Fabrication of a bimetallic Cu/Pt particle-modified carbon nanotube paste electrode and its use for the electrocatalytic oxidation of methanol

In this work, carbon nanotube paste electrode (CNTPE) was used as a substrate for deposition of bimetallic Cu/Pt particles. At first, a Cu film was prepared by electrochemical reduction of Cu ions onto the CNTPE in 0.1 M H₂SO₄ solution. Cu/Pt catalysts were prepared by partial galvanic replacement of Cu with Pt by simply immersion of the Cu-coated CNTPE in 2.0 mM H₂PtCl₆ solution. The nature and surface morphology of the bare CNTPE and fabricated Cu/Pt species were characterized by scanning electron microscopy and energy dispersive X-ray spectrometry. The Cu/Pt-modified CNTPE exhibits remarkable electrocatalytic activity towards methanol oxidation. It has been shown that carbon nanotubes improve the electrocatalytic activity of the catalysts towards oxidation. Then, the influence of various parameters such as Cu source concentration, electrodeposition time, replacement time, and methanol concentration on its oxidation as well as long-term stability of the modified electrode have been investigated by electrochemical methods.     

Entropy generation in a hollow cylinder with temperature dependent thermal conductivity and internal heat generation with convective–radiative surface cooling

This article investigates entropy generation in an asymmetrically cooled hollow cylinder with temperature dependent thermal conductivity and internal heat generation. The inside surface of the cylinder is cooled by convection on its inside surface while the outside surface experiences simultaneous convective–radiative cooling. The thermal conductivity of the cylinder as well as the internal heat generation within the cylinder are linear functions of temperature, introducing two nonlinearities in the one-dimensional steady state heat conduction equation. A third nonlinearity arises due to radiative heat loss from the outside surface of the cylinder. The nonlinear system is solved analytically using the differential transformation method (DTM) to obtain the temperature distribution which is then used to compute local and total entropy generation rates in the cylinder. The accuracy of DTM is verified by comparing its predictions with the analytical solution for the case of constant thermal conductivity and constant internal heat generation. The local and total entropy generations depend on six dimensionless parameters: heat generation parameter Q, thermal conductivity parameter β, conduction–convection parameters Nc₁ and Nc₂, conduction–radiation parameter Nr, convection sink temperature δ and radiation sink temperature η.     

Convective‐radiative fins with simultaneous variation of thermal conductivity,heat transfer coefficient,and surface emissivity with temperature

This paper is a numerical study of thermal performance of a convective‐radiative fin with simultaneous variation of thermal conductivity, heat transfer coefficient, and surface emissivity with temperature. The convective heat transfer is assumed to be a power function of the local temperature between the fin and the ambient which allows simulation of different convection mechanisms such as natural convection (laminar and turbulent), boiling, etc. The thermal conductivity and the surface emissivity are treated as linear functions of the local temperature between the fin and the ambient which provide a satisfactory representation of the thermal property variations of most fin materials. The thermal performance is governed by seven parameters, namely, convection–conduction parameter Nc, radiation–conduction parameter Nr, thermal conductivity parameter A, emissivity parameter B, the exponent n associated with convective heat transfer coefficient, and the two temperature ratios, θ_a and θ_s, that characterize the temperatures of convection and radiation sinks. The effect of these parameters on the temperature distribution and fin heat transfer rate are illustrated and the results interpreted in physical terms. Compared with the constant properties model, the fin heat transfer rate can be underestimated or overestimated considerably depending on the values of the governing parameters. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20408     

