A comparative study of physical properties in Fe3O4 nanoparticles prepared by coprecipitation and citrate methods

Magnetite exhibits unique structural, electronic, and magnetic properties in extreme conditions that are of great research interest. In this work, the effects of preparation technique on X‐ray peak broadening, magnetic and elastic moduli properties of Fe₃O₄ nanoparticles prepared by coprecipitation (FcP‐NPs) and citrate (FC‐NPs) methods have been investigated. The structural characterization of the samples is evidence for a cubic structure with Fd‐3m space group. The Williamson‐Hall analysis was used to study crystallite sizes and lattice strain of the samples and also stress and energy density. In addition, the crystallite sizes are compared with the particle sizes and the magnetic core sizes obtained from TEM and VSM methods, respectively. In addition, the cation distribution obtained from calculated inversion parameter indicate that in the smaller particles, more amount of Fe²⁺ on the tetrahedral sites can be related to higher stress induced in the FcP‐NPs compared to the FC‐NPs. The saturation magnetization of the FcP‐NPs is almost two times bigger than the saturation magnetization of the FC‐NPs. It could be attributed to the decrease in the negative interaction on the octahedral site and also the magnetic moment on the tetrahedral site of the FcP‐NPs. The increase in force constants of the FC‐NPs determined by infrared spectra analysis compared to FcP‐NPs suggests the strengthening of their interatomic bonding. The values of shear and longitudinal wave velocities obtained from force constants have been used to determine the values of Young's modulus, rigidity modulus, bulk modulus, and Debye temperature. By comparison of the elastic results of FC‐NPs with the FcP‐NPs, we can observe that the elastic properties of the F‐NPs have been improved by synthesis method, while Poisson's ratio almost remains constant. In addition, using the values of the compliance s_ij obtained from elastic stiffness constants, the values of Young's modulus and Poisson's ratio along the oriented direction [hkl] have been calculated for the samples.     

Nanoencapsulation of montmorillonite clay within poly(ethylene glycol) nanobeads by electrospraying

The present study describes the preparation and characterization of a novel nanocomposite, based on montmorillonite clay (MMT) encapsulation in poly(ethylene glycol) (PEG) by an electrospraying process. PEG/MMT nanocomposites with MMT contents ranging from 1 to 5 wt % were successfully prepared and characterized in relation to their morphological, spectroscopic, structural, and thermal properties. Scanning electron microscopy, transmission electron microscopy, and atomic force microscopy micrographs showed that the PEG nanobeads formed spherical shapes, and with increasing amount of MMT clay, the size of the beads decreased significantly, ranging from 120 to 3.7 nm. The Fourier transform infrared spectroscopy results suggested that there was no significant chemical interaction between PEG and MMT clay. However, the d‐spacing of MMT clay in PEG/MMT increased, a clear indication of the intercalation of PEG in the interlayer spaces of MMT clay. Furthermore, the thermal stability of PEG polymer decreased upon encapsulation of MMT clay in PEG/MMT composites. Nanoindentation results showed that the hardness and Young's modulus of the PEG/MMT composites increased with 3 wt % loading of MMT. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45048.     

Lignin‐based carbon fibers: Accelerated stabilization of lignin fibers in the presence of hydrogen chloride

Organosolv switchgrass lignin (SGL) and hardwood lignin (HWL) polymers are used as precursors to prepare low cost carbon fibers (CFs). Lignin powder and fiber samples are stabilized and carbonized at different conditions to investigate the effect of HCl on thermal‐oxidative stabilization time, mass yield, fiber diameter, and mechanical properties. The results show that HCl can accelerate stabilization and reduce the stabilization time from many hours to 75 min for the SGL fibers, and to 35 min for the HWL fiber. The rate of rapid stabilization in HCl/air is at least four times faster than conventional stabilization in air. The CFs prepared with two different stabilization methods have almost the same strength and modulus, but higher carbon yield is obtained with the rapid stabilization due to a short time of oxidation. Pores and defects observed on the surface and the cross‐section of the CFs across all stabilization conditions contribute to low fiber strength. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45507.     

