Study on novel poly (vinyl pyrrolidone) doped MWCNTs/polyrhodanine nanocomposites: Synthesis,characterization, and thermal performance

In this paper, poly (vinyl pyrrolidone) (PVP) doped multiwall carbon nanotubes (MWCNTs/polyrhodanine), were synthesized through one-step chemical oxidative polymerization of rhodanine monomers on the surface-modified carbon nanotubes. Characterization of MWCNTs/polyrhodanine was conducted by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transforms infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and EDX spectrum analyses in which the results confirmed the successful formation of MWCNTs/polyrhodanine. In addition, to investigate the thermal properties of samples, thermogravimetric analysis (TGA) was employed, and results exhibited significant improvement in the nanocomposite thermal stability due to the addition of MWCNTs with reinforcement effect in polymer matrix.     

Investigation of MHD Go-water nanofluid flow and heat transfer in a porous channel in the presence of thermal radiation effect

In this paper, flow and heat transfer of MHD Go-water nanofluid between two parallel flat plates in the presence of thermal radiation are studied. One of plates is externally heated and cooled by coolant injection through the other plate, which also expands or contracts with time. A similarity transformation is used to transmute the governing momentum and energy equations into non-linear ordinary differential equations with the appropriate boundary conditions. The obtained non-linear ordinary differential equations are solved by Duan–Rach Approach (DRA). This method allows us to find a solution without using numerical methods to evaluate the undetermined coefficients. This method modifies the standard Adomian Decomposition Method by evaluating the inverse operators at the boundary conditions directly. The impacts of various parameters such as the Reynolds number, the expansion ratio, the magnetic parameter, the power law index, the solid volume fraction and the radiation parameter are investigated on the velocity and temperature. Furthermore, the value of the Nusselt number is calculated and presented through figures. The results indicate that the temperature profile and the Nusselt number have a direct relationship with the solid volume fraction and have an inverse relationship with the radiation parameter. In addition, the limiting cases are gained and found to be in an excellent agreement with the previous works.     

On the analysis of fracture mechanisms and mechanical behavior of AA5083-based tri-modal composites reinforced with 5 wt.%B4C and toughened by AA5083 and AA2024 coarse grain phases

In this article, the influence of AA2024 and AA5083 coarse grains on mechanical properties and failure mechanisms of AA5083-5wt. %B₄C tri-modal composite has been discussed. AA2024 and AA5083 powders (<100 µm) were added to mechanically milled AA5083-5 wt.%B₄C powders in 25 and 50 wt.% and the mixtures were consolidated using the hot press and hot extrusion techniques. Results indicated that by adding AA2024 and AA5083 powders as coarse grains, hardness and tensile strength of AA5083-5 wt.%B₄C composite decreased but ductility increased. Moreover, by adding AA2024 powders as coarse grains, fracture mode changed and cracks tended to grow through along AA2024/AA5083-5 wt.%B₄C interface rather than being arrested or deflected. It seemed that dislocation mobility and the interface between coarse grains and ultra-fine grains had the main role in determining the mechanical properties and failure mechanisms in tri-modal AA5083-B₄C composites.     

Thermo-mechanical characterization of polyurea variants

Mechanics of Time-Dependent Materials - The aim of this study is to investigate the role of chain length and hard segment dispersion within the soft segment on thermo-mechanical properties of a...     

Zebrafish Embryos Allow Prediction of Nanoparticle Circulation Times in Mice and Facilitate Quantification of Nanoparticle–Cell Interactions

The zebrafish embryo is a vertebrate well suited for visualizing nanoparticles at high resolution in live animals. Its optical transparency and genetic versatility allow noninvasive, real‐time observations of vascular flow of nanoparticles and their interactions with cells throughout the body. As a consequence, this system enables the acquisition of quantitative data that are difficult to obtain in rodents. Until now, a few studies using the zebrafish model have only described semiquantitative results on key nanoparticle parameters. Here, a MACRO dedicated to automated quantitative methods is described for analyzing important parameters of nanoparticle behavior, such as circulation time and interactions with key target cells, macrophages, and endothelial cells. Direct comparison of four nanoparticle (NP) formulations in zebrafish embryos and mice reveals that data obtained in zebrafish can be used to predict NPs' behavior in the mouse model. NPs having long or short blood circulation in rodents behave similarly in the zebrafish embryo, with low circulation times being a consequence of NP uptake into macrophages or endothelial cells. It is proposed that the zebrafish embryo has the potential to become an important intermediate screening system for nanoparticle research to bridge the gap between cell culture studies and preclinical rodent models such as the mouse.     

