Investigation on carbon nanomaterials: Coaxial CNT-cylinders and CNT-polymer composite

The macroscopic coaxial carbon cylinders (dia. ∼0.5 cm with varying lengths, ∼ 7–10 cm) consisting of aligned carbon nanotube (CNT) stacks have been prepared by controlled spray pyrolysis method. The coaxial carbon cylinders of CNT stacks have been formed directly inside the quartz tube. Another study is done on multi-walled CNTs (MWNTs)-polymer (e.g. polyethylene oxide (PEO), polyacrylamide (PAM)) composite films. We have investigated the structural, electrical and mechanical properties of MWNTs-PEO composites. Composites with different wt% (between 0 and 50 wt% of MWNTs) have been prepared and characterized by the scanning electron microscopic technique. Enhanced electrical conductivity and mechanical strength were observed for the MWNTs-PEO composites. We have also studied the electrical property of MWNTs-PAM composite films.     

Compton profiles of MoP and WP: Validation of second order generalized gradient approximation

Recently, Zhao and Truhlar (J. Chem. Phys. 128, 184109, 2008) have constructed second order generalized gradient approximation (SOGGA) within the density functional theory. The authors have successfully tested the performance of SOGGA by computing lattice constants, cohesive energies, bond distances and few energetic quantities of different solids and molecules. In this paper, to establish the usefulness of SOGGA in deducing the momentum densities, we have compared our experimental Compton profiles of MoP and WP with those computed using GGA and SOGGA within density functional theory. It is seen that SOGGAPBE based Compton profiles of both the samples are in better agreement with the corresponding experimental data than those derived from BPBE-GGA. In addition, energy bands, density of states and relative nature of bonding in both the phosphides is explained in terms of equal-valence-electron-density profiles and Mulliken’s population analysis.     

INFLUENCE OF DESIGN AND OPERATIONAL PARAMETERS ON YIELD OF FULLERENES

Fullerene production by arc-discharge method using graphite electrodes has been studied with respect to influence of different design and operational parameters on fullerene yield in a constant arc fullerene reactor. The design parameters like reactor length, diameter, heat transfer area and operational parameters like voltage, current, pressure, coolant flow rate, graphite evaporation rate and electrode diameter etc. have been experimentally studied in detail to establish a relationship between these parameters and fullerene yield. All the parameters affecting the yield have been correlated by dimensional analysis and an equation to calculate the fullerene yield is derived. It was observed experimentally as well as by dimensional analysis that many favorable parameters for getting good yield are linked with other parameters which also get changed if the favorable parameters are changed and thus it is difficult to make a substantial change in the yield of fullerenes.  The relationship established between the yield and parameters is however useful in optimising fullerene yield in a reactor and also helpful in designing a futuristic fullerene reactor of improved yield and productivity. The fullerene yield from different designs of reactors is obtained in the range of 4% to 20%.     

Effect of temperature and α-irradiation on gas permeability for polymeric membrane

In the present study the polyethersulphone (PES) membranes of thickness (35 ±2) μm were prepared by solution cast method. The permeability of these membranes was calculated by varying the temperature and by irradiation of α ions. For the variation of temperature, the gas permeation cell was dipped in a constant temperature water bath in the temperature range from 303–373 K, which is well below the glass transition temperature (498 K). The permeability of H₂ and CO₂ increased with increasing temperature. The PES membrane was exposed by a-source (₉₅Am₂₄₁) of strength (1 μ Ci) in vacuum of the order of 10⁻⁶ torr, with fluence 2.7 × 10⁷ ions/cm². The permeability of H₂ and CO₂ has been observed for irradiated membrane with increasing etching time. The permeability increases with increasing etching time for both gases. There was a sudden change in permeability for both the gases when observed at 18 min etching. At this stage the tracks are visible with optical instrument, which confirms that the pores are generated. Most of pores seen in the micrograph are circular cross-section ones.     

Gender-related differences in susceptibility of A/J mouse to benzo[a]pyrene-induced pulmonary and forestomach tumorigenesis

A commercial patient dose verification system utilizing non-invasive metal oxide semiconductor field effect transistor (MOSFET) dosimeters originally designed for radiotherapy applications has been evaluated for use at diagnostic energy levels. The system features multiple dosimeters that may be used to monitor entrance or exit skin dose and intracavity doses in phantoms in real time. We have characterized both the standard MOSFET dosimeter designed for radiotherapy dose verification and a newly developed "high sensitivity" MOSFET dosimeter designed for lower dose measurements. The sensitivity, linearity, angular response, post-exposure response, and physical characteristics were evaluated. The average sensitivity (free in air, including backscatter) of the radiotherapy MOSFET dosimeters ranged from 3.55 x 10(4) mV per C kg(-1) (9.2 mV R(-1)) to 4.87 x 10(4) mV per C kg(-1) (12.6 mV R(-1)) depending on the energy of the x-ray field. The sensitivity of the "high sensitivity" MOSFET dosimeters ranged from 1.15 x 10(5) mV per C kg(-1) (29.7 mV R(-1)) to 1.38 x 10(5) mV per C kg(-1) (35.7 mV R(-1)) depending on the energy of the x-ray field. The high sensitivity dosimeters demonstrated excellent linearity at high energies (90 and 120 kVp) and acceptable linearity at lower energies (60 kVp). The angular response was significant for free-in-air exposures, as illustrated by the sensitivity differences between the two sides of the dosimeter, but was excellent for measurements within a tissue equivalent cylinder. The post-exposure drift response is a complicated but reproducible function of time. Real-time monitoring requires little if any corrections for the post-exposure drift response. The MOSFET dosimeter system brings some unique capabilities to diagnostic radiology dosimetry including small size, real-time capabilities, nondestructive measurement, good linearity, and a predictable angular response.     

