超临界N_2微孔发泡PA6的制备及性能研究

采用超临界N2微孔发泡注射成型方法制备微孔发泡尼龙(PA)6材料,研究了注射温度、成核剂含量对泡孔密度、直径的影响。采用扫描电子显微镜考察了注射温度对泡孔大小、密度以及分布的影响。结果表明,随着注射温度的升高,泡孔直径变大,泡孔密度减小;成核剂含量增加泡孔密度变大,成核剂到达一定含量后泡孔密度增大不显著,成核剂含量对泡孔直径无显著影响。     

纳米级无机粒子对聚乙烯的增强与增韧

对μｍ级ＣａＣＯ３、ＴｉＯ２和ｎｍ级ＳｉＣ／Ｓｉ３Ｎ４粒子填充ＬＤＰＥ的性能进行了研究。实验证明，μｍ级粒子对ＬＤＰＥ虽无明显的增强增韧作用，但也未使基体的机械性能大幅度下降。ｎｍ级ＳｉＣ／Ｓｉ３Ｎ４对ＬＤＰＥ有较大的增强增韧作用，在５％质量分数时冲击强度出现最大值，缺口冲击强度达５５．７ｋＪ／ｍ２为纯ＬＤＰＥ的２０３％；伸长率到６２５％时仍未断裂，为纯ＬＤＰＥ的５００％，但熔体流动速率急剧下降，仅为纯ＬＤＰＥ的２６％，当含量在３％和１５％质量分数时，熔体流动速率分别为纯ＬＤＰＥ的３３７％和１５１％。     

活性白土负载SO4^2——Al2O3催化合成氯乙酸异丙酯

用活性白土负载SO4^2--Al2O3催化氯乙酸和异丙醇合成氯乙酸异丙酯,研究了各种因素对酯化率的影响,确定了反应的最佳条件：酸醇摩尔比为1：3,反应时间为5h,催化剂加入量为酸量的4％(m/m),反应温度为回流温度,酯化率可达90.6%。     

Male-Produced Aggregation Pheromone of Coffee Bean Weevil, <Emphasis Type="Italic">Araecerus fasciculatus</Emphasis>

The coffee bean weevil (CBW), Araecerus fasciculatus (De Geer, 1775), is a cosmopolitan stored-product pest, especially in tropical and subtropical areas. Previous reports showed evidence for aggregation behavior of CBW and this study aimed to identify and evaluate the aggregation pheromone of this pest. Whole-body solvent extractions were analyzed by coupled gas chromatography-mass spectrometry and comparison of male and female extracts showed a male-specific compound which was identified as squalene, 2,6,10,15,19,23-hexamethyl-2,6,10,14,18,22-tetracosahexaene. This compound was shown to attract male and female CBW in Y-tube olfactometer and storage trap assays. The longevity of septum lures was also evaluated in a warehouse. Squalene could be useful in monitoring and controlling this pest.     

生物无纺布反应器预处理黄河水的试验研究

利用自行研制的生物无纺布反应器对进入济南市鹊山水库一号泵站的黄河水进行了生物预处理试验研究。当水力负荷从2m3/(m2·h)增加到8m3/(m2·h)时,深入地探讨了生物无纺布对黄河水中的CODMn、NH4+-N、浊度、藻类、色度和SS的去除效果。试验结果表明,生物无纺布反应器能够有效地去除黄河水中的CODMn、NH4+-N等污染物质,是解决水源水微污染的有效预处理工艺。     

Long Crack R-Curve of Aligned Porous Silicon Nitride

Long crack R -curve of a porous Si₃N₄ with aligned fibrous grains was investigated, using a chevron-notched beam technique. A crack was constrained to propagate normal to the grain alignment. The crack growth resistance of aligned porous Si₃N₄ was much larger compared with that of dense Si₃N₄ ceramics. Microstructure observations showed that pullouts of fibrous grains in aligned porous Si₃N₄ markedly increased during crack propagation relative to those of dense Si₃N₄, due to the existence of pores. The efficient grain pullouts in porous Si₃N₄ increased the bridging stress at the crack wake.     

微生物诱导的矿化及其在油气工业的应用

微生物诱导的矿化沉淀是自然界中存在的一种普遍现象,并且碳酸盐沉淀是微生物诱导矿化的一种形式。微生物代谢活动所产生的碳酸盐沉淀,在二氧化碳封存、封堵大孔道来提高原油采收率方面具有重要的作用。常见的诱导碳酸盐沉淀的生物包括蓝藻,巴斯德孢子菌,硫酸盐还原菌,尿素分解菌,硝酸盐还原菌,产甲烷菌等,这些微生物诱导碳酸盐沉淀的潜在机理包括微生物的自身代谢活动改变沉淀环境,微生物菌体及胞外聚合物吸引离子来诱导沉淀。根据代谢类型不同,微生物诱导碳酸钙沉淀的作用类型以分为光合作用、硫酸盐还原、反硝化、氨化、甲烷氧化等。本文综述了自然条件下微生物诱导的碳酸盐沉淀的一些潜在机理,以及与沉淀过程相关的微生物的主要类型及其所处的自然环境,着重探究了微生物诱导的碳酸盐沉淀在石油工业的应用及这项技术所面临的挑战和未来展望。     

Iodothiocyanation/Nitration of Allenes with Potassium Thiocyanate/Silver Nitrite and Iodine

Direct strategies for the iodothiocyanation and iodonitration of allenes have been developed. In this process, potassium thiocyanate/silver nitrite and molecular iodine are used as the source of SCN, ONO₂ and iodine to provide the desired products in moderate to good yields with high stereoselectivity.

     

Microbial fuel cell-based sensor for Enterobacter sp. KBH6958 activity monitoring during hydrogen production: the effects of pH and glucose concentration

Journal of Applied Electrochemistry - A microbial fuel cell (MFC) is an electricity-generating device utilising electrochemically active microorganisms as biocatalysts. Using MFC as a biosensor to...     

硬质合金烧结技术的发展

硬质合金问世以来,其烧结工艺技术的发展经历了好几个阶段。本文就这些阶段的主要内容进行介绍,并对其先进性和不足方面的问题进行比较。目的旨在促进各硬质合金厂家根据自己的实际情况,选择适当的烧结工艺和装备。