用红外分光光度法定量分析 PVC 电缆粒料中双酚 A 抗氧剂的含量

本工作建立了一种红外光谱定量测定 PVC 电缆粒料中双酚 A 的方法。     

闭式冷却塔中空气与喷淋水同向和逆向流动的流阻试验研究

一些高效逆流闭式冷却塔盘管管外的空气流动和喷淋水的流动方向相同(顺流),其空气流动阻力的规律性尚待进一步探索,本文对此进行了试验研究。设计构建了相关的试验装置、试验件,进行了一系列的试验。为便于对比,分别针对盘管管外的空气流动和喷淋水的流动方向同向以及逆向(逆流)进行了试验。通过改变喷淋水的喷淋量和空气的流速,得到了相关的空气流动阻力的规律性。试验表明,顺流型式比逆流型式的空气流动阻力大为降低,逆流型式存在空气流动阻力的突增点,顺流型式不存在阻力的突增点。     

Fluorescent Imaging‐Guided Chemotherapy‐and‐Photodynamic Dual Therapy with Nanoscale Porphyrin Metal–Organic Framework

Imaging‐guided therapy systems (IGTSs) are revolutionary techniques used in cancer treatment due to their safety and efficiency. IGTSs should have tunable compositions for bioimaging, a suitable size and shape for biotransfer, sufficient channels and/or pores for drug loading, and intrinsic biocompatibility. Here, a biocompatible nanoscale zirconium‐porphyrin metal–organic framework (NPMOF)‐based IGTS that is prepared using a microemulsion strategy and carefully tuned reaction conditions is reported. A high content of porphyrin (59.8%) allows the achievement of efficient fluorescent imaging and photodynamic therapy (PDT). The 1D channel of the Kagome topology of NPMOFs provides a 109% doxorubicin loading and pH‐response smart release for chemotherapy. The fluorescence guiding of the chemotherapy‐and‐PDT dual system is confirmed by the concentration of NPMOFs at cancer sites after irradiation with a laser and doxorubicin release, while low toxicity is observed in normal tissues. NPMOFs are established as a promising platform for the early diagnosis of cancer and initial therapy.     

Yolk–Shell MnO@ZnMn2O4/N–C Nanorods Derived from α‐MnO2/ZIF‐8 as Anode Materials for Lithium Ion Batteries

Manganese oxides (MnO_x) are promising anode materials for lithium ion batteries, but they generally exhibit mediocre performances due to intrinsic low ionic conductivity, high polarization, and poor stability. Herein, yolk–shell nanorods comprising of nitrogen‐doped carbon (N–C) coating on manganese monoxide (MnO) coupled with zinc manganate (ZnMn₂O₄) nanoparticles are manufactured via one‐step carbonization of α‐MnO₂/ZIF‐8 precursors. When evaluated as anodes for lithium ion batteries, MnO@ZnMn₂O₄/N–C exhibits an reversible capacity of 803 mAh g^?1 at 50 mA g^?1 after 100 cycles, excellent cyclability with a capacity of 595 mAh g^?1 at 1000 mAg^?1 after 200 cycles, as well as better rate capability compared with those non‐N–C shelled manganese oxides (MnO_x). The outstanding electrochemical performance is attributed to the unique yolk–shell nanorod structure, the coating effect of N–C and nanoscale size.     

柞蚕场管理制度改革初探

大堡蒙古族乡位于凤城市的中东部,素有“八山一水半分田,半分道路和庄园”之称,雨量充沛,气候适宜;全乡有柞林面积129318亩,其中柞蚕场面积68342亩;柞蚕场面积占全乡柞林面积的52．8％,全乡年放养柞蚕五百把左右;蚕业收入占农业总收的8％-12％。     

Effect of ligand passivation on morphology,optical and photoresponse properties of CdS colloidal quantum dots thin film

In the present report, cadmium sulfide (CdS) colloidal quantum dots (CQDs) with average diameter of 6 nm were synthesized by using oleylamine as ligand and solvent. The insulating oleylamine ligands form barriers around the CdS CQDs to decrease carrier mobility. In order to remove the ligands and improve the photoelectrical properties of the closed-packed film, ethanedithiol, mercaptopropionic acid and cetyltrimethylammonium bromide (CTAB) were applied for solid state ligand exchange. CTAB treated film had the fastest 3 dB bandwidth of 144.7 Hz and yielded the highest detectivity of 1.37 × 10⁸ Jones. The excellent properties of ligand passivation have important application in nanocrystals based electronic and optoelectronic devices.     

Therapy for cerebral ischemic injury with erythropoietin-containing nanoparticles

In this study we prepared nanocarrier of erythropoietin (EPO) and the curative effect of the EPO-containing nanoparticles for periventricular leukomalacia (PVL) model was validated. It was demonstrated that EPO-containing nanoparticles can ameliorate drug-induced liquefaction caused by hypoxia. EPO-containing nanomedicine may open new therapeutic strategies in hypoxia cure.