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51.
Rheological characteristics of two pretreated petroleum pitches, during their transformation to mesophase, have been studied
by using rotalional viscometer. Simultaneously, the formation, growth, coalescence of mesuphase spheres, and the alignment
of coalesced mesophase were observed by Hot-Stage-Cinema-Microscope, discussed with the results of viscosity change and the
Q.I. content. It is found that both pretreated pitches were Newtonian fluids at low temperature, but behaved pseudoplastics
as increase of mesophase content above 390C. Shear thinning behaviour was also apparent in the shear rate range of 1.9–20
sec−1 at temperature above 390C. The apparent viscosity-temperature curves of this pyrolysed pitches were much affected by the
pretreatment conditions. 相似文献
52.
Chlorinated isotactic polypropylenes (CPP) having various chlorine contents were blended with poly(ethylene-co-vinyl acetate)s (EVA) having various vinyl acetate (VA) contents. The blends were made by casting films from dilute THF solutions and miscibility of the blends was identified by single glass transition temperature, which was confirmed by DSC and dynamic mechanical measurements. Based on the miscibility data from a large number of CPP/EVA combinations, a miscibility map was depicted where CO equivalent weight (CO-EQW) of EVA was plotted against chlorine equivalent weight (Cl-EQW) of CPP. Though an attractive interaction between CPP and EVA could be detected in all the miscible and immiscible blend pairs, miscibility of the CPP/EVA blends could solely be observed in a relatively narrow range of Cl-EQW ca. 65–100 and CO-EQW ca. 170–230. 相似文献
53.
Seung Bum Kil Yannick Augros Yves Leterrier Jan‐Anders E. Mnson Andreas Christel Camille Borer 《Polymer Engineering and Science》2003,43(2):329-343
The rheological properties in solution, in shear and in uniaxial elongation of poly(ethylene terephthalate) (PET) reacted together with hyperbranched polymers (HBPs) were investigated. Two different PET grades, of low and high molecular weights, were compounded with sub‐ to over‐stoichiometric concentrations of HBPs of second and fourth pseudo‐generation, and subsequently subjected to a solid‐state polycondensation (SSP). The formation of microgels, which occurs at high HBP concentration, gave rise to a large increase in melt elasticity and a related decrease in melt strength. At low HBP concentrations, the complex viscosity of the unreacted HBP/PET was considerably reduced, thus demonstrating a lubrication effect of the HBP molecules. During SSP, the intrinsic and shear viscosities exhibited a gradual increase, which was similar for both PET and HBP/PET blends, and was correlated to an increase in molecular weight, through linear‐chain extension and branching reactions. The elongational viscosity of the reactive blends was also increased as a function of reaction time, and this increase was much larger in the case of the HBP/PET blends. A 400% increase in melt strength of the PET was obtained by combining SSP and trace amounts of an HBP of second generation, without any decrease in drawability. 相似文献
54.
To synthesize new functional poly(urethane‐imide) crosslinked networks, soluble polyimide from 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride, 4,4′‐oxydianiline, and maleic anhydride and polyurethane prepolymer from polycaprolactone diol, tolylene 2,4‐diisocyanate and hydroxyl ethyl acrylate were prepared. Poly(urethane‐imide) thin films were finally prepared by the reaction between maleimide end‐capped soluble polyimide (PI) and acrylate end‐capped polyurethane (PU). The effect of polyurethane content on dielectric constant, residual stress, morphology, thermal property, and mechanical property was studied by FTIR, prism coupler, Thin Film Stress Analyzer (TFSA), XRD, TGA, DMTA, and Nano‐indentation. Dielectric constant of poly(urethane‐imide) thin films (2.39–2.45) was lower than that of pure polyimide (2.46). Especially, poly(urethane‐imide) thin films with 50% of PU showed lower dielectric constant than other poly(urethane‐imide) thin films did. Lower residual stress and slope in cooling curve were achieved in higher PU content. Compared to typical polyurethane, poly(urethane‐imide) thin films exhibited better thermal stability due to the presence of the imide groups. The glass transition temperature, modulus, and hardness decreased with increase in the flexible PU content even though elongation and thermal expansion coefficient increased. Finally, poly(urethane‐imide) thin films with low residual stress and dielectric constant, which are strongly affected by the morphological structure, chain mobility, and modulus, can be suggested to apply for electronic devices by variation of PU. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 113–123, 2006 相似文献
55.
Yong?Rae?Chae Yeo?Joon?Yoon Keun?Garp?RyuEmail author 《Korean Journal of Chemical Engineering》2004,21(5):999-1002
Expanded bed behavior was modeled by using the Richardson-Zaki correlation between the superficial velocity of the feed stream and the void fraction of the bed. A polydisperse material, Chelating excellose® (70-210 Μm in diameter, 1.21 g/cm3 in density), which has Ni2+ ions for the selective binding of histidine-tagged proteins, was used as the resin. A method to modify the Stokes expression to express the terminal settling velocity of the resins by introducing two empirical parameters, the effective diameter of the resins and an exponent for(ρ p -ρ)/Μ term, was developed. Combined use of the Richardson-Zaki correlation and the modified Stokes expression was successful in modeling the bed expansion by incorporating physical properties of feed streams and the resins. 相似文献
56.