Fluorescence spectroscopic studies on interactions between liver annexin VI and nucleotides--a possible role for a tryptophan residue

Annexin VI is a 68-kDa calcium-, phospholipid-, and cytoskeletal-element-binding protein, which has been implicated in various processes, including calcium release and sequestration in calcifying cartilage, in a receptor-mediated endocytosis in human fibroblasts, and in secretion from chromaffin granules. In these processes it was found that, in addition to Ca2+ and annexin, the presence of ATP is also a prerequisite. In the present report we show that annexin VI binds ATP and the binding of nucleotide to protein is accompanied by quenching of an intrinsic fluorescence of annexin VI, which was found to be specific for 2'-(or 3')-O-(2,4,6-trinitrophenyl)adenosine 5'-triphosphate, GTP and ATP, and dependent on the annexin conformation. The nucleotide-binding site within an annexin VI molecule is likely to be close to the tryptophan-containing domain of annexin VI. We propose that ATP plays the role of a physiological ligand for annexin VI, and its binding to annexin VI may represent an alternative cellular mechanism for the regulation of annexin-membrane interactions coupled to overall energy transitions in the cell.     

Two Channel Thermally Tunable Band-Stop Filter for Wavelength Selective Switching Applications by Using 1D Ternary Superconductor Photonic Crystal

By studying temperature-dependent dispersion characteristics and group velocity of 1D ternary photonic crystal (TPC) composed of dielectric-superconductor-dielectric materials, a thermally tunable band-stop filter which is capable of stopping unique wavelength channels without causing any interference amongst equally spaced wavelength channels of full width at half maximum of 1 nm each as per the requirement of wavelength division multiplexing standards adopted by the International Telecommunication Union specifying channel spacing in terms of frequency (wavelength) is suggested. The proposed structure can efficiently work as a two-channel wavelength selective switch for wavelength division multiplexing (WDM)-based all-optical networks. This study also gives theoretical insight to design some new kind of optical memories and tunable buffers which holds data temporary and have potential applications in modern communication systems.     

Oxidative stress following traumatic brain injury in rats

BACKGROUND: Free radicals may be involved in the pathophysiology of traumatic brain injury (TBI) through oxidative damage of neurovascular structures. Endogenous antioxidants, such as ascorbate and alpha-tocopherol, may play a critical role in combating these oxidative reactions and their oxidized products can serve as an important index of oxidative stress. METHODS: We used electron spin resonance (ESR) spectroscopy and in vivo spin trapping (reaction of an organic compound with free radical species) to detect the possible generation of free radicals after TBI. Injury was inflicted by a weight drop technique over the head (5.7 kg-cm). Rats were intravenously infused with either 1 mL, 0.1 M of the spin trap, alpha-phenyl-N-tert-butyl nitrone (PBN), or an equivalent volume of saline immediately before TBI or sham-injury. Animals were divided into four groups: (1) Group I: PBN-infused sham-injured, (2) Group II: PBN-infused injured, (3) Group III: saline-infused sham-injured, and (4) Group IV: saline-infused injured. Additional groups of saline-infused uninjured, saline-infused, and PBN-infused injured animals were used for histopathology. Sixty minutes after TBI or sham-injury, rats were again anesthetized and decapitated. The brains were removed within 1 minute, homogenized, and extracted for lipids. The extracts were analyzed by ESR spectroscopy. Brain ascorbic acid (AA) concentration was determined spectrophotometrically, using the ascorbate oxidase assay. RESULTS: No PBN spin adduct signals (indicating trapped free radical species) were visible 60 minutes after TBI. All groups of rats showed an ascorbyl free radical signal. The ascorbyl signal intensity (AI) was, however, significantly higher in the injured rats, while the brain (AA) was significantly reduced. In addition, the ratio of AI/AA, which eliminates the effect of variable ascorbate concentrations in the brain, was also significantly higher in the injured animals. CONCLUSIONS: We conclude that 60 minutes following TBI there was a significantly increased level of oxidative stress in the brain. This may reflect formation of free radical species with subsequent interaction with ascorbate (antioxidant) during the 60 minute period. The lack of PBN spin adduct signals 1 hour after TBI may indicate that free radical generation is time dependent and might be detectable earlier or later than the 60 minute period.     

Exploring a reversible NOR from a 4 × 4 modified Fredkin gate and its optical mapping using a LiNbO3-based MZI

Journal of Computational Electronics - The extensive search for the implementation of reversible logic using emerging technologies has paved the way for the rise of optical computing. The...     

Conduction nature of conical pores in PET membrane

Summary The preparation of conical pores in polyethylene terepthlate (PET) membrane is described. The conical pores prepared in PET by track etching technique. For this purpose, Cl⁹⁺ ion irradiated film was placed into an electrolytic cell and etched from one side while other side of membrane was protected by a stopping medium. During etching, current was recorded as a function of time, which shows a sudden change, indicating the pores breakthrough. After breakthrough, the etch process is interrupted by replacing the etching solution. After etching, the current voltage characteristics were determined under symmetric bath conditions. The resulting conical pores show non ohmic behavior, similar to that of an electronic diode.