聚丙烯酸钠类高吸水性树脂的研究

采用反相悬浮聚合法合成高吸水性树脂.将丙烯酸(单体,水相)用氢氧化钠部分中和,然后与环己烷(溶剂,油相)共混,用水溶性的过硫酸钾做引发剂,N,N-亚甲基双丙烯酰胺做交联剂,在一定的反应温度和时间下,得到聚丙烯酸钠高吸水性树脂.     

基于FLUENT软件的管式搅拌反应器流场的数值模拟

运用商业计算流体力学(CFD)软件FLUENT对一种新型管式搅拌反应器进行流场模拟,用GAMBIT建立流场实体模型,采用标准k-ε湍流模型以及多重参考系法(MRF)处理搅拌桨区.结果表明,计算所选模型能较准确地预测搅拌反应器的速度场、压力场及湍流动能分布,考察流量为1 m3/h时不同搅拌转速对反应器内部混合的影响,此时对应的最佳搅拌转速为50 rpm左右.模拟结果将为实验研究提供适当的操作参数,对搅拌反应器的优化和放大具有一定参考价值.     

高柔韧性尼龙1010材料的制备

对尼龙1010/NBR/增塑剂体系进行了系统研究,发现在挤出机中环氧扩链剂可以对尼龙进行扩链反应,且环氧树脂对尼龙1010的扩链反应活性较高,扩链效果比较明显;N-丁基苯磺酰胺是尼龙的良好增塑剂,经增塑、增韧后可以使经扩链后的尼龙1010柔韧性有明显提高.采用SEM和TEM对所制备的材料进行了形貌分析,发现用NBR增韧尼龙,对于不同的基体材料,橡胶粒子的形貌有很大不同,粒子由增韧纯尼龙的椭球形变为在增塑尼龙基体中不规则的形状.     

氩等离子体辐照反相乳液接枝改性涤纶织物的研究

首次提出了在等离子体辐照后再用反相乳液接枝改性涤纶织物的新方法,探讨了接枝颗粒特征以及织物各项物理力学性能.接枝织物的结构及性能的测试结果表明:接枝物的尺寸远小于纤维的直径,在提高织物吸湿性的同时,对织物透气性能和强力等无明显影响;实验也证实了乳液中未接枝单体可以再次聚合.     

Asymmetric Regulation System Fit for Chinese Telecom Market

After the new round of restructuring of Chinese telecom sector,it's pressing to formulate and implement asymmetric regulation policies so as to shape an effectively competitive market structure in a relatively short term.This paper reviewed the asymmetric regulation policies and practices carried out in foreign telecom market,and then according to the specific situations of Chinese telecom market,proposed the principles and corresponding policies for establishing an asymmetric regulation system fit for Chin...     

校长要努力营造校内和谐的人际关系氛围

校长是国家教育方针的执行者,是学校行政工作的主帅,是学校活动的组织者、指挥者、协调者.如何正确处理校内人际关系,营造一个校内宽松、和谐、民主的人际环境,是校长工作中的重要环节,是能否调动校内一切积极因素、凝心聚力,形成正向合力必不可少的条件.     

Phase transition of LCP fluids confined in nanochannels through MD simulation

Manipulation of molecular orientation alignment in MCTLCPs (main-chain thermotropic liquid crystalline polymers) by pure shear at nano scale has been investigated for the first time using molecular dynamics (MD) simulation. Results indicate that high planar shear induces long-range uniform orientation ordering (liquid crystalline phase) of initially randomly orientated molecules of MCTLCP fluid confined in a nanochannel, which is confirmed by analyzing the orientation order parameter and the snapshots of MCTLCP liquid in a nanochannel under different shear rates. Insights into the origin of the phase transition phenomena are given at molecular level through investigating the thermodynamic density distribution of MCTLCP molecules in the nanochannel, suggesting that the energy shift due to a radical jump of system density affects both the magnitude and the orientation of the molecular ordering. Simulation results also show that there is a critical shear rate for transforming isotropic phase into liquid crystalline phase. The critical shear rate is dependent on the temperature of the MCTLCP system. Findings in this paper may present useful information for processing TLCP molecules at nano scale and the understanding of nanoflow.     

Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).