Synthesis and room temperature coating of nano ZrB2 on copper using mechanical roll-milling

In this study, ZrB₂ was prepared from ZrOCl₂.8H₂O, H₃BO₃ and citric acid by using the gel method. The gel was dried at 400 °C and then it was calcined at 1500 °C. The prepared 0.5–1 μm ZrB₂ powder was encapsulated into the Cu tube. For the purpose of coating ZrB₂ on Cu metal, the roll-milling of ZrB₂ particles inside the cylindrical Cu tube has been performed at room temperature. The prepared ZrB₂ coating on Cu was analyzed by using FE-SEM, EDS, XRD, electrical resistivity and CV measurements. The final ZrB₂ particle size on the surface of the coating layer was below 100 nm, and the coating thicknesses were about 15–20 μm. The long nanofiber like ZrB₂ structures was observed. The coating of nano ZrB₂ on Cu was achieved by using this novel roll-milling process which is an environmental friendly, low cost and practical technique.     

Block-based fuzzy-image authentication method

Abstract

Fragile watermarking methods have been widely used for image authentication. A novel image-authentication method based on fuzzy coding is presented in this work. This method is a block-based method and it consists of watermark generation, watermark embedding, watermark extraction, tamper detection, and image recovery phases. First, the cover image is divided into nonoverlapping blocks. In the watermark-generation step, fuzzy sets and fuzzy coding are used. To generate fuzzy sets, three threshold points are selected from a histogram of the cover image and fuzzy sets are created by using these threshold points. Memberships of pixels are calculated to generate features. Fuzzy coding is used to generate the watermark. The watermark-embedding function uses ±1 data hiding function for each block. Therefore, high visual quality is achieved. The generated watermark is compared with the extracted watermark in the tamper-detection phase. Finally, a new image-recovery algorithm is proposed for recovering tampered areas. To evaluate the proposed method, visual quality, tamper detection ability, image recovery capability, and computational complexity were used. The experimental results clearly indicated that the proposed method was a success.     

Effectiveness of Scrap Tire Chips as Sorptive Drainage Material

Scrap tire disposal is a problem of growing concern. One solution to this problem is innovative methods for the reuse and recycling of scrap tires. Based on batch isotherm tests, scrap tire chips have been identified to be good sorbents of volatile organic compounds (VOCs) and could be used as leachate drainage layer material in solid waste landfills and in other similar applications. To demonstrate the effects of tire chips on the leachate they come in contact with in a drainage layer over a liner, large-scale tank tests simulating the drainage layer and the clay liner and also field tests were performed. Two cells were constructed in a landfill: one with scrap tire chips and the other with gravel leachate collection layer. According to the results of the large-scale tank tests and field tests, shredded tire chips have a significantly positive impact on the quality of the leachate with which they come in contact. The use of scrap tires in landfills would reduce the magnitude of the current tire disposal problem (a 1 ha landfill requires approximately 300,000 tires to fill 0.3 m of a leachate collection layer) and convert one waste into a beneficial construction material and simultaneously mitigate the problem of VOC transport from through landfill liners.     

Oil recovery from lime‐treated wastewater of olive mills

Olive mill wastewater is a by‐product of olive oil production and generates a major environmental problem in the Mediterranean area. The amount of oil and grease, which is one of the parameters used for the characterization of this wastewater, cannot be determined easily using a standard method. Therefore some modifications of the standard method were investigated in this study. To this end wastewater was first treated with lime, without using diatomaceous‐silica, then acidified, filtered through muslin cloth only, and finally extracted with an organic solvent. However, the results obtained by the modified method didn't differ significantly from those obtained by the standard method. Furthermore some tests were conducted to recover the remaining oil, which may be economically important, in these waste products. The oil could be recovered in the range of 70.6 to 96.4% if the wastewater was treated with lime while air was passed through the mixture, filtered using a muslin cloth disk, dried, and extracted with an organic solvent.     

Effect of some selective aromatic cosolutes on the main thermodynamic parameters of aqueous poly(n‐vinyl‐2‐pyrrolidone) solutions

Cloud‐point curves and theta temperatures have been determined for aqueous solutions of poly(N‐vinyl‐2‐pyrrolidone) at several concentrations for a variety of aromatic additives (benzoic acid, o‐ and p‐hydroxy benzoic acid, aniline, o‐ and p‐hydroxy aniline). The theta temperature of polymer is suppressed at lower temperatures depending on the chemical structure and the concentration of additives. The effectiveness, in decreasing order, of the cosolutes in reducing the temperature is: p‐hydroxy benzoic acid > o‐hydroxy benzoic acid > p‐hydroxy aniline > o‐hydroxy aniline ≈ benzoic acid > aniline. It is understood that changes in theta temperatures caused by the cosolute result from the changes taking place in the hydrophilic and hydrophobic interactions among polymer, solvent and polymer–solvent interactions from the added cosolute. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 507–510, 2000     

The effect of Er:YAG laser and bulk filled composite type on marginal adaptation of class II cavities: an SEM analysis study