Microwave-assisted preparation of mesoporous-activated carbon from coconut (Cocos nucifera) leaf by H3PO4 activation for methylene blue adsorption

Mesoporous-activated carbon was prepared from fallen coconut (Cocos nucifera) leaf, an agricultural waste through a microwave-induced H₃PO₄ activation process. The characterization of the coconut leaf–activated carbon (CAC) was evaluated through the iodine number, ash content, bulk density, and moisture content. Fourier transform infrared spectroscopy, scanning electron microscope, Brunauer–Emmett–Teller (BET) surface area, X-ray diffraction, and pH_PZC. CAC has a mesopore content of 84% with an average pore size of 36.5?Å and a large BET surface area of 632?m²/g. The uptake properties of the CAC with methylene blue was evaluated at different CAC dosage levels (0.2–10?g/L), initial pH (3–10), methylene blue concentration (50–350?mg/L), and time (0–360?min) using batch mode operation. The kinetic profiles were described by the pseudo-second-order kinetics. The equilibrium data were well fitted to the Langmuir model with a maximum monolayer adsorption capacity of 250?mg/g at 30°C. Thermodynamic functions indicate a spontaneous and exothermic nature of the adsorption process. This study indicates that coconut leaves are a promising renewable precursor that can be utilized to develop an efficient mesoporous-activated carbon.     

Performance of fly ash based polymer gels for water reduction in enhanced oil recovery: Gelation kinetics and dynamic rheological studies

The complexity of well and reservoir conditions demands frequent redesigning of water plugging polymer gels during enhanced oil recovery (EOR). In the present study, we developed coal fly ash (CFA) based gels from polyacrylamide (PAM) polymer and polyethyleneimine (PEI) crosslinker for water control in mature oil fields. The CFA acts as an inorganic additive to fine-tune gelation performance and rheological properties of PAM/PEI gel system. Hence, effects of various CFA (0.5 to 2 wt%), PAM (2 to 8.47 wt%) and PEI (0.3 to 1.04 wt%) concentrations on gelation kinetics and dynamic rheology of pure PAM/PEI gel and PAM/PEI-CFA composite gels were studied at a representative reservoir temperature of 90 oC. Experimental results reveal that gelation time of pure PAM/PEI gel increases with increasing CFA addition. Further observation demonstrates that increasing PAM and PEI concentrations decreases the gelation times of PAM/PEI-CFA composite gels. Gelation time was found to be within 3-120 hours. Understanding the property of reaction order enables better prediction of gelation time. Dynamic rheological data show that viscoelastic moduli (G′ and G″) of various PAM/PEI-CFA composite gels improved better as compared to the pure PAM/PEI gel across the strain-sweep and frequency-sweep tests. SEM analysis of selected samples at 72 hours and 720 hours of gelation activity consolidated gelation kinetics and dynamic rheological results. These polymer gels are excellent candidates for sealing water thief zones in oil and gas reservoirs.     

Effect of support layer on gas permeation properties of composite polymeric membranes

PES/Pebax and PEI/Pebax composite membranes were prepared by coating the porous PES and PEI substrate membranes with Pebax-1657. The morphology and performance of the prepared membranes were investigated by SEM and CO₂ and CH₄ permeation tests. The CO₂ permeances of 28 and 52 GPU were achieved for PES/Pebax and PEI/Pebax composite membranes, respectively, with CO₂/CH₄ selectivities almost equal to that of Pebax (26). The experimental data were further subjected to a theoretical analysis using the resistance model. It was found that the porosity and the thickness of the dense section of PES substrate were an order of magnitude higher than those of PEI substitute. The porosity/thickness ratio of PEI substrate was, however, higher than PES, explaining the higher permeance of PEI/Pebax composite membrane. Substrates with porosities much higher than the Henis-Tripodi gas separation membrane were used in this work, aiming to achieve the selectivity of Pebax, rather than those of the substrate membrane materials.     

