A novel solvent-impregnated resin containing 3-hydroxy-2-naphthoic acid for stepwise extraction of Th(IV) and U(VI) over other coexistence ions

A new solvent-impregnated resin (SIR) was constructed using Amberlite XAD-2 and 3-hydroxy-2-naphthoic acid (3H2NA). The SIR was applied for stepwise extraction of Th(IV) and U(VI) from the coexistence ions dissolved in aqueous media at pHs of 3.0 and 7.0, respectively. The U(VI) and Th(IV) ions adsorbed on the minicolumn were consecutively eluted with 0.5 M and 4 M HCl solutions. They were then measured by Arsenazo III at their maximum absorption wavelengths. The characteristic parameters for the successful separation of these ions from the aqueous media were investigated. The SIR showed excellent reproducibility during the 800 subsequent extraction cycles.     

Mortality response of folate receptor-activated,PEG–functionalized TiO2 nanoparticles for doxorubicin loading with and without ultraviolet irradiation

TiO₂ nanoparticles (NPs) were synthesized by hydrothermal assisted sol–gel technique. In the next step, as-synthesized NPs were modified by poly ethylene glycol (PEG). Then, folic acid (FA) was conjugated to TiO₂–PEG. Finally, Doxorubicin (Dox) as an anticancer drug was loaded on as-prepared TiO₂–PEG–FA nanocarrier. The optimization of TiO₂ and FA concentration and the influence of ultraviolet (UV) irradiation on photocatalytic activity of nanocarrier and Dox loaded carrier were assessed by utilizing the 3-(4,5-dimethylthiazol-2yl)-2,5-diphenyltetrazolium bromide (MTT)-assay method.     

Use of a selective extractant-impregnated resin for removal of Pb(II) ion from waters and wastewaters: Kinetics,equilibrium and thermodynamic study

Adsorption of Pb(II) ion by a novel extractant-impregnated resin, EIR, was studied as a function of various experimental parameters using batch adsorption experiments. The new EIR was prepared by impregnating gallocyanine (GCN) onto Amberlite XAD-16 resin beads. The EIR was characterized by nitrogen analysis and SEM micrographs. The new EIR showed excellent selectivity factor values (α) for Pb(II) adsorption respect to other metal ions. The effects of some chemical and physical variables were evaluated and the optimum conditions were found for Pb(II) removal from aqueous solutions. The equilibrium adsorption isotherm was fitted with the Langmuir adsorption model. The maximum adsorption capacity (q_max) of EIR for Pb(II) ions was found to be 367.92 mg g⁻¹. The kinetic studies showed that the intra-particle diffusion is the rate-controlling step. Also, the intra-particle diffusion coefficients, D_ip values, were of the order of 10⁻¹² m² s⁻¹. The values of enthalpy (ΔH°) were positive, which confirms the endothermic nature of adsorption process. Also, the positive entropy changes (ΔS°) were showed that the randomness increased along with the adsorption process. In addition, the obtained negative values of Gibbs free energy (ΔG°) indicated feasible and spontaneous nature of the adsorption process at different temperatures. The new adsorbent was very stable so that it can be successfully used for many consecutive cycles without significant loss in its adsorption capacity.     

CFD modeling of immiscible liquids turbulent dispersion in Kenics static mixers: Focusing on droplet behavior

The present study is concerned with the computational fluid dynamics(CFD) simulation of turbulent dispersion of immiscible liquids, namely, water–silicone oil and water–benzene through Kenics static mixers using the Eulerian–Eulerian and Eulerian–Lagrangian approaches of the ANSYS Fluent 16.0 software. To study the droplet size distribution(DSD), the Eulerian formulation incorporating a population balance model(PBM) was employed. For the Eulerian–Lagrangian approach, a discrete phase model(DPM) in conjunction with the Eulerian approach for continuous phase simulation was used to predict the residence time distribution(RTD) of droplets.In both approaches, a shear stress transport(SST) k-ω turbulence model was used. For validation purposes, the simulated results were compared with the experimental data and theoretical values for the Fanning friction factor, Sauter mean diameter and the mean residence time. The reliability of the computational model was further assessed by comparing the results with the available empirical correlations for Fanning friction factor and Sauter mean diameter. In addition, the influence of important geometrical and operational parameters, including the number of mixing elements and Weber number, was studied. It was found that the proposed models are capable of predicting the performance of the Kenics static mixer reasonably well.     