Purpose: To evaluate the effect of cavity preparation method (Er:YAG laser or diamond bur) and bulk-filled composite material type on marginal adaptation mesial occlusal (MO) class II cavities. Materials and Methods: Two-surface box cavities (4-mm proximal depth and 5-mm occlusal width) were prepared on 60 human mandibular molar teeth. Cavities were prepared using Er:YAG laser or diamond burs in an air-turbine hand-piece. All cavities were applied Single Bond Universal dentin bonding agent. The cavities were further subdivided into three subgroups according to the restorative material used; two bulk-filled composites [Filtek Bulk Fill Posterior (3M ESPE) and SonicFill 2 (Kerr)] and one traditional composite material Filtek Ultimate Universal Restorative (3M ESPE). Restorations were evaluated using scanning electron microscopy at ×200 magnification for their adaptation to the approximal margins of the tooth. Results were analyzed using the two-way ANOVA and Tukey Post Hoc Test (p < 0.05). Results: A total of 900 SEM figures were obtained from all groups. Filtek Bulk Fill Posterior, SonicFill 2, and Filtek Ultimate Universal Restorative exhibited statistically similar gapped margins. However, the lowest scores of gapped margins were observed with SonicFill 2 (4.22%). Conclusions: Completely gap-free margins were not obtained with any of the tested materials. Bulk-fill composite materials showed similar marginal adapatation compared with standard composite. Marginal adaptation of Er:YAG laser prepared cavities was more irregular and had more gaps, but was statistically similar to diamond bur-prepared cavities.     

Sorption of boron by invasive marine seaweed: Caulerpa racemosa var. cylindracea

The sorption of boron from aqueous solution onto Caulerpa racemosa var. cylindracea (CRC), collected from Seferihisar/Izmir region in Turkey, was investigated as a function of pH, temperature, initial boron concentration, adsorbent dosage, contact time and ionic strength. Optimum conditions for the sorption of boron were obtained at pH 7.5, 318 K, 8 mg L⁻¹ initial boron concentration, 0.2 g of CRC, 2.5 h contact time and greater ionic strength (10⁻¹ M NaCl). As the temperature was increased the boron removal took place with higher percentages. In experiments conducted at optimum conditions, maximum boron sorption was determined to be about 63%. The experimental data were analyzed by Freundlich, Langmuir and Dubinin–Radusckevich (DR) equations. Freundlich and DR models provide best conformity with the experimental data. In order to describe kinetics of boron sorption onto CRC, first-order Lagergren equation, pseudo-second-order kinetic model and intraparticle diffusion model were used. It was seen that the first order Lagergren equation was better described than the pseudo-second-order kinetic model. Thermodynamic parameters of sorption process were also calculated. It was obtained that sorption process was not spontaneous. The characterization of CRC was carried out by Fourier transform infrared spectroscopy (FTIR) analysis.     

Effect of an Er,Cr:YSGG laser preparation on dentin bond strength of a universal adhesive

The aim of this study was to evaluate the bond strength of a universal adhesive system to dentin prepared with SiC paper or an Er,Cr:YSGG laser using different bonding strategies (etch-and-rinse versus self-etch mode). Ninety-six extracted caries-free, sound human molars were used. The teeth were longitudinally sectioned in the mesiodistal direction and were wet polished with 600-grit SiC paper to obtain a standardized flat dentin surface. All prepared teeth were randomly divided into two groups, according to the surface preparation method: GroupI:an erbium, chromium:yttrium,scandium, gallium, garnet laser; Group II: silicon carbide paper[SiC] (n = 48). Each group was then assigned into three subgroups according to the universal adhesive’s (Single Bond Universal) bonding strategies: (a) etch-and-rinse mode with phosphoric acid, (b) etch-and-rinse mode with a laser, (c) self-etch mode (n = 16). For surface preparation, the Er,Cr:YSGG laser was used at 3 W, 30 Hz with 140 μs pulse duration for 25 s. For etching mode, the laser was used at 1.5 W (60% air, 70% water). Cylinders of composite were fabricated on the bonding area and shear bond strength was determined using a universal testing machine. Failure modes were evaluated using a stereomicroscope. The data were analyzed using two-way ANOVA followed by the Bonferroni test (p < 0.05). Bonding strategies showed statistically significant differences in both the SiC-and laser-prepared groups (p < 0.05).Universal adhesive used in etch-and-rinse mode with acid showed significantly higher bond strength values than in self-etch mode (p < 0.05). The bond strength values did not differ according to the surface preparation method (p > 0.05). Irrespective of preparation method, using universal adhesive in etch-and-rinse mode with acid might improve dentin bond strength. Laser preparation did not affect the bond strength of the universal adhesive tested.     

The effects of anhydride type and amount on viscosity and film properties of alkyd resin

In this study, a modified method for preparing low viscosity alkyd resin was suggested. For this purpose the preparation of sunflower oil-based alkyd resins were achieved into two steps. First sunflower oil and glycerol were reacted to form partial glycerides, and then, after removing free glycerol, esterification reaction was achieved between partial glycerides and anhydride. Glutaric, maleic, phthalic and succinic anhydride were used. Sunflower oil alkyd resins were also prepared by classical method. The results obtained were compared with each other. By the modified method low viscosity and good film properties resins could be prepared.