Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4:Eu

It has been found that charge compensated CaMoO₄:Eu³⁺ phosphors show greatly enhanced red emission under 393 and 467 nm-excitation, compared with CaMoO₄:Eu³⁺ without charge compensation. Two approaches to charge compensation, (a) 2Ca²⁺ → Eu³⁺ + M⁺, where M⁺ is a monovalent cation like Li⁺, Na⁺ and K⁺ acting as a charge compensator; (b) 3Ca²⁺ → 2Eu³⁺ + vacancy, are investigated. The influence of sintering temperature and Eu³⁺ concentration on the luminescent property of phosphor samples is also discussed.     

Liquid Letters

Using the interfacial jamming of cellulose nanocrystal (CNC) surfactants, a new concept, termed all‐liquid molding, is introduced to produce all‐liquid objects that retain the shape and details of the mold with high fidelity, yet remain all liquid and are responsive to external stimuli. This simple process, where the viscosity of the CNC dispersion can range from that of water to a crosslinked gel, opens tremendous opportunities for encapsulation, delivery systems, and unique microfluidic devices. The process described is generally applicable to any functionalized nanoparticles dispersed in one liquid and polymer ligands having complementary functionality dissolved in a second immiscible liquid. Such sculpted liquids retain all the characteristics of the liquids but retain shape indefinitely, very much like a solid, and provide a new platform for next‐generation soft materials.     

组成、粘度比及加工条件对PB／CS共混物粘度和形态的影响

研究了组成、粘度比、转速和混合时间对聚丁烯／玉米浆共混物的粘度和形态的影响。结果表明，共混物的粘度均随转速的提高而增大。在高转速下，８０／２０共混物的粘度比其它组成的共混物的粘度增长迅速。在聚丁烯和玉米浆的界面观察到复合乳化结构。分散相液滴尺寸较小时，液滴尺寸的变化对共混物的粘度有很大的影响。     

Grain‐Boundary “Patches” by In Situ Conversion to Enhance Perovskite Solar Cells Stability

The power conversion efficiency of organic–inorganic hybrid perovskite solar cells has increased rapidly, but the device stability remains a big challenge. Previous studies show the grain boundary (GB) can facilitate ion migration and initiate device degradation. Herein, methimazole (MMI) is employed for the first time to construct a surface “patch” by in situ converting residual PbI₂ at GBs. The resultant MMI–PbI₂ complex can effectively suppress ion migration and inhibit diffusion of the metal electrodes. The origin of the surface “patch” effect and their working mechanisms are investigated experimentally and theoretically at the microscopic level. It hence demonstrates a simple and effective method to prolong the device stability in the context of GB engineering, which could be extensively applied to perovskite‐based optoelectronics.     

水中油分浓度分析仪新旧检定规程的比较

本文通过比较新旧规程,从规程适用范围、通用技术要求、计量器具控制、计量性能要求等解读其中的主要异常。     

煤与PVC共热解固体产物在燃烧中氯的释放特性

通过实验研究了煤与PVC共热解固体产物燃烧时氯的释放特性,结果表明,氯的释放量（率）与燃烧温度、煤与PVC共热解的温度以及共热解时PVC的加入量有关．燃烧温度越高,氯的释放率越大,900℃燃烧时,氯的释放率都在94％以上;热解温度越高。在同一温度燃烧时,氯的释放率越低．400℃时焦中氯的最高释放率达99．86％,而1000℃时焦中氯的最高释放率为94．35％．     

基于工业以太网的动态通信平滑过滤器研究

针对工业控制系统的特点,在不改变以太网协议的条件下,采用一种新的动态通信平滑过滤器来控制网络负荷以满足控制系统的实时通信要求.研究表明该动态通信平滑过滤器不仅可以为非实时数据提供合理的网络吞吐率,并且可以显著地控制实时数据传输的超时比率,其性能明显优于静态通信平滑过滤器.