Thermal fracture analysis of orthotropic functionally graded materials using an equivalent domain integral approach

A new computational method based on the equivalent domain integral (EDI) is developed for mode I fracture analysis of orthotropic functionally graded materials (FGMs) subjected to thermal stresses. By using the constitutive relations of plane orthotropic thermoelasticity, generalized definition of the J-integral is converted to an equivalent domain integral to calculate the thermal stress intensity factor. In the formulation of the EDI approach, all the required thermomechanical properties are assumed to have continuous spatial variations through the functionally graded medium. Developed methodology is integrated into a fracture mechanics research finite element code FRAC2D using graded finite elements that possess cubic interpolation. Steady-state and transient temperature distribution profiles in orthotropic FGMs are computed using the finite elements based heat transfer analysis software HEAT2D. EDI method is validated and domain independence is demonstrated by comparing the numerical results obtained using EDI to those calculated by an enriched finite element method and to those available in the literature. Single and periodic edge crack problems in orthotropic FGMs are examined in order to study the influences of principal thermal expansion coefficient and thermal conductivity components, relative crack length and crack periodicity on the thermal stress intensity factors. Numerical results show that among the three principal thermal expansion coefficient components, the in-plane component perpendicular to the crack axis has the most significant influence on the mode I stress intensity factor. Gradation profile of the thermal expansion coefficient parallel to the crack axis is shown to have no effect on the outcome of the fracture analysis.     

Synthesis of Quaternary,Long-Chain N-Alkyl Amides and Their Corrosion Inhibition in Acidic Media

New cationic surfactants were synthesized by the quaternization of a number of straight-chain amide derivatives with triethylamine or pyridine. The corrosion inhibition tests of the surface-active compounds were performed at room temperature for 24 h on carbon steel coupons in acidic media using the gravimetric method. The acidic media used were 1.5 M HCl and 1.5 M H₂SO₄. Almost all of the synthesized cationic surfactants showed efficient inhibition of corrosion in the test. To establish the inhibition efficiencies of the inhibitors, surface characterization studies (contact angle measurements, SEM analysis and optical profilometer images) of the metal coupons used were performed.     

Determination of the quality and purity characteristics of olive oils obtained from different regions of Turkey,depending on climatic changes

Virgin olive oils (VOOs) obtained from olives grown in different regions of Turkey under changing climatic conditions sometimes show different sensory and chemical properties. This study was planned to determine whether these deviations are due to climatic changes or not. For this purpose, five different olive varieties (Ayvalık, Memecik, Gemlik, Nizip Yağlık, Kilis Yağlık) of commercial importance were harvested from the provinces/districts (four different region) where cultivation is intense during the 2017/2018–2020/2021 harvest years. Every year, olive samples were collected from 3 orchards from 13 provinces/districts. One hundred and fifty-six samples were subjected to the purity, quality and sensory analysis. Basic climatic values (average, minimum and maximum temperature, humidity and precipitation) were examined for four consecutive years. All of the examined olive oil samples were determined within the legal limits in terms of fatty acid composition and fatty acid ethyl ester values. However, delta-7-stigmastenol value from the sterol composition was found to be above 0.5% in some samples in all the years studied (total 21 samples). Delta-7-stigmastenol values of olive oil samples varied between 0.16% and 1.14%. Multiple linear regression analysis was applied using a genetic algorithm-based inverse least squares method to determine whether there is a relationship between climate data and delta-7-stigmastenol values. According to this result, it has been determined that the delta-7-stigmastenol value is high when the annual average relative humidity is low and the annual average temperature is high. There is an urgent need to make forward-looking plans due to climate change.     

New current–mode special function continuous-time active filters employing only OTAs and OPAMPs

This paper reports three current mode second order filters, each of which realizes a specific function without any external passive elements. These filters realize low-pass notch (LPN), high-pass notch (HPN) and all-pass (AP) functions. Two OPAMPs, a double output OTA and a single output OTA are employed for each circuit. The filter structures can be easily cascaded since they have high output impedances. This property is especially useful for achieving high-order filters using these LPN and HPN filters as building blocks. The presented theory is verified with macro models in SPICE simulations and, using the SPICE parameters of the layout technology, post layout simulations are carried out, with parasitics extracted from the layouts of the filter chips.     

Physical and mechanical properties of Gokceada: Imbros (NE Aegean Sea) Island andesites

The physical and mechanical properties of the andesite forming much of the island of Gökçeada (Imbros), Turkey, were investigated using 54 mm samples cores from 12 blocks obtained from a quarry. The results were evaluated using regression analysis and good empirical relationships were obtained.     

A highly selective and sensitive benzothiazole‐based ‘turn‐on’ fluorescent sensor for Hg2+ ion

A simple benzothiazole‐based fluorescent probe (TDA) for the determination of Hg²⁺ ion in aqueous solutions was synthesised in one step and characterised by ¹H NMR, ¹³C NMR, APT, COSY, FTIR, and elemental analysis. TDA shows a significant fluorescence change upon the interaction of Hg²⁺ ion in DMF–water (v/v = 1/1), while only minor changes in fluorescence intensity are observed with 18 other metal ions. Fluorescence enhancement by a factor of 15 is achieved upon selective interaction with Hg²⁺ ion. The Hg²⁺ ion detection process is found to be pH dependent; therefore, TDA could be feasible within a pH range of 4.0–7.0.