A new consideration on reinforcement distribution in the different planes of nanostructured metal matrix composite sheets prepared by accumulative roll bonding (ARB)

Recently, a number of novel methods based on accumulative roll bonding (ARB) have been introduced to produce particulate metal matrix composites. Nonetheless, the microstructure uniformity from the reinforcement distribution viewpoint in the different planes of ARBed composite sheets has not been focused up to date. This paper aims to compare the evolution of the B₄C particles distribution in nanostructured Al-10 vol.% B₄C composites prepared by ARB in the rolling direction-normal direction (RD-ND) and transverse direction-normal direction (TD-ND) planes. From optical microscopic evaluations quantified by the radial distribution function analysis, it is realized that the homogeneity in the RD-ND planes is in excess of the TD-ND planes. In addition, transmission electron microscopy reveals the development of nanostructures in the Al matrix after seven ARB passes.     

Black Nickel Coating and Color Anodized Layers for Solar Absorber

Solar selective absorbers are considered as an essential part of a thermal solar collector for which the optical properties are dependent upon their structure and surface morphology. In this paper, optical properties of Ni-pigmented anodized are compared with black electroless nickel coatings. The effect of heat treatment on optical properties of the coatings was also investigated. Anodized films were formed in 6 M phosphoric acid followed by a black coloration process. Scanning electron microscope was used to study the morphology, and X-ray diffraction was employed to identify the phases present. Evaluation of optical properties was carried out by spectral reflectance. Evaluation of the optical characteristics showed that Ni-pigmented anodized and black electroless samples, after heat treatment, had the highest absorption coefficient at about 0.98 as well as the lowest emission coefficient. The ξ factor reached about 6 in heat treated Ni-pigmented anodized layer and offered optimal properties in this research.     

Analysis of multi-layered filament-wound composite pipes under combined internal pressure and thermomechanical loading with thermal variations

The composite pipes manufactured by filament winding technology have anisotropic behavior owing to different reinforced ply angles. Composite pipes can be exposed to the thermomechanical loading due to hot fluid that flows into them. In this paper, based on the three-dimensional anisotropic elasticity, an exact elastic solution for thermal stresses and deformations of the pipes under internal pressure and a temperature gradient has been studied. Giving heat convection conditions the variation of temperature field within the pipe is obtained by solving the conduction equation at the wall. The influence of temperature field in the governing equations of thermoelasticity has been considered via a constitutive law. The shear extension coupling is also considered because of lay-up angles. Stress, strain and deformation distributions for different angle-ply pipe designs are investigated using the present theory.     

Preparation and functional properties of fish gelatin–chitosan blend edible films

With the goal of improving the physico-chemical performance of fish gelatin-based films, composite films were prepared with increasing concentrations of chitosan (Ch) (100G:0Ch, 80G:20Ch, 70G:30Ch, 60G:40Ch and 0G:100Ch, gelatin:Ch), and some of their main physical and functional properties were characterised. The results indicated that the addition of Ch caused significant increase (p < 0.05) in the tensile strength (TS) and elastic modulus, leading to stronger films as compared with gelatin film, but significantly (p < 0.05) decreased the elongation at break. Ch drastically reduced the water vapour permeability (WVP) and solubility of gelatin films, as this decline for the blend film with a 60:40 ratio has been of about 50% (p < 0.05). The light barrier measurements present low values of transparency at 600 nm of the gelatin–chitosan films, indicating that films are very transparent while they have excellent barrier properties against UV light. The structural properties investigated by FTIR and DSC showed a clear interaction between fish gelatin and Ch, forming a new material with enhanced mechanical properties.