Binding of externally supplied chlorides in micro silica concrete under field exposure conditions

Chloride binding has remarkable influence on the chloride penetration and hence, on the time to corrosion initiation in reinforced concrete structures. Previous studies have mainly looked at the chloride binding from internal sources in laboratory, which is not representative of practical situations. The current work focuses on the chloride binding characteristics of concrete samples exposed to an external source of chlorides from the sea water at Persian Gulf region. Some of the important parameters including w/c ratio, silica fume replacement and effect of chloride concentration on chloride binding were investigated in order to provide insight into the distribution of free and bound chloride ions after a long-term exposure.The results of the current study suggest that the chloride binding capacity increases with increasing the w/c ratio and chloride concentration but decreases by using silica fume. A general equation was also developed correlating the total and bound chloride in order to obtain more accurate service life prediction.     

Radiation dose to neonates undergoing X-ray imaging in special care baby units in Iran

Radiographic imaging has a significant role in the timely diagnosis of the diseases of neonates in intensive care units. The estimation of the dose received by the infants undergoing radiographic examination is of great importance, due to greater more radiosensitivity and longer life expectancy of the neonates and premature babies. In this study, the values of entrance skin dose (ESD), dose area products (DAPs), energy imparted (EI), whole-body dose, effective dose and risk of childhood cancer were estimated using three methods including direct method [using thermoluminescence dosimetry (TLD) chips], indirect method (using tube output) and Monte Carlo (MC) method (using MCNP4C code). In the first step, the ESD of the neonates was directly measured using TLD-100 chips. Fifty neonates, mostly premature, with different weights and gestational ages in five hospitals mostly suffering from respiratory distress syndrome and pneumonia were involved in this study. In the second step, the values of ESD to neonates were indirectly obtained from the tube output in different imaging techniques. The imaging room, incubator, neonates and other components were then simulated in order to obtain the ESD values using the MCNP4C code. Finally, the values of ESD assessed by the three methods were used for calculation of DAP, EI, whole-body dose, effective dose and risk of childhood cancer. The results indicate that the mean ESD per radiograph estimated by the direct, indirect and MC methods are 56.6±4.1, 50.1±3.1 and 54.5±3.3 μGy, respectively. The mean risk of childhood cancer estimated in this study varied between 4.21×10(-7) and 2.72×10(-6).     

Dimensional change and elastic behavior of layered silicates and Portland cement paste

The role of water in hydrated Portland cement paste (hpc) is germane to understanding the nature of nanostructure – property relationships of the material. The irreversible dimensional changes of hpc and phase pure C–S–H that occur on wetting and drying are dissimilar to those observed for other silicate minerals of interest to cement science. This irreversibility in hpc is also observed for the modulus of elasticity parameter. Length change, mass change and modulus of elasticity isotherms (including drying–wetting cycles) were determined for specimens of hpc, Ca-montmorillonite and 1.4 nm tobermorite. Length change and modulus of elasticity versus mass loss curves were also obtained for phase pure C–S–H (C/S = 0.8, 1.0 and 1.5). All the isotherms exhibit significant irreversible behavior. Similarities and differences in the nature and character of the isotherms and the relevance of the C–S–H data are discussed. Inferences are made with respect to the nanostructural nature of hpc, its dimensional response in aqueous media and the correspondence in behavior of synthetic C–S–H and that formed in hpc. It is apparent that hpc has unique characteristics that are responsible for stability.