Growth of InAs/InP core-shell nanowires with various pure crystal structures

We have studied the epitaxial growth of an InP shell on various pure InAs core nanowire crystal structures by metal-organic vapor phase epitaxy. The InP shell is grown on wurtzite (WZ), zinc-blende (ZB), and {111}- and {110}-type faceted ZB twin-plane superlattice (TSL) structures by tuning the InP shell growth parameters and controlling the shell thickness. The growth results, particularly on the WZ nanowires, show that homogeneous InP shell growth is promoted at relatively high temperatures (～500?°C), but that the InAs nanowires decompose under the applied conditions. In order to protect the InAs core nanowires from decomposition, a short protective InP segment is first grown axially at lower temperatures (420-460?°C), before commencing the radial growth at a higher temperature. Further studies revealed that the InP radial growth rate is significantly higher on the ZB and TSL nanowires compared to WZ counterparts, and shows a strong anisotropy in polar directions. As a result, thin shells were obtained during low temperature InP growth on ZB structures, while a higher temperature was used to obtain uniform thick shells. In addition, a schematic growth model is suggested to explain the basic processes occurring during the shell growth on the TSL crystal structures.     

Self-assembled nanomicelles using PLGA–PEG amphiphilic block copolymer for insulin delivery: a physicochemical investigation and determination of CMC values

Self-assembled nanomicelles can be used as synthetic biomaterials and colloidal carriers for poorly water-soluble drug delivery systems. Some of these micellar systems have been introduced in clinical trials and showed hopeful results relating to their therapeutic index in patients. Biodegradable nanomicelle was prepared from self-assembling amphiphilic block copolymer composed of poly(dl-lactic-co-glycolic acid) (PLGA) as a core and polyethylene glycol (PEG) as a corona. The PLGA–PEG block copolymer was first synthesized and characterized by FTIR, ¹H NMR, GPC and inherent viscosity measurements. The nanomicelle formed by PLGA–PEG block copolymer in the aqueous solution was characterized by dynamic light scattering, zeta potential, scanning electron microscopy (SEM) and fluorescence excitation and emission spectra of pyrene probe. The critical micelle concentration of obtained nanomicelle was about 0.006 mg/mL, with the size of about 160 nm and the zeta potential of −29 mV. Insulin-loaded PLGA–PEG nanomicelles were prepared by modified dialysis method and the physicochemical parameters of the micelles such as drug content, entrapment efficiency and in vitro drug release were characterized. The results showed that insulin was entrapped into PLGA–PEG nanomicelles with drug loading of 3.9 wt% and entrapment efficiency of 55 wt%. The nanomicelles containing insulin exhibited a controlled release profile. These observations suggested that the PLGA–PEG block copolymers nanomicelles have been prepared by a new synthetic route are potent nanocarrier for poorly water-soluble drugs as insulin.     

Application of Taguchi Method for Characterization of Corrosion Behavior of TiO2 Coating Prepared by Sol‐Gel Dipping Technique

Titanium oxide (TiO₂) nanoparticle coatings were deposited on the 316L stainless steel substrates by sol‐gel method. The morphology, structure, and corrosion resistance of the coating were analyzed using SEM, AFM, X‐ray diffraction, and electrochemical techniques. The deposition parameters employed to realize the anticorrosion performance including calcinations temperature, polyethylene glycol (PEG) content, pH value, and number of dipping cycles were investigated. Taguchi statistical experiments were carried out to determine the influence of the deposition variables on anticorrosion properties and optimal conditions. The results indicated that a higher anticorrosion performance of TiO₂ films could be achieved using 1 g of PEG in a sol with pH in range of 7–9, six cycles of dipping, and calcination temperature at 400°C. The Tafel polarization measurements indicate that i_corr value decreases about 200 times and the R_corr value increases around 57 times compared with uncoated 316L stainless steel.     