Solid extraction of caffeine and theophylline from green tea by molecular imprinted polymers 总被引:1,自引:0,他引:1
Dexian?Wang Seung?Pyo?Hong Kyung?Ho?RowEmail author 《Korean Journal of Chemical Engineering》2004,21(4):853-857
This paper involves a feasibility study on using molecular imprinted polymers as the sorbent materials in solid phase extraction
for caffeine and theophylline from green tea. Two kinds of MIPs, with caffeine-theophylline mixture and pentoxifylline-theophylline
mixture as the templates respectively, MAA as the monomer, EDMA as the crosslinker and ATBN as the initiator, were applied
to this purpose. Mixture solution of caffeine and theophylline (1 Μg/ ml in acetonitrile) was applied to the solid extraction
cartridges following a load, wash and elute procedure with acetonitrile, methanol, methanol-acetic acid (90/10, v/v) as the
solvents, respectively. This solid phase extraction protocol was applied for extraction of caffeine and theophylline from
green tea. Comparison between the results obtained with the MIPs cartridges and a traditional C18 reversed-phase cartridge was made. It showed that the MIP-based sorbent on the solid phase extraction was comparable with
that of C18 material. HPLC analysis using a C18 column (5 Μm, 250× 4.6 mm from Rstech corporation), methanol: water (60 :40, v/v) as the mobile phase at a flow rate of 0.6
ml/min was applied for the quantitative determination. 相似文献
57.
Yong?An?Jung Du?Young?Choi Seung?Bum?Hong Kyung?Ho?RowEmail author 《Korean Journal of Chemical Engineering》2003,20(4):705-708
Reversed-phase high-performance liquid chromatography was successfully developed for the simultaneous and rapid separation for the main whey proteins, α-Lactalbumin and β-Lactoglobulin. This method consisted of a linear gradient of the two mobile phases of 0.1% trifluoroacetic acid in water and 0.1% trifluoroacetic acid in acetonitrile. The total run time for this separation was approximately 30 min, and α-Lactalbumin was eluted followed byβ- Lactoglobulin. The injection volume was fixed at 20 μl and the flow rate was 1 ml 1/min. The optimum mobile phase composition and gradient conditions to separate α-Lactalbumin and β-Lactoglobulin (A+B) were experimentally obtained at the 15 μm particle with a pore size of 300 Å on the linear-gradient mode. 相似文献
58.
Jun-Bin Ko Sung Wook Lee Dong Eun Kim Young Un Kim Gang Li Seung Goo Lee Tae-Sun Chang Dojin Kim Yong Lak Joo 《Journal of Porous Materials》2006,13(3):325-330
(1 − x)SiO2-(x)ZrO2 (x = 0.1, 0.2) composite fiber mats were prepared by electrospinning their sol-gel precursors of zirconium acetate and tetraethyl
orthosilicate (TEOS) without using a polymer binder. The electrospun composite fibers were characterized by powder X-ray diffraction
(XRD), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FT-IR) and mercury porosimetry. The composite
fibers having a tetragonal crystalline ZrO2 were obtained by calcining the electrospun composite fibers at high temperatures. The results show that the structure and
crystallization of ZrO2 in the composite fibers can be controlled by sintering temperature, while the porosity and morphology of the fiber mats did
not depend on the sintering temperature. 相似文献
59.
Yeong-Koo Yeo Jong Ho Park See-Han Park Changman Sohn 《Korean Journal of Chemical Engineering》2005,22(3):339-344
In this work, the Model Algorithmic Control (MAC) method is applied to control the grade change operations in paper mills.
The neural network model for the grade change operations is identified first and the impulse model is extracted from the neural
network model. Results of simulations for MAC control of grade change operations are compared with plant operation data. The
major contribution of the present work is the application of MAC in the industrial plants based on the identification of neural
network models. We can confirm that the proposed MAC method exhibits faster responses and less oscillatory behavior compared
to the plant operation data in the grade change operations. 相似文献
60.
In order to demonstrate the effectiveness of the process identification algorithm, on-line parameter estimator is evaluated
experimentally by using two-tank system with interaction. On-line parameter estimator used in this paper is based on a recursive
parameter estimation algorithm. MIMO linear, bilinear and quadratic models based on ARMA model are used to identify two-tank
system. A quadratic model for two-tank system with interaction is developed to confirm the propriety of MIMO quadratic model
used in identification of two-tank system. The results of on-line identification experiments on the two-tank system show that
the estimated parameters of each model converge and the output tracking errors are bounded by disturbance bound. But, the
quadratic model showed the best convergence. 相似文献