Heterogeneous acid catalytic esterification by porous polyoxometalate-tantalum pentoxide nanocomposites

Polyoxometalates (POMs) are useful catalysts in both redox and acid catalysis reactions since its catalytic features can be controlled at a molecular level. We investigated POM (POM = H₃PW₁₂O₄₀) on tantalum pentoxide (Ta₂O₅) via hydrolysis of tantalum pentachloride (TaCl₅) in the presence of POM using the sol-gel method for acid catalytic reaction. All obtained amorphous materials have been characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES), Fourier transform infrared (FT-IR) spectra, Raman scattering spectroscopy, ³¹P magic-angle spinning (MAS) NMR, field emission scanning electron microscopy (FESEM), and nitrogen adsorption/desorption analysis, in order to confirm the structure integrity of the Keggin unit in as-prepared composites and investigate the morphology and surface textural property of the composites. Catalytic activity of the catalysts has been evaluated for esterification of acetic acid with ethanol as a model reaction with different catalytic reaction parameters such as POM loading, reaction time, catalyst dose, molar ratio of the reactants, etc. The conversion of ethanol reached 87.4 % and the turnover frequency (TOF) was 2.9×10³.Meanwhile, it is easy to separate and recover POM/Ta₂O₅ from the reaction system.     

An interpolation model to accelerate the frequency-domain response calculation of grounding systems using the method of moments

The transient characteristics of grounding systems are essential for their designs and related electromagnetic-compatibility problems in power systems. Although the method of moments (MoM) is a popular way to analyze the characteristics of grounding systems, it is time-consuming. In this paper, a two-stage method is presented to construct fitted models of the frequency-domain responses of grounding systems to accelerate the calculations of the MoM. In the first stage, the adaptive model-based parameter estimation is used to adaptively choose the most valuable frequency sampling points to construct the initial fitted functions, and then the fitted functions are adjusted in the second stage by comparing the fitted results with those computed by the first principle model at some points. The validation was achieved by a comparison of the numerical results and those obtained by inverse fast Fourier transformation.     

石墨炉原子吸收测定化探样品中痕量金的研究

采用以王水分解样品,泡沫塑料富集,硫脲解脱,石墨炉原子吸收分光光度计测定微量金。研究了测定时干燥温度和时间的选择,原子化温度和时间的选择,灰化温度和时间的选择,以及王水体积分数对吸附效果等条件对测定结果的影响。该方法检出限为0.2×10-9,经国家一级分析标准样品验证,结果与标准值相符。     

光传送网的未来发展探讨

文章从网络结构与拓扑两个方面，重点对下一代光传送网进行了探讨，具体介绍了新兴的光传送网——自动交换光网络(ASON)结构及其关键协议，并从运营商和设备商两个不同角度，较为深入地探讨了现有网络向ASON过渡时所采用的策略。     

基于广域测量的系统电压崩溃点预测

许多文章对电力系统电压崩溃问题进行了研究，其中潮流分析的方法是最常见的，大都是以Q—V曲线为基础。近些年，越来越多的人认识到电力系统电压稳定问题是一个动态问题，而电压崩溃点是可以提前预知的。随着GPS(全球定位系统)和PMU(向量测量单元)的进一步应用，广域测量技术应用范围越来越广，其用在电力系统电压崩溃点的预测也将成为必然。本文以广域测量技术为辅助手段，根据功率边缘的概念，使用电压崩溃预洲器来预洲系统中电压崩溃点的位置。     

Fluxing Agents on Ceramification of Composites of MgO-Al<Subscript>2</Subscript>O<Subscript>3</Subscript>-SiO<Subscript>2</Subscript>/Boron Phenolic Resin

Fluxing agents of zinc borate, antimony oxide, galss frit A and glass frit B, with different melting or softening point temperatures, were added into MgO-Al₂O₃-SiO₂/boron phenol formaldehyde resin (MAS/BPF) composites to lower the formation temperature of eutectic liquid phase and promote the ceramification of ceramifiable composites. The effects of fluxing agents on the thermogravimetric properties, phase evolution, and microstructure evolution of MAS / BPF composites were characterized by TG-DSC, XRD and SEM analyses. The results reveal that the addition of a fluxing agent highly reduces the decomposition rate of MAS / BPF composites. Fluxing agents lower the formation temperatures of liquid phases of ceramifiable MAS / BPF composites obviously, and then promote the ceramification and densification process. The final residues of composites are ceramic surrounded by large amount of glass phases.     

高碳铬铁降碳探讨

介绍了在12 5MVA电炉上进行高碳铬铁降碳的试验情况 ,分析了影响FeCr67C6 0合金含碳量的因素 ,从理论和实践两方面阐述了降碳措施