Simultaneous preconcentration and determination of U(VI), Th(IV), Zr(IV) and Hf(IV) ions in aqueous samples using micelle-mediated extraction coupled to inductively coupled plasma-optical emission spectrometry

A simple cloud point extraction method followed by inductively coupled plasma-optical emission spectrometry (ICP-OES) was developed for simultaneous preconcentration and determination of trace amounts of U(VI), Th(IV), Zr(IV) and Hf(IV) ions in aqueous samples. The metal ions in 50 ml of aqueous solution (containing 0.1 M sodium acetate, pH 6.0) were formed complexes with dibenzoylmethane (DBM). Then, Triton X-114 (0.2%, w/v) was added to the solution. By increasing the temperature of the solution up to 50 degrees C, a phase separation occurred. After centrifugation at 4000 rpm for 6 min, the surfactant-rich phase (sediment phase) was diluted with 1.0 ml of 20:80 (v/v) of methanol/1 M HNO(3). The metal ions were then determined using ICP-OES. Finally, the main factors affecting the cloud point extraction were evaluated and optimized. Under optimized conditions, enhancement factors in the range of 37.0-43.6 were obtained. The calibration graphs were linear in the range of 0.5-1500 microg l(-1) for Th and Zr, 0.5-500 microg l(-1) for Hf and 2.5-1240 microg l(-1) for U with correlation coefficients (r(2)) better than 0.9926. The detection limits were between 0.1 and 1.0 microg l(-1) and the R.S.D. values for seven replicates were lower than 6.1%.     

Effect of melamine polyphosphate on thermal degradation of polyamides: a combined X-ray diffraction and solid-state NMR study

The effect of melamine polyphosphate (MpolyP) on the thermal degradation of both polyamide 66 (PA66) and polyamide 6 (PA6) was studied using a combination of solid-state techniques. The mixtures of MpolyP with polyamides were heated for different times at 350 and 450 °C. The residues were then analyzed by X-ray diffraction and both solid-state ¹³C NMR and ³¹P NMR. The chemical structures formed in these oven experiments were used to study the chemical changes that take place during a standard flammability test. The mixtures of MpolyP with polyamides were also characterized by frequency-dependent rheological experiments. It was shown that MpolyP could induce significant cross-linking in PA66 and leads to dramatic depolymerization of PA6. These results were used to explain the performance of MpolyP as a flame retardant in these polyamides.     

SIMULATION OF THERMAL AND DISINFESTATION CHARACTERISTICS OF A FORAGE DRYER

The thermal morality data for the cocoon stage of the insect Sitodiplosis mosellana (Gehin) were fitted to a normal distribution function and a probit viability equation was developed. The equation was included in a new tunnel dryer simulation program to compute the cumulative mortality of the insect during baled- forage drying. From the analysis it became clear that the temperature of dried forage remained at or above 60 C during drying and thus 99.99% kill of the insect was assured.     

Investigation and numerical analysis of strain distribution in the twist extrusion of pure aluminum

The effects of performing three twist extrusion passes on high purity aluminum samples were studied in this paper in regard to numerical analysis and experimental studies. The finite element analysis of the von-Mises stress and the equivalent plastic strain in the outer longitudinal and transverse cross-sections, which are parallel and normal to the billet axis respectively, was carried out. The simulation results showed that the end of the workpiece underwent more equivalent plastic strains in contrast to the head of the sample. Moreover, the corner regions experienced more strains than the center zone did. However, the heterogeneity in strain distribution in both longitudinal and transverse cross-sections decreased by performing the sequential twist extrusion passes. The experimental outcomes such as microstructure evolutions, microhardness and tensile tests validated the simulation results.     

