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41.
P.G.Joshi R.J.Cruse R.J.Pickwell K.J.Weller M.H.Hofstetter E.R.Pohl M.F.Stout F.D.Osterholtz 涂学忠摘译 《轮胎工业》2005,25(2):96-103
填充白炭黑的低滚动阻力轮胎的开发不断获得新进展。与填充普通炭黑的轮胎相比,白炭黑轮胎不仅降低了油耗,而且具有优异的牵引性能和与后者相当的磨耗寿命。高分散性白炭黑和多硫化双-烷氧基硅烷的发展使高填充白炭黑轮胎商品化获得重大突破。炭黑胶料和白炭黑-硅烷胶料的能耗散机理差异很大, 相似文献
42.
Experimental data on reverse osmosis using a sodium chloride solution by cellulose triacetate membranes are presented. The investigation involved studies on the composition of membrane casting solutions and their effects on the performance. A higher polymer concentration (11–13%) is found suitable for production of a uniform and highly salt rejecting membrane. Salt rejection of 99.0% and 4–5 GFD product water flux were obtained at 1000 psi operating pressure using 30,000 ppm TDS seawater in the initial experiments. 相似文献
43.
Mixtures of polystyrene and high density polyethylene were injection molded from recycled and virgin polymers to generate cocontinuous structures. The mechanical properties of these blends were evaluated to assess their conformance to rule of mixtures behavior in general and to identify areas of synergy or incompatibility in specific. Flexural and tensile data for recycled blends showed that generally the properties are not additive, except in a cocontinuous region of composition near 35/65 PS/HDPE that has been identified previously for recycled materials. Analysis of crystallinity in the HDPE phase of these blends by differential scanning calorimetry indicates a marked reduction in the level of HDPE crystallinity at the 35/65 PS/HDPE composition. Similar blends of virgin PS/HDPE polymer do not show the differing regions of incompatibility and synergy illustrated by the recycled materials, but rather show approximate conformance to the rule of mixtures. Furthermore, the virgin blends show virtually no crystallinity suppression and a more pronounced Tg shift in the polystyrene compared to recycled materials. Detailed characterization of the recycled materials in terms of polymer and particulate impurities should improve understanding of these differences and perhaps provide direction for obtaining enhanced synergistic behavior in virgin polymer blends. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
44.
Synthesis, characterization and antimicrobial activities of an interesting class of biologically potent macrocyclic complexes have been carried out. All the complexes have been evaluated for their antimicrobial effects on different species of pathogenic fungi and bacteria. The testicular sperm density, testicular sperm morphology, sperm motility, density of cauda epididymal spermatozoa and fertility in mating trails and biochemical parameters of reproductive organs have been examined and discussed. The resulting biologically active [M(MaL(n))(R(2))]Cl(2) and [Pb(MaL(n))(R(2))X(2)] (where, M = Pd(II) or Pt(II) and X = Cl or NO(3)) type of complexes have been synthesized by the reactions of macrocyclic ligands (MaL(n)) with metal salts and different diamines in 1:1:1 molar ratio in methanol. Initially the complexes were characterized by elemental analyses, molecular weight determinations and conductivity measurements. The mode of bonding was established on the basis of IR, (1)H NMR, (13)C NMR, (195)Pt NMR, (207)Pb NMR, XRD and electronic spectral studies. The macrocyclic ligand coordinates through the four azomethine nitrogen atoms which are bridged by benzil moieties. IR spectra suggest that the pyridine nitrogen is not coordinating. The palladium and platinum complexes exhibit tetracoordinated square-planar geometry, whereas a hexacoordinated octahedral geometry is suggested for lead complexes. 相似文献
45.
Synthetic, spectroscopic and antimicrobial aspects of some fertility inhibitor heterobimetallic complexes have been carried out. These heterobimetallic chelates [M(C(5)H(5)N(3))(2)M(2)'(R)(4)]Cl(2) (M = Pd or Pt and M' = Si, Sn, Ti and Zr) have been successfully synthesinzed via the reaction of M(C(5)H(7)N(3))(2)Cl(2) with group four or fourteen dichlorides in 1:2 stoichiometric proportions. The products were characterized by elemental analyses, molecular weight determinations, magnetic susceptibility measurements, conductance, and IR multinuclear NMR and electronic spectral studies. A square planar geometry has been suggested for all the complexes with the help of spectral data. Conductivity data strongly suggest that chlorine atoms are ionic in nature due to which complexes behave as electrolytes. All the complexes have been evaluated for their antmicrobial effects on different species of pathogenic fungi and bacteria. The testicular sperm density, testicular sperm morphology, sperm motility, density of cauda epididymal spermatozoa and fertility in mating trails and biochemical parameters of reproductive organs have been examined and discussed. 相似文献
46.