A mechanistic analysis of viscous fingering in low-tension polymer flooding in heavy-oil reservoirs

Modeling of the low tension polymer flooding (LTPF) in heavy oil reservoirs suffers from the paucity of detailed knowledge of viscous instability or fingering effects. Major limitations of previous approaches for studying viscous fingering in immiscible displacements are that the reported experiments have been conducted utilizing the linear displacements schemes in the media with high, single-phase permeabilities. Consequently, viscous instability has not been studied in low-permeability media and using the displacement schemes similar to the oil-field patterns (e.g., five-spot). To help understand viscous fingering in LTPF in heavy oil reservoirs and to overcome the limitations of previous studies, we conducted experiments in the low-permeability, one-quarter, five-spot patterns. New insights into the main driving mechanisms for viscous fingering are proposed. In summary, the mechanisms of spreading, splitting, coalescence, and microscopic crossflow drive the finger growth. In addition, the viscous fingers are readily initiated in the porous medium, but they can be damped out before traveling very far. This damping of the viscous fingers is due to the flow of the two phases in a direction transverse to the direction of bulk fluid movement as a result of dispersive processes such as stream splitting. Also, the initially-developed fingers may deteriorate over the time of displacement. This depends on the distance between the injector and producer and width of the porous medium. The presence of instabilities that look like fingers and stable displacements behind the unstable front were discovered. The results also indicate that a stable zone exists and progresses at varying velocities. Finally, we reveal three different types of displacements that occur in LTPF: stable displacements, displacement with macroscopic viscous fingering, and displacements with both macroscopic and microscopic viscous fingering.     

Thermal diffusivity measurement of Au nanofluids of very low concentration by using photoflash technique

In this paper, the application of photoflash technique to measuring the thermal diffusivity of gold nanofluids of very low concentration at room temperature was presented. The nanofluid samples were prepared from the pulse laser ablation procedure. The thermal diffusivity was obtained by fitting the theoretical temperature signal to the experimental data, and it was found to increase linearly from 1.47 × 10⁻³ cm² s⁻¹ to 1.68 × 10⁻³ cm² s⁻¹ as the concentration increased from 1.11 mg/L to 3.18 mg/L. The increase in thermal diffusivity in these multidispersed nanofluids was attributed to the higher nanoparticle concentration as well as to the increasing presence of the smaller size nanoparticles.     

Effect of Y2O3 and Er2O3 co-dopants on phase stabilization of bismuth oxide

Bi₂O₃ compositions were prepared to investigate the effect of rare earth metal oxides as co-dopants on phase stability of bismuth oxide. Compositions containing 9-14 mol% of Y₂O₃ and Er₂O₃ were synthesized by solid state reaction. The structural characterization was carried out using X-ray powder diffraction. The XRD results show that the samples containing 12 and 14 mol% total dopants had cubic structure, whereas the samples with lower dopant concentrations were tetragonal. Comparing the lattice parameters of the cubic phases of (Bi₂O₃)_0.88(Y₂O₃)_0.06(Er₂O₃)_0.06 and (Bi₂O₃)_0.86(Y₂O₃)_0.07(Er₂O₃)_0.07 revealed that lattice parameter decreases by increasing the dopant concentration. The XRD pattern and the powder density results indicated the formation of solid solution in the studied systems. After annealing samples with cubic phase at 600 °C for various periods of time, phase transformation to tetragonal and rhombohedral occurs.     

Characterization of Iranian Virgin Olive Oil from the Roodbar Region: A Study on Zard,Mari and Phishomi

The aim of this study is to describe the physicochemical properties of Iranian virgin olive oil (Zard, Mari and Phishomi) cultivated in Roodbar, Gilan. There were statistically significant differences for most of the parameters (P < 0.05). The acidity and peroxide value were in the limit established for classification as extra virgin olive oil. The oil of Zard had the highest amount of monounsaturated fatty acids followed by Mari and Phishomi oils. Mari oil proved to have the minimum value of polyunsaturated fatty acids, and the highest amount of phenolic compounds and oxidative stability. The oil of Phishomi had the maximum amount of chlorophylls and carotenoids and therefore it had the highest color index. There were no significant differences between the cultivars regarding the refractive index (1.469 at 20 °C for all three cultivars). According to the high content of monounsaturated fatty acids, the lowest amounts of polyunsaturated fatty acids and the highest amounts of phenolic compounds as well as the results of a Rancimat assay, it seems that the quality of the oil of Mari cultivar is better than Zard and Phishomi oils and is also more stable against oxidation.