Linear-like properties arise naturally in the adaptive control setting

Classical discrete-time adaptive controllers typically provide asymptotic stabilization and tracking; usually the affect of the noise is at best bounded-input bounded-output. Recently we have shown that if you design a discrete-time adaptive controller in just the right way, then in a variety of situations you not only obtain exponential stability, but also a bounded gain on the noise in every p−norm, as well as a never-before-seen linear-like convolution bound on the input–output behavior. Quite surprisingly, the approach is very natural, and relies on the use of the unmodified, original projection algorithm to carry out parameter estimation; if the set of plant uncertainty is not convex, then a multi-estimator and switching are used. The goal of this paper is to provide an overview of the approach, discuss the results-to-date, and list some of the open problems.     

Two safety coefficients for a typical 13 × 13 annular fuel assembly

Recently, annular fuel rods are proposed for both PWRs and BWRs to achieve more average power density and therefore many neutronic as well as thermal-hydraulics calculations have been made to find more performance in the future reactors. Also, some safety margins are studied for the proposed uranium-nitride (and/or other fissile materials) annular pins. Our aim herein is to study two important safety coefficient of the annular fuel core. These are “prompt reactivity” and “power coefficients”, where all investigations are made using MCNP-5 code. Also, a thermal resistance model for annular fuel heat transferring were given and then we have calculated its (a case) thermal resistance numerically.     

Biopower generation from mountain pine infested wood in Canada: An economical opportunity for greenhouse gas mitigation

Biomass is considered carbon neutral, and displacement of fossil fuel-based power by biomass-based power is one means to mitigate greenhouse gases. Large forest areas in British Columbia (BC), Canada, are infested by the mountain pine beetle (MPB). Dead wood from the infestation is expected to vastly exceed the ability of the pulp and lumber industry to utilize it; current estimates are that 200–600 million m³ of wood will remain unharvested over the next 20 years. Regions where the damaged wood is not harvested will experience loss of jobs in the forestry sector, increased risk of forest fire hazard, carbon emissions from burned or decaying wood, and uncertainty about timing of replanting since this usually occurs at harvest. This paper reports the results of a detailed preliminary techno-economic analysis of producing power from MPB killed wood. Power plant size and location are critical factors affecting overall power cost. Overall cost of power rises steeply at sizes below 300 MW net power output. By locating the power plant in an area of high infestation, transportation distances can be minimized. A 300 MW power plant would consume 64 million m³ of wood over a 20-year lifetime, and hence is a significant sink for otherwise unharvestable wood. Cost estimates are based on harvesting of whole dead trees with roadside chipping and transport to a central power plant located in either the Nazko or Quesnel regions of BC. A circulating fluidized bed boiler with a conventional steam cycle is a currently available technology demonstrated at 240 MW in Finland. The estimated power cost is $68 to $74 per MWh, which is competitive with other “green power” values in BC. Given recent values of export power in the Pacific Northwest, a 300 MW MPB power plant is viable with a carbon credit below $15 per tons of CO₂.     

MODIFICATION OF ASPHALT BY CHEMICAL TREATMENT WITH SULPHUR

The Theological properties of asphalt of different chemical compositions were assessed after treating them with sulphur at various reaction conditions. To correlate the observed alterations in the physical properties of the products with changes in the chemical composition, a study on model compounds was conducted to throw some light on this issue.     

Modelling the Bulk Cooling of Alfalfa Pellets

Cooling of alfalfa pellets after being made is one o f the unit operations in the pelleting of alfalfa. Using the thermal properties and drying diffusion coeficient together with other properties reported in refereed journals. a combined heat and mass transfer model was developed for the cooling of alfalfa pellets in deep beds. The model utilized the distributed heat and mass transfer equations to describe the temperature and moisture of the pellets. The distributed model interacts with the cooling air through a convective boundary condition for the temperature and a time-varying exponential surface condition for the moisture. Coupling o f the heat and mass transfer processes was carried out at the surface of the pellet using evaporative surface condition. The model was validated with field experimental data from a double-deck crossflow cooler. The simulated pellet and air temperatures were within 5⁰C of the collected field data while predicted moisture from the model was within 0.3% o f the experimental data.