The effect of compaction temperature and pressure on the pores in nanostructured metal compacts prepared by magnetic pulsed compaction

The pore behavior of nano Al compacts prepared by magnetic pulsed compaction in a temperature range from 20°C to 300°C and under pressure of 0.7 and 1.6 GPa was studied by small angle neutron scattering (SANS) analysis. The size distribution and volume fraction of pores in the compact were determined by corrected scattering curves using a direct model fitting, under the assumption that the pores were spherical in shape. The densities obtained from the SANS analysis were well matched with those of direct measurement in the range of 76–95% of theoretical density. As the compaction temperature increased from 20°C to 300°C, the size of pores increased from 1.69 to 2.31 nm; however, the number of pores decreased from 169 to 71 (1/cmŲ) in the case of 1.6 GPa compaction pressure. As a result, the density increased as the compaction temperature increased.     

Interfacial reaction in ASZ/A384 Al composite and its influence on mechanical properties

In an ASZ/A384 Al composite, the interfacial reaction was observed to take place between the SiO₂ binder layer and Mg within the matrix to form MgAl₂O₄ at the interface. Formation of MgAl₂O₄ at the interface between ASZ short fibers and the Al matrix alloy is believed to enhance the interfacial bonding strength, resulting in improved composite strength. However, the interfacial reaction in the ASZ/A384 Al proceeds at the expense of Mg in the matrix, resulting in a composite devoid of Mg bearing precipitates such as Al₂CuMg and Mg₂Si.     

Separation of oxide inclusions from liquid metal in an applied electrostatic field

It is known that oxide inclusions in liquid metal carry mostly positive charges on their surfaces. In an electrostatic field, therefore, such charged particles suspended in a liquid metal experience forces and accumulate in the region of the negatively charged surface, resulting in the separation of oxide inclusions from the liquid metal. In this study, this principle was experimentally demonstrated for the case of a capacitor cell by the imposition of a d.c. potential on electrodes. The capacitor cell consisted of a dielectric container of Pyrex tube, a high voltage d.c. source, and two electrodes, which were symmetrically attached onto the outer surface of the Pyrex. tube. Experiments were carried out for suspensions of liquid tin/metal oxides, such as SnO₂, WO₃, and PbO under an applied potential of up to 12 kV. All experimental results were in good agreement with the theoretical prediction and showed that the degree of separation was significantly increased with the applied potential.     

Workpiece surface modification using electrical discharge machining

Electrical discharge machining (EDM) is a widely used process in the mould / die and aerospace industries. Following a brief summary of the process, the paper reviews published work on the deliberate surface alloying of various workpiece materials using EDM. Details are given of operations involving powder metallurgy (PM) tool electrodes and the use of powders suspended in the dielectric fluid, typically aluminium, nickel, titanium, etc. Following this, experimental results are presented on the surface alloying of AISI H13 hot work tool steel during a die sink operation using partially sintered WC / Co electrodes operating in a hydrocarbon oil dielectric. An L8 fractional factorial Taguchi experiment was used to identify the effect of key operating factors on output measures (electrode wear, workpiece surface hardness, etc.). With respect to microhardness, the percentage contribution ratios (PCR) for peak current, electrode polarity and pulse on time were ˜24, 20 and 19%, respectively. Typically, changes in surface metallurgy were measured up to a depth of ˜30 μm (with a higher than normal voltage of ˜270 V) and an increase in the surface hardness of the recast layer from ˜620 HK_0.025 up to ˜1350 HK_0.025.     

The form error prediction in side wall machining considering tool deflection

In this research, an effective method for the form error prediction in side wall machining with a flat end mill is suggested. The form error is predicted directly from the tool deflection without surface generation by cutting edge locus with time simulation. The developed model can predict the surface form error accurately about 300 times faster than the previous method. Cutting forces and tool deflection are calculated considering tool geometry, tool setting error and machine tool stiffness. The characteristics and the difference of generated surface shape in up milling and down milling are discussed. The usefulness of the presented method is verified from a set of experiments under various cutting conditions generally used in die and mold manufacturing. This study contributes to real time surface shape estimation and cutting process planning for the improvement of form accuracy.     

