Efficient multi-millijoule THz wave generation from laser interactions with a cylindrical GaAs waveguide

This study involved a comprehensive investigation aimed at achieving efficient multi-millijoule THz wave generation by exploiting the unique properties of cylindrical GaAs waveguides as effective mediators of the conversion of laser energy into THz waves. Through meticulous investigation, valuable insights into optimizing THz generation processes for practical applications were unearthed. By investigating Hertz potentials, an eigenvalue equation for the solutions of the guided modes （i.e., eigenvalues） was found. The effects of various parameters, including the effective mode index and the laser pulse power, on the electric field components of THz radiation, including the fundamental TE （transverse electric） and TM （transverse magnetic） modes, were evaluated. By analyzing these factors, this research elucidated the nuanced mechanisms governing THz wave generation within cylindrical GaAs waveguides, paving the way for refined methodologies and enhanced efficiency. The significance of cylindrical GaAs waveguides extends beyond their roles as mere facilitators of THz generation; their design and fabrication hold the key to unlocking the potential for compact and portable THz systems. This transformative capability not only amplifies the efficiency of THz generation but also broadens the horizons of practical applications.     

The use of biomass and stillage recycle in conventional ethanol fermentation

Modifications of the conventional ethanol fermentation process using biomass and stillage recycle were investigated and the advantages of the technique were studied. The biomass recycle method resulted in a reduction in the use of approximately 8% raw material (molasses). The recycle of 15–70% of stillage (dealcoholised) from a previous fermentation was also tested successfully. Generally the results of these experiments revealed 13–47% less water consumption and consequently about 13–47% reduction of stillage volume, which was more economical for further treatments.     

The glass transition temperature of nitrated polystyrene/poly(acrylic acid) blends

Low-molecular-weight polystyrene was nitrated to different levels. The nitrated polystyrene was blended with different molecular weights of poly(acrylic acid), PAA. The glass transition temperatures (T_g) for the mixtures were investigated by differential scanning calorimetry. A single T_g was observed for all blends, indicating single-phase blends. In general, it was found that the T_g increases with molecular weight of PAA. The T_g values of the blends showed a positive deviation from the linear average T_g as a result of strong hydrogen bonding between the segments of the component polymers. The observed T_g values were not adequately represented by simple predictive equations or by single-parameter fitting equations. However, two-parameter fitting equations gave a reasonable representation of the data.     

MRI and PET image fusion using structure tensor and dual ripplet-II transform

Multimedia Tools and Applications - Medical image fusion aims at preserving salient image features, reducing the redundancy, and increasing the interpretation quality of images in clinical...     

Fucoxanthin content and antioxidant properties of Undaria pinnatifida

This study investigated the fucoxanthin content of New Zealand (NZ) Undaria pinnatifida harvested from two locations in the Marlborough Sounds, New Zealand across its growing season. Fucoxanthin content and antioxidant properties of processed New Zealand U. pinnatifida and commercial wakame from Japan and Korea were further compared. Results showed that U. pinnatifida harvested from Port Underwood had higher fucoxanthin content in the blade compared to Pelorus Sound. The sporophyll also contained a significant amount of fucoxanthin throughout the harvest season, although lower than in the blade. Two antioxidant measurement methods, DPPH and CUPRAC, were utilised to measure antioxidant activities. Processed NZ U. pinnatifida had a lower fucoxanthin content and antioxidant activity than freeze-dried Undaria. Fucoxanthin content and antioxidant activities of NZ processed U. pinnatifida were not significantly different from other commercial samples from Japan and Korea. In conclusion, U. pinnatifida in New Zealand has a great potential to be a food and nutraceutical resource.     

Toward the discovery of novel anti-HIV drugs. Second-generation inhibitors of the cellular ATPase DDX3 with improved anti-HIV activity: synthesis, structure-activity relationship analysis, cytotoxicity studies, and target validation

A hit optimization protocol applied to the first nonnucleoside inhibitor of the ATPase activity of human DEAD-box RNA helicase DDX3 led to the design and synthesis of second-generation rhodanine derivatives with better inhibitory activity toward cellular DDX3 and HIV-1 replication. Additional DDX3 inhibitors were identified among triazine compounds. Biological data were rationalized in terms of structure-activity relationships and docking simulations. Antiviral activity and cytotoxicity of selected DDX3 inhibitors are reported and discussed. A thorough analysis confirmed human DDX3 as a valid anti-HIV target. The compounds described herein represent a significant advance in the pursuit of novel drugs that target HIV-1 host cofactors.     

Morphological and separation performance study of polysulfone/titanium dioxide (PSF/TiO2) ultrafiltration membranes for humic acid removal

In this study, polysulfone (PSF) hollow fiber membranes with enhanced performance for humic acid removal were prepared from a dope solution containing PSF/DMAc/PVP/TiO₂. The main reason for adding titanium oxide during dope solution preparation was to enhance the antifouling properties of membranes prepared. In the spinning process, air gap distance was varied in order to produce different properties of the hollow fiber membranes. Characterizations were conducted to determine membrane properties such as pure water flux, molecular weight cut off (MWCO), humic acid (HA) rejection and resistance to fouling tendency. The results indicated that the pure water flux and MWCO of membranes increased with an increase in air gap distance while HA retention decreased significantly with increasing air gap. Due to this, it is found that the PSF/TiO₂ membrane spun at zero air gap was the best amongst the membranes produced and demonstrated > 90% HA rejection. Analytical results from FESEM and AFM also provided supporting evidence to the experimental results obtained. Based on the anti-fouling performance investigation, it was found that membranes with the addition of TiO₂ were excellent in mitigating fouling particularly in reducing the fouling resistances due to concentration polarization, cake layer formation and absorption.     

Unique microstructure analysis of ethylene-propylene copolymer synthesized using catalytic system based on α-diimine nickel complexes: a comparative study by 13C NMR technique

The microstructure of rubber-like ethylene-propylene copolymer (MN4) produced by a mixed nickel-based system (MN) containing catalysts of dibromo[N,N′-bis(2,6-diisopropylphenyl)-2,3-butanediimine]nickel(II) n1 and dibromo[N,N′-(phenanthrene-9,10-diylidene)bis(2,6-diisopropylaniline)]nickel(II) n2 was determined by ¹³C NMR technique. Sequences distribution of ethylene (E), propylene (P), EP, inverted propylene and uninterrupted methylene and also methylene number-average sequence lengths for the copolymer (MN4) were estimated. The results obtained from the MN4 EP copolymer were compared with reported copolymers which had been synthesized using constrained geometry catalyst (CGC) and vanadium-based Ziegler-Natta catalyst. The results demonstrated that the MN4 EP copolymer had fewer alternating comonomer sequences than ethylene-propylene elastomers obtained by CGC and vanadium-based (V) catalysts. A large number of the inversion structures (66 %) and high mole percent of sequences containing a long branch (3.2 mol%) were also observed in unique microstructure of the copolymer (MN4).