均相催化水合法合成乙二醇动力学研究

在反应温度为45～75℃,NY 健化剂浓度为0.093mol/L,水比为6～10的反应条件下,对均相催化水合法合成乙二醇动力学进行了研究。测定了反应速率常数及反应过程中溶液 pH 值的变化。依据实验结果,提出了反应机理,建立了反应动力学方程,并利用 Levenberg-Marquardt 方法回归了动力学参数。研究结果表明:在 NY 催化剂存在下,均相催化水合法合成乙二醇反应对环氧乙烷浓度是一级反应,其表观活化能为71113.8 J/mol 和指前因子3.05×10~9 min~(-1)。相对直接水合法而言,NY 催化剂降低了反应的活化能,大大提高了反应速度。     

Acrylonitrile-based copolymer membranes containing reactive groups: Surface modification by the immobilization of biomacromolecules

Asymmetric membranes fabricated from poly(acrylonitrile-co-maleic acid) (PANCMA) were immobilized with heparin and/or insulin to improve their surface properties. These biomacromolecule-immobilized PANCMA membranes were prepared by the amination of the membrane surface with ethylenediamine, followed by the reaction of the amino groups with heparin and/or insulin in the presence of 1-ethyl-3-(3-dimethyl amidopropyl) carbodiimide. The surface-modified membranes were analyzed by X-ray photoelectron spectroscopy to confirm the immobilization of the biomacromolecules. Morphological changes on the membrane surface and in the cross section were characterized by scanning electron microscopy. The surface hydrophilicity and hemocompatibility of the studied membranes were evaluated on the basis of water contact angle, platelets adhesion and cell attachment measurements. It was found that, after the immobilization of the biomacromolecules, the water contact angle and the amount of adhered platelets and macrophages on the membrane decreased significantly when compared with the nascent ones, indicating the improvement of surface hydrophilicity. Furthermore, the heparin immobilized membrane showed the best hemocompatibility among the corresponding membranes studied.     

莫莱石－堇青石滤料滤池在生产上的应用

本文对景德镇市黄泥头水厂进行了单层莫－堇滤料滤池和双层莫－堇－煤滤料滤池的生产性试验。试验结果表明：单层莫－堇滤池和双层莫－堇－煤滤池的周期产水量分别是单层砂滤池和双层砂－煤滤池的１．４倍和１．５倍，而且前两种滤池的出水水质优于后两种滤池。     

掺纳米Al2O3的纳米ZrO2(4Y)固体电解质的电性能

以纳米ZrO2(4Y)粉和纳米Al2O3粉为原料, 单轴成型, 1 200, 1 300 ℃无压烧结. 对掺不同质量分数(0.0～5.0%)Al2O3的ZrO2(4Y)烧结体, 用XRD, SEM和TEM研究了相组成和微观结构. 在不同温度下(300～1 000 ℃)测试了交流阻抗谱, 发现掺很少量的纳米Al2O3可降低ZrO2(4Y)的晶粒电阻. 但随着Al2O3掺入量的增加, 晶界电阻增大, 晶粒电阻也有所回升. 晶粒和晶界电导活化能则随Al2O3掺入量的变化不大. 对1 200 ℃,2 h烧结样品, 在1 000 ℃时, 掺0.5% Al2O3的ZrO2(4Y)样品有最大电导率, 为3.8×10-2Ω-1·cm-1.     

云母钛珠光颜料的研制

对钛盐的沉析特性、云母精制、颜料制备进行了探讨。研制出云母－钛珠光颜料，即二氧化钛包覆云母，包覆层明显，珠光效果显著。     

有色金属冶炼烟气SO2的回收治理及其资源化

简要说明了在有色金属冶炼过程中回收元素硫的必要性,介绍了火法冶金工艺中回收硫及其资源化的一些方法,简单讨论了不同方法的优缺点;主张综合利用回收硫资源发展市场需求的硫化工产品。     

Orthogonal and fine lithographic structures attained from the next generation proton beam writing facility

A second generation proton beam writing (PBW) system has been built at the Centre for Ion Beam Applications at the National University of Singapore for fabrication of high aspect ratio 3D nano lithographic structures. System improvements and a few lithographic structures obtained with this facility are presented in this paper. Through accurate alignment of the magnetic quadrupole lenses and the electrostatic scanning system, orthogonal beam scanning has been achieved. The earlier constrain of limited beam scan area has been overcome by adopting a combination of beam and stage scanning as well as stitching. With these improvements smallest ever Ni structure of 65 nm in width has been fabricated using nickel electroplating on a proton beam written PMMA sample in the second generation PBW facility. Using this improved PBW facility, we have also demonstrated the fabrication of fine lithographic patterns with 19 nm line width and 60 nm spacing in 100 nm thick negative high resolution hydrogen silsesquioxane resist. Future possible system improvements leading to finer resolution will be discussed briefly.     

计算机辅助试验研究系统

１９８１年我们研制了可在我校４４１Ｂ－Ⅲ和ＤＰＳ８／４９电子计算机上运行的多变量橡胶配方试验程序（ｔ－ｓ），为了微型计算机普遍使用的形势，根据在生产和科学研究中应用统计方法实际情况，我们改写、扩展，组成了计算机辅助试验研究（ＣＯＭＰＵＥＲＡＩＤＥＤ ＲＥＳＥＡＲＣＨ，简称ＣＡＲ）系统，其主要内容包含正交试验法和回归分析法等，具有实验设计、配方（配合）开发、实验拟合模型等功能，可作多因素试验的定性     

Mechanical properties of hybrid fiber-reinforced concrete at low fiber volume fraction

Concretes containing different types of hybrid fibers at the same volume fraction (0.5%) were compared in terms of compressive, splitting tensile, and flexural properties. Three types of hybrid composites were constructed using fiber combinations of polypropylene (PP) and carbon, carbon and steel, and steel and PP fibers. Test results showed that the fibers, when used in a hybrid form, could result in superior composite performance compared to their individual fiber-reinforced concretes. Among the three types of hybrids, the carbon-steel combination gave concrete of the highest strength and flexural toughness because of the similar modulus and the synergistic interaction between the two reinforcing fibers.