Modelling the temperature dependence of kinematic viscosity for refined canola oil

Viscosities of refined, bleached, deodorized (RBD) and refined, bleached, winterized (RBW) canola oils were measured at temperatures from 4 to 100°C. The viscosities of these refined canola oils were exponentially related to the oil temperature. Viscosity of the RBW oil was slightly greater than that of the RBD oil when the temperature was below 15°C. Compared to refined soybean oil, the canola oils were substantially more viscous. The viscosity of canola oil was modelled asv = exp(C₀ + C₁T + C₂T²). The maximum predicted error was less than 1.6% over the tested temperature range.     

Kinetics of Dehydration of Green Alfalfa

Artificial drying is an important step in processing of green crops in order to preserve their freshness and nutrients for longer time at relatively lower costs. Forage crops, tea and tobacco are the major green crops where the commercial drying is a major operation in their processing. Fresh green alfalfa at about 75 to 80% moisture is subjected to drying in different types of dryers.ln the case of alfalfa, the raw material consists of leaves, stems, chops and fine stems, each varying distinctly in their physical and structural characteristics. The moisture content is reduced from initial level to about 10%. The drying air temperatures range from 40 b 800°C; the lower temperatures are used inconveyor dryers whereas high temperatures are used in rotary drum drycn.The results on drying behavior, and changes in physico-chemical propedes during drying for components of green alfalfa over the temperature range of 40 m 800°C are presented in this paper. The optimum temperature for drying from the stand point of color and protein solubility was found to be 175°C.     

Hot deformation behavior of microstructural constituents in a duplex stainless steel during high-temperature straining

The hot deformation characteristics of 1.4462 duplex stainless steel （DSS） were analyzed by considering strain partitioning between austenite and ferrite constituents. The individual behavior of ferrite and austenite in microstructure was studied in an iso-stress condition. Hot compression tests were performed at temperatures of 800-1100~C and strain rates of 0.001-1 s-1. The flow stress was modeled by a hyperbolic sine constitutive equation, the corresponding constants and apparent activation energies were determined for the studied alloys. The constitutive equation and law of mixture were used to measure the contribution factor of each phase at any given strain. It is found that the contribution factor of ferrite exponentially declines as the Zener-HoUomon parameter （Z） increases. On the contrary, the austenite contribution polynomially increases with the increase of Z. At low Z values below 2.6. x 1015 （lnZ---35.5）, a negative contribution factor is determined for austenite that is attributed to dynamic recrystallization. At high Z values, the contribution factor of austenite is about two orders of magnitude greater than that of ferrite, and therefore, austenite can accommodate more strain. Microstructural characterization via electron back-scattered diffraction （EBSD） confirms the mechanical results and shows that austenite recrystallization is possible only at high temperature and low strain rate.     

Simulation of temperature and moisture changes during storage of woody biomass owing to weather variability

The objective of this study is to describe moisture content and temperature profile in the woody biomass pile by a two dimensional mathematical model. Woody biomass in the form of wood chips and bundles was stored for a period of one year. Heat and moisture transfer model for drying processes was solved by finite element method using MATLAB programming. The simulation was performed using the recorded climate conditions during the experiment and constant drying air conditions. The temperature change inside the bundles shows the same trend and effect with ambient air temperature, however, in case of wood chips shows lesser effect at various ambient air temperature. Uniformly declined moisture content was observed inside the covered wood chips pile during the storage period. The proposed two dimensional model is in close agreement with experimental data to describe the moisture and temperature profile of the pile wood chips and bundles. However, as the wood chips pile height increases more than 3 m temperature development inside the pile could be rapid and the effect of chemical reaction in the wood chips pile has to be included for better accuracy of prediction.     

