Effect of wafer thinning methods towards fracture strength and topography of silicon die

This paper characterizes die damage resulting from various wafer thinning processes. Die fracture strength is measured using ball breaker test with respect to die surface finish. Further study on surface roughness and topography of each surface finish is obtained by atomic force microscopy (AFM) and scanning electron microscopy (SEM) techniques. Stress relief process with 25 μm removal is able to strengthen 100 μm wafer by 20.4% using chemical wet etch and 75 μm wafer by 36.4% with plasma etch. Relatively, plasma etching shows higher fracture strength and flexibility compared to chemical wet etch. This is due to topography of the finished surface of plasma etch is smoother and rounded, leading to a reduced stress concentration, hence improved fracture strength.     

Optimization of composite plates with piezoelectric stiffener-actuators under in-plane compressive loads

Stiffeners which are used to strengthen a plate can be constructed of piezoceramic materials and subsequently used as piezo actuators to improve the load carrying capacity of the plate. In the present study, a fibre composite plate with initial imperfections and under in-plane compressive loads is studied with a view towards minimizing its deflection using the piezo actuators and the fibre orientations. Piezoceramic stiffeners are bonded symmetrically on the top and bottom of the plate and deployed as actuators. Two cases of electric fields, namely, the in-phase and out-of-phase voltages are applied to the actuators. The presence of initial deflections leads to deformation under the in-plane compressive loads which should be less than the critical buckling load. Two cases of initial imperfections are considered, and the first one is the deterministic initial deflections which are known a priori and as such they are given as input parameters for the problem. In the second case the initial deflections are uncertain and they have to be obtained according to a given criterion. In the present study they are determined to produce the least favourable initial deflection (largest deflection) at a given point and the solution is obtained by convex modelling. The effect of the actuators, the ply angles and the voltage are studied and their effects on the transverse deflection are investigated. A performance index involving the L₂ norm of the deflections is minimized using the piezo effect and as well as the ply angles the optimal values of which are determined for various problem parameters.     

Influence ofβ-cyclodextrin as an encapsule and as an inclusion complex dopant on conducting polyaniline

An investigation on the effect ofβ-cyclodextrin (CD) in both free and inclusion-complexed forms with a guest anionic metal complex, dioxalatodiaquochromate(III) (DDC), on the characteristics of conducting polyaniline (PANI) is carried out. Four materials, PANI (i.e. PANI-SO ₄ ²⁻ ), PANI-DDC, PANI-CD and PANI-CD + DDC were prepared byin situ chemical oxidative polymerization in aqueous H ₂SO₄ at pH 1 and subjected to electrical conductivity and spectral (IR and UV-vis bd measurements. DDC and CD when separately incorporated, reduce the conductivity of PANI by about half whilst their inclusion complex CD + DDC enhances it. Spectral characterization reveals that DDC as a dopant and CD as an encapsule exhibit their effects through adverse interaction with imine-amine N centres and benzenoid moiety of PANI. The inclusion complex CD + DDC, on the contrary, functions as a dopant by lying in between the chains and seems to promote the extended conformation of PANI chain and hence theπ -electron delocalization. Exposure of the material to methanol vapour causes a decrease in conductivity in PANI and PANI-CD while an increase in PANI-CD + DDC. This study makes explicit the distinct role of CD as an encapsule and CD + DDC inclusion complex as a dopant in altering the electrical property of PANI.     

Modified stiffness formulation of unbalanced anisotropic sandwich plates

An approximate formulation is presented for the analysis of sandwich plates consisting of an orthotropic core and two unequal thickness anisotropic face plates. The method uncouples the membrane and bending actions, thereby significantly reducing the effort involved in accurately predicting displacements and stresses. Defining modified stiffnesses, the formulation is valid for relatively thick anisotropic laminated face plates and can be combined with a variety of analysis techniques. Using a series solution, results are generated herein for simply supported sandwich plates with unbalanced cross-ply and angle-ply faces.     

Tuning PI controllers for stable processes with specifications on gain and phase margins

In industrial practice, controller designs are performed based on an approximate model of the actual process. It is essential to design a control system which will exhibit a robust performance because the physical systems can vary with operating conditions and time. Gain and phase margins are well known parameters for evaluating the robustness of a control system. This paper presents a tuning algorithm to design and tune PI controllers for stable processes with a small dead time while meeting specified gain and phase margins. Simulation examples are given to demonstrate that the proposed design method can result, in a closed-loop system, in better performances than existing design methods which are also based on user-specified gain and phase margins.     

Quality evaluation model using loss function for multiple S-type quality characteristics

Most of the studies of quality system or product-quality assessment deal with a single quality characteristic to determine the quality loss. Products are often assessed on more than one quality characteristic. For this reason, different multivariate quality loss functions have been proposed. However, these loss functions only consider the nominal-the-best quality characteristics (N-type); they do not consider the condition when the quality characteristics are of the smaller-the-better (S-type). In this article, we present a quality evaluation model using loss function for multiple S-type quality characteristics. A numerical example is illustrated showing that using inappropriate loss functions will lead to inaccurate results that give either an underestimate or overestimate of the expected quality costs.     

New Beta-lactamases in Candidate Phyla Radiation: Owning Pleiotropic Enzymes Is a Smart Paradigm for Microorganisms with a Reduced Genome

The increased exploitation of microbial sequencing methods has shed light on the high diversity of new microorganisms named Candidate Phyla Radiation (CPR). CPR are mainly detected via 16S rRNA/metabarcoding analyses or metagenomics and are found to be abundant in all environments and present in different human microbiomes. These microbes, characterized by their symbiotic/epiparasitic lifestyle with bacteria, are directly exposed to competition with other microorganisms sharing the same ecological niche. Recently, a rich repertoire of enzymes with antibiotic resistance activity has been found in CPR genomes by using an in silico adapted screening strategy. This reservoir has shown a high prevalence of putative beta-lactamase-encoding genes. We expressed and purified five putative beta-lactamase sequences having the essential domains and functional motifs from class A and class B beta-lactamase. Their enzymatic activities were tested against various beta-lactam substrates using liquid chromatography-mass spectrometry (LC-MS) and showed some beta-lactamase activity even in the presence of a beta-lactamase inhibitor. In addition, ribonuclease activity was demonstrated against RNA that was not inhibited by sulbactam and EDTA. None of these proteins could degrade single- and double-stranded-DNA. This study is the first to express and test putative CPR beta-lactamase protein sequences in vitro. Our findings highlight that the reduced genomes of CPR members harbor sequences encoding for beta-lactamases known to be multifunction hydrolase enzymes.     

Spectrophotometric Study of α-Nitroso-β-naphthol and its 3,6-disulphonic acid (nitroso-R-Salt)

The U. V. and visible absorption spectra of α-nitroso-β-naphthol and nitroso-R-salt are recorded in solutions of varying pH. The U. V. bands are assigned to π → π* transition within the aromatic system while the visible bands are assigned to intramolecular charge transfer. The pK of both compounds are determined from spectrophotometric and pH measurements.