Anodized Aluminum Oxide/Polydimethylsiloxane Hybrid Mold for Roll‐to‐Roll Nanoimprinting

Two types (hard and soft) of the molds are widely used in nanoimprint lithography for a high throughput over a large area, and high‐resolution parallel patterning. Although hard molds have proven excellent resolutions and can be used at high temperatures, cracks often occur in the mold in addition to the requirement of high imprinting pressure. On the other hand, though soft molds can operate at lower pressures, they give poor pattern resolution. Here, a novel hybrid mold of anodized aluminum oxide (AAO) template attached to a flexible polydimethylsiloxane (PDMS) plate is introduced. Due to the flexible nature of PDMS, various polymer nanostructures are obtained on flat and curved substrates without crack formation on the AAO mold surface. Furthermore, the hybrid mold is successfully used for roll‐to‐roll imprinting for the fabrication of high density array of various shaped polymeric nanostructures over a large area.     

Reversible Conversion Reactions and Small First Cycle Irreversible Capacity Loss in Metal Sulfide‐Based Electrodes Enabled by Solid Electrolytes

Solid‐state batteries can potentially enable new classes of electrode materials which are unstable against liquid electrolytes. Here, SnS nanocrystals, synthesized by a wet chemical method, are used to fabricate a Li‐ion electrode, and the electrochemical properties of this electrode are examined in both solid and liquid electrolyte designs. The SnS‐based solid‐state cell delivers a capacity of 629 mAh g^?1 after 100 cycles and exhibits an unprecedentedly small irreversible capacity in the first cycle (8.2%), while the SnS‐based liquid cell shows a rapid capacity decay and large first cycle irreversible capacity (44.6%). Cyclic voltammetry (CV) experiments show significant solid electrolyte interphase (SEI) formation in the liquid cell during the first discharge while SEI formation by electrolyte reduction in the solid‐state cell appears negligible. Along with CV, X‐ray photoelectron spectroscopy and energy dispersive spectroscopy are used to investigate the differences between the solid‐state and liquid cells. The reaction chemistry of SnS in solid‐state cells is also studied in detail by ex situ X‐ray diffraction and X‐ray absorption spectroscopy. The overarching findings are that use of a solid electrolyte suppresses materials degradation and electrolyte reduction which leads to a small first cycle irreversible capacity and stable cycling.     

Investigation of interface traps in LDD pMOST's by the DCIV method

Interface traps in submicron buried-channel LDD pMOSTs, generated under different stress conditions, are investigated by the direct-current current-voltage (DCIV) technique. Two peaks C and D in the DCIV spectrum are found corresponding to interface traps generated in the channel region and in the LDD region respectively. The new DCIV results clarify certain issues of the underlying mechanisms involved on hot-carrier degradation in LDD pMOSTs. Under channel hot-carrier stress conditions, the hot electron injection and electron trapping in the oxide occurs for all stressing gate voltage. However, the electron injection induced interface trap spatial location changes from the LDD region to the channel region when the stressing gate voltage changes from low to high     

Autotuning of phase-lead controller for integrating systems

In this paper, a new method for autotuning of a phase-lead controller for nonselfregulating or integrating systems is proposed. By connecting the system with a suitable high-order derivative filter and a relay with hysteresis, the frequency data of the system can be obtained and phase-lead controllers can be designed based on some phase margin specifications. Simulations and experimental studies are included in the paper to illustrate the performance of the proposed algorithm     

A sensitivity optimization approach to design of a disturbanceobserver in digital motion control systems

This paper is concerned with a digital design methodology for the disturbance observer. The controller (disturbance observer) is designed such that the system sensitivity function is made to match a chosen target sensitivity function by numerical optimization. One advantage of the proposed design method is that the tradeoff between command following, disturbance suppression, and measurement noise rejection is made transparent in the process of the control system design. This allows the system designer to bypass the effort of obtaining a highly accurate system model. Another aim of this research, relative to previous works, is to study how the design specifications can be best structured in the digital filter (a main component of the disturbance observer) for easy implementation. The robust feedback controller, designed in the velocity loop, is used in conjunction with a feedback controller located in the position loop and a feedforward controller acting on the desired output to construct a control structure for high-speed/high-accuracy motion control. Simulation and experiments applied to a high-speed XY table designed for micro positioning demonstrate the effectiveness of the proposed controller     

Wirebond profiles characterized by a modified linkage-spring model which includes a looping speed factor

The linkage-spring model based on a quasi-static looping has been used to determine the design rules to reduce the loop heights and the sagging altitude of gold wire in the package. In order to further simulating the capillary trajectory which includes a looping speed factor from the first bond to the second bond stages, a linkage-spring model is modified in this study. The factors of the inertia mass and variations in material properties with different strain-rates need to be considered due to a high speed looping.It is found that the looping speed effects on the wirebond profiles due to the inertia mass can be neglected at a regular looping process of 3–5g acceleration even up to around 10g acceleration. However, variations in the material properties during deformation at different strain-rates could be an important factor on the wirebond profiles. Fortunately, a pure annealed state like pure gold wire would be little strain-rate sensitivity. The effects of the strain-rate in pure gold wire, therefore, can be excluded in analysis. Accordingly, a linkage-spring model based on the quasi-static looping is still applicable in analyzing the wirebond profiles.     

Excellent Switching Uniformity of Cu-Doped $hbox{MoO}_{x}/hbox{GdO}_{x}$ Bilayer for Nonvolatile Memory Applications

We have investigated a Cu-doped MoO_x/GdO_x bilayer film for nonvolatile memory applications. By adopting an ultrathin GdO_x layer, we obtained excellent device characteristics such as resistance ratio of three orders of magnitude, uniform distribution of set and reset voltages, switching endurance up to 10⁴ cycles, and ten years of data retention at 85degC. By adopting bilayer films of Cu-doped MoO_x/GdO_x, a local filament was formed by a two-step process. Improved memory characteristics can be explained by the formation of nanoscale local filament in the ultrathin GdO_x layer.     

Inertia-based video cut detection and its integration with video coder

An encoder-dependent video cut detection algorithm is proposed. Based on the inertia property of natural videos, the proposed algorithm detects video cuts in the video-coding loop by making use of the intermediate results of video compression. Experiments show that the detection performance of the proposed algorithm is quite good as compared to previous works, and when it is integrated with the coder, not only is the content accessibility of the output code stream improved but also the compression ratio is improved. The authors regard this inertia-based algorithm as a step towards the integration of video compression and content-based video retrieval.     

Highly reliable nitride-based LEDs with SPS+ITO upper contacts

Nitride-based blue light emitting diodes (LEDs) with an n/sup +/-short period superlattice (SPS) tunnel contact layer and an indium tin oxide (ITO) transparent contact were fabricated. Compared with conventional nitride-based LEDs with Ni/Au upper contacts, it was found that we could achieve a 60% increase in electroluminescence (EL) intensity by using ITO upper contacts. However, it was also found that the lifetime of ITO LEDs were much shorter. Furthermore, it was found that we could achieve a longer lifetime and a smaller reverse leakage current (I/sub R/) by the deposition of a SiO/sub 2/ layer on top of the ITO LEDs.