from the screw classifier overflow slimes by direct flotation was studied.The relative effectiveness of sodium silicates with different silica-to-soda mole ratios as depressants for silica and silicate bearing minerals was investigated.Silica-to-soda mole ratio and silicate dosage were found to have significant effect on the separation efficiency.The results show that an increase of Fe content in the concentrate is observed with concomitant reduction in SiO2 and Al2O3 levels when a particular type of sodium silicate at a proper dosage is used.The concentrate of 58.89wt％ Fe,4.68wt％ SiO2,and 5.28wt％ Al2O3 with the weight recovery of 38.74％ and the metal recovery of 41.13％ can be obtained from the iron ore slimes with 54.44wt％ Fe,6.72wt％ SiO2,and 6.80wt％ Al2O3,when Na2SiO3 with a silica-to-soda mole ratio of 2.19 is used as a depressant at a feed rate of 0.2 kg/t.     

Onset of thermal instability in a horizontal layer of fluid with modulated boundary temperatures

Thermal instability in a horizontal layer of fluid, with the boundary temperatures modulated sinusoidally in time, is studied. The amplitude of modulation is assumed small and is used as an expansion parameter. It is shown that an exact solution can be obtained, even when the boundaries are considered to be rigid. When only the lower boundary temperature is modulated, for small values of the Prandtl number modulation is always stabilizing, while for large values it can be stabilizing or destabilizing depending on the modulation frequency. When both boundary temperatures are modulated in phase, modulation is destabilizing for low modulation frequency, but for higher modulation frequency stabilization occurs for low values of the Prandtl number. When the two boundary temperatures are modulated out of phase the modulation always has a stabilizing effect.     

Effect of Prefault Load on Field Overvoltages in Rectifier-Excited Synchrondus Machine During Sequential 3-Phase Fault

ABSTRACT

In a Synchronous machine with rectifier excitation, large reverse voltages may be induced across the field during a transient condition when the field current tends to flow in the reverse direction and is blocked by rectifiers. Earlier investigation on an initially unloaded machine showed that a sequential 3-phase fault, in which a line to line fault develops into a 3-phase fault after a short time, produces field overvoltages whose magnitudes may be comparable to those due to line to line fault. In this paper, analysis has been carried out to estimate the magnitude of the field overvoltage during a sequential 3-phase fault when the machine is assumed to operate on a prefault load. Numerical results show that a sequential 3-phase fault on a machine having prefault loads may be much more severe compared to a line to line fault from the field overvoltage point of view. The results also indicate that very large field overvoltages may be produced during a sequential 3-phase fault on a salient pole machine operating initially on leading power factor loads.     

Stress-intensity factors for a wide range of semi-elliptical surface cracks in finite-thickness plates

Surface cracks are among the more common flaws in aircraft and pressure vessel components. Accurate stress analyses of surface-cracked components are needed for reliable prediction of their crack growth rates and fracture strengths. Several calculations of stress-intensity factors for semi-elliptical surface cracks subjected to tension have appeared in the literature. However, some of these solutions are in disagreement by 50–100%.

In this paper stress-intensity factors for shallow and deep semi-elliptical surface cracks in plates subjected to tension are presented. To verify the accuracy of the three-dimensional finite-element models employed, convergence was studied by varying the number of degrees of freedom in the models from 1500 to 6900. The 6900 degrees of freedom used here were more than twice the number used in previously reported solutions. Also, the stress-intensity variations in the boundary-layer region at the intersection of the crack with the free surface were investigated.     

Lanthanum samarium oxalate — its growth and structural characterization

Lanthanum samarium oxalate (LSO) single crystals are grown in silica gels by the diffusion of a mixture of aqueous solutions of lanthanum nitrate and samarium nitrate into the test tube having the set gel impregnated with oxalic acid. Tabular crystals of LSO having well defined hexagonal basal planes are observed at different depths inside the gel. LSO crystals grown by this method are colourless and transparent. Laue transmission X-ray diffraction pattern of LSO reveals well defined spots with two-fold symmetry along the horizontal axis. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) support that LSO loses water around 120°C, and CO and CO₂ around 350–450°C. The infrared (IR) absorption spectrum of LSO establishes the presence of oxalate (C₂ O₄)²⁻ ions. Energy dispersive X-ray analysis (EDAX) confirms the presence of La and Sm in the sample. X-ray photoelectron spectroscopic (XPS) studies of LSO confirm the presence of La and Sm in their respective oxide states. An empirical structure for LSO has been proposed on the basis of these findings.     

Electrochemical recovery of silver from waste aqueous Ag(I)/Ag(II) redox mediator solution used in mediated electro oxidation process

The paper presents a process for the electrochemical recovery of silver(Ag) by electro deposition on the electrode surface from the waste solutions of Ag(I)/Ag(II) redox system in nitric acid medium used for the mediated electrochemical process. Electrochemical recovery was carried out in an undivided cell with DSA-O₂ electrodes at room temperature condition. At an optimized current density of 12 A/dm², 99% of Ag recovery efficiency was achieved with high yield and low energy consumption. Experimental runs were made in order to observe the performance of the Ag recovery process. The operating conditions like current density, temperature and Ag(I) concentration of the electrolyte, the acid concentrations, agitation rate and inter-electrode distance were optimized.     

Applicability and evaluation of an implicit self-starting unconditionally stable methodology for the dynamics of structures

The applicability and evaluation of a new self-starting, unconditionally stable, implicit methodology of computation for the dynamics of structures is described. The methodology offers different perspectives and architecture for structural dynamics compared with the tranditional (widely advocated and commonly used) time integration methods. It is based on velocity representations and architecture and uses finite elements as the principal analysis tool for structural dynamic modeling/analysis. In particular, the dynamics of beam-type flexural models are considered, and comparative results validate and support the proposed use of the self-starting methodology of computation for the dynamics of linear/nonlinear structures. The overall effectiveness and elegance strongly support its use in most existing commercial codes.     

Satellite derived crop calendar for canal operation schedule in Bhadra project command area,India

Spatial information on crop calendars in the command areas of irrigation systems is useful to irrigation engineers in order to achieve chronological synchronization between water delivery pattern and crop life cycle. Such synchronization is vital for efficient use of water. The capability of satellite remote sensing technology to generate spatial crop calendar information in an irrigated command area and its usefulness in the evaluation of water delivery patterns are demonstrated in this paper. The study pertains to the major crop paddy during the rabi season (December to June) of 1992-93, in the Bhadra project command area of Karnataka state, India. Analyses of multidate Normalized Difference Vegetation Index (NDVI) profiles of paddy crop generated from Indian Remote Sensing (IRS) satellite data for each distributary command reveal three distinct growth patterns in the study area with each pattern characterized by a particular crop calendar. The spatial variability in crop calendar over the total command area has thus been derived. The ground truth data obtained in crop cutting experiments (CCEs) validate the satellite derived crop calendar. Distributary wise, water delivery data have been studied in conjunction with the satellite derived crop calendar to determine whether the existing pattern of water delivery covers the required length of crop life cycle in the command area. It was found that the water supply was stopped about 30 days before harvesting in some distributaries and in some about 20-30 days before harvesting. A list of distributaries with greater lags between cessation of water supply and crop harvest was provided to irrigation system engineers to aid their plans for providing a reliable and predictable irrigation service. This is possible either through reorganization of canal operation schedule or through educating farmers about the need for adjusting their agricultural activities to match water supply patterns.