The First Study of SCR of NO x by Acetylene in Excess Oxygen

Acetylene as a reducing agent for the selective catalytic reduction (C₂H₂-SCR) of NO in the presence of excess oxygen on various Ce-exchanged zeolites was investigated for the first time. Under the conditions of 1600 ppm NO, 800 ppm C₂H₂, and 9.95 % O₂ in He, the Ce-H-ZSM-5 (Si/Al=25) catalyst shows about 83% NO conversion to N₂ at the temperatures ranged from 300 to 350 °C. It is followed by the other zeolites in the activity order of Ce-H-Y (Si/Al=2.5), Ce-H-_ (Si/A1=20∼30), and Ce-H-SAPO (Si/Al=34), Ce-H-5A (Si/Al=12). Almost no NO conversion was obtained over Ce-Na-ZSM-5 (Si/Al=25) and Na-ZSM-5 (Si/Al=25) catalyst samples. The Conversion of NO to N₂ increased with O₂ concentration in the range of 0.1 ∼ 9.95% over the CeH-ZSM-5 (Si/Al=25) catalyst. It is suggested that O₂ plays an important role in the C₂H₂-SCR of NO reaction, by oxidizing NO to NO₂ on acid sites in assistant with cerium species of the catalyst. A large amount of CO, which seems to be in proportion with the NO conversion to N₂, was produced. Long-term experiments up to 56 h combined with a excursion of the reaction temperature up to 650 °C over the Ce-H-ZSM-5 (Si/A1=25) confirmed the catalyst’s durable performance under the reaction conditions. It is found that the de-NO_x activity of Ce-H-ZSM-5 catalyst can be enhanced by the presence of 50 ppm of sulfur dioxide in the dry-feed reaction conditions.     

Trusted Integrated Circuits: The Problem and Challenges

Hardware security has become more and more important in current information security architecture. Recently collected reports have shown that there may have been considerable hardware attacks prepared for possible military usage from all over the world. Due to the intrinsic difference from software security, hardware security has some special features and challenges. In order to guarantee hardware security, academia has proposed the concept of trusted integrated circuits, which aims at a secure circulation of IC design, manufacture and chip using. This paper reviews the main problems of trusted integrated circuits, and concludes four key domains of the trusted IC, namely the trusted IC design, trusted manufacture, trusted IP protection, and trusted chip authentication. The main challenges in those domains are also analyzed based on the current known techniques. Finally, the main limitations of the current techniques and possible future trends are discussed.     

网络化雷达协同抗欺骗式干扰技术研究进展

网络化雷达在战场上可以构成全方位、立体化、多层次的战斗体系,因 此对欺骗式干扰对抗具有很大的优越性。本文首先简要介绍了网络化雷达概念,并分析了其 抗干扰优势。根据网络化雷达融合结构不同,将现有协同抗干扰方法分为数据级融合抗欺骗 式干扰和信号级融合抗欺骗式干扰两大类,其中,数据级融合方法进一步分类为点迹关联和 航迹关联两类。本文对各类方法进行了详细介绍,在此基础上,比较分析了数据级融合和信 号级融合两类方法的抗干扰性能及算法复杂度,为抗干扰措施的选择提供依据。最后,针对 现有方法中存在的问题,对网络化雷达协同抗欺骗式干扰的发展趋势进行展望,指出下一步 的研究方向。     

腐植酸物质对盐碱化中低产田土壤理化性质及玉米影响的研究

通过田间试验探讨了复合改良制剂、草炭、风化煤等腐植酸类物质施用对盐碱化中低产田土壤理化性质及生长作物的影响，结果表明：复合改良制剂、草炭、风化煤施用对土壤理化性质均有积极的影响，与对照相比达到显著水平。玉米产量的方差分析表明，复合改良制剂处理与草炭、风化煤等处理差异显著，与对照差异极显著，增产率均达到30．67％以上。     

高强度聚乙烯纤维绳索的制备研究

研究了纤维的捻度及浸胶处理对超高相对分子质量聚乙烯 (UHMWPE)纤维力学性能及摩擦磨损性能的影响。结果表明 ,UHMWPE纤维的断裂强力随着纤维捻度的增加而减小 ,纤维浸胶处理后的断裂强力增大 ;当UHMWPE纤维中改性氯丁胶粘剂或聚氨酯胶粘剂的含量为 6%时 ,其断裂强力分别增加 17.2 %或 13 .9% ,聚氨酯胶粘剂处理过的UHMWPE纤维的耐摩擦磨损性能最好。     

施釉机器人静力学分析的研究

根据6自由度施釉机器人的终端受力，利用雅可比矩阵，求解出各转动关节在稳定平衡状态下的受力和所需的驱动力矩，为设计施釉机器人确定各转轴的电机及其他动力元件提供了可靠的依据。     

煤矸石对硅酸盐水泥水化历程的影响

从强度、反应程度、孔溶液碱度和SEM等方面,研究了煤矸石作为水泥辅助胶凝材料的水化情况,并与Ⅱ级粉煤灰进行比较。试验结果表明:煤矸石发生火山灰反应时间比粉煤灰早,且发生火山灰反应所需的碱度值比粉煤灰低;掺煤矸石水泥水化样的早期抗压强度比粉煤灰水泥水化样低,但7d到28d强度增长速率明显大于相同掺量的粉煤灰水泥,相同28d抗压强度的条件下,煤矸石掺量比粉煤灰的掺量高10%。     

我国塑料助剂生产现状与发展趋势

简述了我国塑料助剂生产现状、市场供需及发展方向，“十五”期间我国塑料助剂工业发展势头强劲，目前已基本满足我国塑料工业的发展需求，但是在品种和产品质量等方面与国外先进水平相比仍有较大的差距。提出了提高我国塑料助剂国际市场竞争力的措施。     

Hydrothermal Synthesis and Characterization of KxNa(1−x)NbO3 Powders

NaNbO₃, KNbO₃, and K _x Na_{(1− x )}NbO₃ powders were successfully prepared by the hydrothermal method. The phase of the products was identified to be orthorhombic structure by X-ray diffraction (XRD) technique, and the XRD results revealed that the x value of the K _x Na_{(1− x )}NbO₃ gradually increased with the increase in the ratio of K⁺ to Na⁺ in alkaline solution. The morphology and the microstructure were investigated by scanning electron microscopy, energy-dispersive spectroscopy, and transmission electron microscopy, and the results indicated that the ratio of K⁺ to Na⁺ in the solution had a great effect on the morphology and the size of products. Na_0.5K_0.5NbO₃ with morphotropic phase boundary composition could be synthesized when the molar ratio of K⁺ to Na⁺ was between 4:1 and 6:1 in the solution. A possible formation mechanism of the K _x Na_{(1− x )}NbO₃ crystal was also proposed based on the experimental results.