Dielectric and piezoelectric properties of 0.02Pb(Y2/3 W1/3 )O3 0.98Pb(Zr0.52Ti0.48)O3 ceramics doped with additives (Nb2 O5 , La2 O3 , MnO2 , and Fe2 O3 ) were investigated. The grain sizes of these ceramics decreased with increasing amounts of additives. For additions of MnO2 and Fe2 O3 , dielectric losses decreased, while for Nb2 O5 and La2 O3 , these values increased. The maximum values of the mechanical quality factor Qm were found to be 956 and 975 for additions of 0.9 wt% Fe2 O3 and 0.7 wt% MnO2 , respectively, but donor dopants (Nb2 O5 and La2 O3 ) did not change the values of Qm . On the other hand, the piezoelectric constant d33 and the electromechanical coupling factor kp decreased with additions of MnO2 and Fe2 O3 , but improved with additions of Nb2 O5 and La2 O3 . 相似文献
47.
Prutha Joshi Steven Breaux Joseph Naro Yuyang Wang Md Shakir Uddin Ahmed Komal Vig Maria L. Auad 《应用聚合物科学杂志》2021,138(21):50489
Hydrogels are polymeric materials widely used in medicine due to their similarity with the biological components of the body. Hydrogels are biocompatible materials that have the potential to promote cell proliferation and tissue support because of their hydrophilic nature, porous structure, and elastic mechanical properties. In this work, we demonstrate the microwave-assisted synthesis of three molecular weight varieties of poly(ethylene glycol) dimethacrylate (PEGDMA) with different mechanical and thermal properties and the rapid photo of them using 1-hydroxy-cyclohexyl-phenyl-ketone (Irgacure 184) as UV photoinitiator. The effects of the poly(ethylene glycol) molecular weight and degree of acrylation on swelling, mechanical, and rheological properties of hydrogels were investigated. The biodegradability of the PEGDMA hydrogels, as well as the ability to grow and proliferate cells, was examined for its viability as a scaffold in tissue engineering. Altogether, the biomaterial hydrogel properties open the way for applications in the field of regenerative medicine for functional scaffolds and tissues. 相似文献
48.
We have developed an IT governance disclosure framework to examine how firms communicate their IT governance activities. Using this framework for a sample of 200 commercial banking firms, our empirical assessment indicates that differences in the level of disclosure are systematically related to differences in institutional settings. We also find that firms with relatively good corporate governance practices consider IT performance measurement matters to be highly important when informing and communicating with shareholders. 相似文献
49.
Detecting spatio-temporal clusters, i.e. clusters of objects similar to each other occurring together across space and time, has important real-world applications such as climate change, drought analysis, detection of outbreak of epidemics (e.g. bird flu), bioterrorist attacks (e.g. anthrax release), and detection of increased military activity. Research in spatio-temporal clustering has focused on grouping individual objects with similar trajectories, detecting moving clusters, or discovering convoys of objects. However, most of these solutions are based on using a piece-meal approach where snapshot clusters are formed at each time stamp and then the series of snapshot clusters are analyzed to discover moving clusters. This approach has two fundamental limitations. First, it is point-based and is not readily applicable to polygonal datasets. Second, its static analysis approach at each time slice is susceptible to inaccurate tracking of dynamic cluster especially when clusters change over both time and space. In this paper we present a spatio-temporal polygonal clustering algorithm known as the Spatio-Temporal Polygonal Clustering (STPC) algorithm. STPC clusters spatial polygons taking into account their spatial and topological properties, treating time as a first-class citizen, and integrating density-based clustering with moving cluster analysis. Our experiments on the drought analysis application, flu spread analysis and crime cluster detection show the validity and robustness of our algorithm in an important geospatial application. 相似文献
50.
The genetic cost of sexual reproduction has been attributed to two causes in mathematical formulations: male function or genome dilution. We develop and analyse a genetic model that shows that both costs occur, depending upon the conditions. The model differs from previous formulations in that the level of output and fertilization success of male gametes produced by hermaphrodites that are asexual in their female function (henceforth "parthenogenetic hermaphrodites") are treated as variables, rather than constants fixed at 0 or 1, as has previously been the case. By expressing the cost of sex in terms of per capita egg loss of sexual individuals and parthenogenetic hermaphrodites, we partition the cost into components due to male function and genome dilution. Which component dominates the cost of sex depends upon the relative male gamete output of the parthenogenetic hermaphrodites. The cost of sex is observed to increase, or remain unchanged in some marginal cases, with increases in (i) frequency of parthenogenetic hermaphrodites, (ii) fertilization success of male gametes produced by parthenogenetic hermaphrodites and (iii) potential eggs lost by diverting resources to male gamete production. In certain situations, parthenogenetic hermaphrodites with an intermediate level of male gamete output have the greatest fitness advantage over sexual individuals. If heritable variation for levels of male gamete output exists among parthenogenetic hermaphrodites, this raises the possibility of the evolution of optimal levels of male gamete production by parthenogenetic hermaphrodites through natural selection, in situations of recurring invasion of asexual populations by propagules from sexual populations, a scenario that is increasingly being appreciated as potentially fairly likely to occur in nature. 相似文献