MDP-Based Network Selection Scheme by Genetic Algorithm and Simulated Annealing for Vertical-Handover in Heterogeneous Wireless Networks

The hybrid algorithm for real-time vertical handover using different objective functions has been presented to find the optimal network to connect with a good quality of service in accordance with the user’s preferences. Markov processes are widely used in performance modelling of wireless and mobile communication systems. We address the problem of optimal wireless network selection during vertical handover, based on the received information, by embedding the decision problem in a Markov decision process (MDP) with genetic algorithm (GA), we use GA to find a set of optimal decisions that ensures the best trade-off between QoS based on their priority level. Then, we emerge improved genetic algorithm (IGA) with simulated annealing (SA) as leading methods for search and optimization problems in heterogeneous wireless networks. We formulate the vertical handoff decision problem as a MDP, with the objectives of maximizing the expected total reward and minimizing average number of handoffs. A reward function is constructed to assess the QoS during each connection, and the AHP method are applied in an iterative way, by which we can work out a stationary deterministic handoff decision policy. As it is, the characteristics of the current mobile devices recommend using fast and efficient algorithms to provide solutions near to real-time. These constraints have moved us to develop intelligent algorithm that avoid the slow and massive computations. This paper compares the formulation and results of five recent optimization algorithms: artificial bee colony, GA, differential evolution, particle swarm optimization and hybrid of (GA–SA). Simulation results indicated that choosing the SA rules would minimize the cost function, and also that, the IGA–SA algorithm could decrease the number of unnecessary handovers, and thereby prevent the ‘Ping-Pong’ effect.     

Enhancement of Satellite Image Compression Using a Hybrid (DWT–DCT) Algorithm

Discrete Cosine Transform (DCT) and Discrete Wavelet Transform (DWT) image compression techniques have been utilized in most of the earth observation satellites launched during the last few decades. However, these techniques have some issues that should be addressed. The DWT method has proven to be more efficient than DCT for several reasons. Nevertheless, the DCT can be exploited to improve the high-resolution satellite image compression when combined with the DWT technique. Hence, a proposed hybrid (DWT–DCT) method was developed and implemented in the current work, simulating an image compression system on-board on a small remote sensing satellite, with the aim of achieving a higher compression ratio to decrease the onboard data storage and the downlink bandwidth, while avoiding further complex levels of DWT. This method also succeeded in maintaining the reconstructed satellite image quality through replacing the standard forward DWT thresholding and quantization processes with an alternative process that employed the zero-padding technique, which also helped to reduce the processing time of DWT compression. The DCT, DWT and the proposed hybrid methods were implemented individually, for comparison, on three LANDSAT 8 images, using the MATLAB software package. A comparison was also made between the proposed method and three other previously published hybrid methods. The evaluation of all the objective and subjective results indicated the feasibility of using the proposed hybrid (DWT–DCT) method to enhance the image compression process on-board satellites.     

Scanning electron and light microscopy of foliar epidermal characters: A tool for plant taxonomists in the identification of grasses

SEM and light microscopy are of special interest for biologist to observe various features of the living bodies. In the current study we observed the foliar epidermal micro‐morphological characters of 44 grass species using SEM and Light microscopy to assess their taxonomic utility for taxonomists in the identification process. The aim of this study is to use the foliar epidermal structural variations in both upper and lower surfaces for identification of grasses. Significant diversity was observed in both qualitative and quantitative characters using SEM and Light microscopy. Variations were observed in stomatal number, size, guard cells shape, silica bodies, macro‐hairs, micro‐hairs, epidermal cell number, subsidiary cells, prickles, hooks, papillae, and short and long cells. A taxonomic key is prepared using these variations for the identification of grass species. Based on these findings, SEM and Light microscopy of foliar epidermal features can be of special interest for taxonomists in the identification of complex grass taxa.     

A routing algorithm for reducing optical loss in photonic Networks-on-Chip

Driven by increase in automation, smart homes play an important role in today’s human life. This paper presents a new model for smart home technologies based on multi-device bidirectional visible light communication (VLC). For multiple devices and users, orthogonal code-based wavelength division (color beams) full-duplexed bidirectional VLC link is proposed. The color beams from RGB LEDs are utilized to transmit data and synchronize multi-device transmission. To enhance the performance of the proposed model, receiver diversity is also employed. Performance evaluation reveals that the proposed VLC-based model for smart homes is efficient with superior BER performance in a typical smart home environment except for the far corners. The maximum achievable data rate for each user up to four users is found to be 24 Mbps at both uplink and downlink transmissions.