A review of agricultural crop residue supply in Canada for cellulosic ethanol production

This paper estimates the availability of agricultural crop residue feedstocks in Canada for cellulosic ethanol production. Canada's major field crops generate 100.6 million dry mega grams (Mg) of crops per year while non-forage crops produce 67 million dry Mg, leaving abundant agricultural residues for use as second generation feedstock for cellulosic ethanol production. This study used crop production and livestock data from Statistics Canada for a 10-year period (2001–2010), as well as tillage data from Statistics Canada census years 2001 and 2006, to estimate crop residue availability by province and soil zone. Total residue yield from crops is calculated by incorporating straw to grain ratios. Total agricultural residues available for ethanol production are computed by deducting soil conservation and livestock uses. An average of 48 million dry Mg of agricultural residues is available per year, with a minimum of 24.5 million dry Mg in drought year 2002. This implies an average yearly potential ethanol production of 13 billion litres from crop residues over the 2001–2010 period, with a minimum of 6.6 billion litres in 2002. Ontario, Manitoba, Saskatchewan, and Quebec have enough agricultural residue supply to set up ethanol plants using agricultural crop residues as primary lignocellulosic feedstocks. There is great variability in agricultural residue production between the provinces and by soil zone. Understanding variability in feedstock supply is important for the economics and operational planning of a cellulosic ethanol biorefinery. Factors such as residue yield per hectare and soil zone will influence cellulosic ethanol plant establishment in order to exploit the abundance of lignocellulosic biomass for an ethanol plant.     

Density Functional Theory Study on the Mechanical Properties and Interlayer Interactions of Multi-layer Graphene: Carbonic,Silicon-Carbide and Silicene Graphene-like Structures

Silicon - The main purpose of this study is to calculate the Young’s modulus of carbonic (c-graphene), silicon-carbide (SiC) and silicene graphene-like structures using density functional...     

Investigation on rheological behavior of 8 mol% yttria stabilized zirconia (8YSZ) powder using Tiron

In this research, 8 mol% yttria stabilized zirconia (8YSZ) powder were dispersed in de-ionized water by the use of different amounts of Tiron as dispersant. The results of rheological and sedimentation measurements of each suspension were evaluated and the optimum amount of Tiron was selected (0.8% Tiron). Also, various pH were investigated and the best stabilized suspension is achieved at pH 10. Furthermore, the zeta potential of suspension with and without adding dispersant was obtained. The isoelectric point (IEP) of as-received 8YSZ powder was about 8.5 and shifted obviously to acidic region after adding dispersant to the suspension.     

Overview and some issues related to co‐firing biomass and coal

Low heating values, variable chemical compositions, peculiar physical properties, high investment cost and insecurity of biomass feedstocks supply limit the applications of biomass for energy and other processes. Co‐firing biomass and coal has potential for the development of biomass‐to‐energy capacity with significant economic, environmental, and social benefits. However, co‐firing is not straightforward, and some questions need to be addressed due to the differences in chemical compositions and physical properties of biomass and coal. This paper highlights key issues related to co‐firing, including reactor types, feeding, hydrodynamics, ash sintering, fouling, and corrosion, based on previous studies, as well as calculations and analysis. Direct co‐firing is the most common option for biomass and coal co‐firing currently, mostly due to relatively low investment needed to turn existing coal power plants into co‐firing plants. For direct co‐firing, the physical characteristics and chemical compositions of the fuel entering the combustors or gasifiers are critical to an optimum operation. Any biomass mixed with coal needs to have acceptable physical properties. More research is needed on co‐firing biomass and coal, including work on: preparation, handling, storage, and feeding of biomass feedstocks (e.g. drying, torrefaction, pelletization); co‐firing mechanisms; hydrodynamic analysis of co‐firing combustors and gasifiers; boiler/gasifier capacity, slagging, fouling, corrosion, efficiency, reliability, fuel flexibility; lower emissions and gas cleaning; catalyst poisoning; investment and operating costs.     

Numerical analysis of intermodal delay in few-mode fibers for mode division multiplexing in optical fiber communication systems

In order to achieve higher spectral efficiency, mode division multiplexing (MDM) in few-mode fibers is a new research area. The idea faces lots of technical issues including intermodal delay and mode coupling which limit the achievable length of the system. This paper is designated to complete the analysis of intermodal delay in step-index few-mode fibers. We analyze numerically all the parameters of fiber, which could impact intermodal delay in few-mode fibers and identify the conditions which can increase the number of multiplex modes without significant increase in maximum intermodal delay.