Optimization of a roller levelling process for Al7001T9 pipes with finite element analysis and Taguchi method

This paper is concerned with the optimization of process parameters for a roller leveller that is an indispensable piece of equipment to eliminate the undesirable curvature of a thin-walled aluminum pipe. Optimization of process parameters has been carried out for a multi-staggered-type 14-roller leveller. A finite element model of a multi-staggered 14-roller leveller was constructed for numerical analysis. The analysis is carried out with the fractional model and the Taguchi method for evaluation of the effect of process parameters such as the intermesh and the slanted angle of rollers. The response variable is set to the plastic strain along the pipe length. The optimum combination of process parameters is determined from the numerical result and confirmed by experiments. The comparison of the numerical result with the experimental one shows good coincidence for its validity and reliability.     

Effect of aging treatment on the mechanical properties of C-250 maraging steel by flow forming

The technique of forward flow forming has been used to produce a long, thin walled tube made of C-250 maraging steel. The forward flow forming can save raw material, increase strength, and reduce the production process time. Because the work hardening effect on solution-treated C-250 using flow forming is minimal, the flow-formed tube requires an additional heat treatment to obtain higher hardness and strength. With the direct aging treatment, low elongation values are obtained, making this treatment unsuitable for the engineering design. It was found that the 540 °C/6 h/AC over-aging treatment results in better strength and elongation values. The strengthening phase of the flow-formed C-250 maraging steel was found to be the intermetallic compound of Fe₃Mo.     

Epitaxially Strained CeO2/Mn3O4 Nanocrystals as an Enhanced Antioxidant for Radioprotection

Nanomaterials with antioxidant properties are promising for treating reactive oxygen species (ROS)-related diseases. However, maintaining efficacy at low doses to minimize toxicity is a critical for clinical applications. Tuning the surface strain of metallic nanoparticles can enhance catalytic reactivity, which has rarely been demonstrated in metal oxide nanomaterials. Here, it is shown that inducing surface strains of CeO₂/Mn₃O₄ nanocrystals produces highly catalytic antioxidants that can protect tissue-resident stem cells from irradiation-induced ROS damage. Manganese ions deposited on the surface of cerium oxide (CeO₂) nanocrystals form strained layers of manganese oxide (Mn₃O₄) islands, increasing the number of oxygen vacancies. CeO₂/Mn₃O₄ nanocrystals show better catalytic activity than CeO₂ or Mn₃O₄ alone and can protect the regenerative capabilities of intestinal stem cells in an organoid model after a lethal dose of irradiation. A small amount of the nanocrystals prevents acute radiation syndrome and increases the survival rate of mice treated with a lethal dose of total body irradiation.     

Phosphonium Modification Leads to Ultrapermeable Antibacterial Polyamide Composite Membranes with Unreduced Thickness

Water transport rate in network membranes is inversely correlated to thickness, thus superior permeance is achievable with ultrathin membranes prepared by complicated methods circumventing nanofilm weakness and defects. Conferring ultrahigh permeance to easily prepared thicker membranes remains challenging. Here, a tetrakis(hydroxymethyl) phosphonium chloride (THPC) monomer is discovered that enables straightforward modification of polyamide composite membranes. Water permeance of the modified membrane is ≈6 times improved, give rising to permeability (permeance × thickness) one magnitude higher than state-of-the-art polymer nanofiltration membranes. Meanwhile, the membrane exhibits good rejection (R_Na2SO4 = 98%) and antibacterial properties under crossflow conditions. THPC modification not only improves membrane hydrophilicity, but also creates additional angstrom-scale channels in polyamide membranes for unimpeded transport of water. This unique mechanism provides a paradigm shift in facile preparation of ultrapermeable membranes with unreduced thickness for clean water and desalination.