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31.
Hiroyuki Sasakura Yoshiya Akagi Shigeki Tsukui Takashi Oka Motoaki Adachi 《Journal of Superconductivity and Novel Magnetism》2007,20(5):381-386
Bi-based superconducting compounds with the 2222 structure has been already synthesized in the Bi2Sr2- (Ln1−x
Ce
x
)2Cu2O10+y
(Ln = Sm, Eu, and Gd) systems. One of the characteristics of these compounds is the existence of the fluorite-like (Ln1−x
Ce
x
)2O2 block between two CuO5 pyramids in the crystal structure. The tetravalent ions of Ce4+ are reported to be necessary to stabilize the 2222 structure. Recently, we have discovered that the Bi-2222 phase could be
composed in the Bi2Sr2(Ln2−x
Zr
x
)Cu2O
z
(Ln = Sm, Eu, Gd, and Dy) systems, where Zr4+ is used as a new tetravalent ion stabilizing the 2222 structure in stead of Ce4+. In the new system, nearly single 2222 phase samples have been obtained at the nominal composition of x=0.5 (Ln = Sm, Eu, and Gd) and in the range of 0.1≤x≤0.3 (Ln = Dy). Among them, the sample with Ln = Gd has the smallest resistivity at 273 K. But it is a semiconductor, and
the conduction process at low temperatures is assumed to be followed by a two-dimensional VRH. The experimental results for
the Gd samples with a partial substitution of Pb for Bi in the Bi2Sr2(Gd2−x
Zr
x
)Cu2O
z
system are also reported. 相似文献
32.
Takeshi Ohgai Masayuki Mizumoto Shigeki Nomura Akio Kagawa 《Materials and Manufacturing Processes》2007,22(4):440-443
A nuclear track etched polycarbonate membrane filter with numerous cylindrical nanopores was applied as a nanoporous template for growing metallic nanowires. Nickel, cobalt, and iron nanowires were electrodeposited into the cylindrical nanopores. Cathodic polarization curves were measured to determine an optimum condition for growing nanowires. The shape of nanowires was observed using scanning electron microscope (SEM) and the crystal structure was analyzed using transmission electron microscopy (TEM). Diameter and length of nanowires corresponded to those of nanopores and each nanowire was composed of a single crystal. Anodized aluminum oxide films were also fabricated as a novel nanoporous template. The pore length and diameter was controlled changing anodizing conditions. Ordering behavior of nanopores array in an anodized aluminum oxide film was also investigated to make a novel nanoporous template with a highly ordered honeycomb array of nanopores. 相似文献
33.
Organometallic Bonding in an Ullmann‐Type On‐Surface Chemical Reaction Studied by High‐Resolution Atomic Force Microscopy
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Shigeki Kawai Ali Sadeghi Toshihiro Okamoto Chikahiko Mitsui Rémy Pawlak Tobias Meier Jun Takeya Stefan Goedecker Ernst Meyer 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(38):5303-5311
The on‐surface Ullmann‐type chemical reaction synthesizes polymers by linking carbons of adjacent molecules on solid surfaces. Although an organometallic compound is recently identified as the reaction intermediate, little is known about the detailed structure of the bonded organometallic species and its influence on the molecule and the reaction. Herein atomic force microscopy at low temperature is used to study the reaction with 3,9‐diiododinaphtho[2,3‐b:2′,3′‐d]thiophene (I‐DNT‐VW), which is polymerized on Ag(111) in vacuum. Thermally sublimated I‐DNT‐VW picks up a Ag surface atom, forming a C? Ag bond at one end after removing an iodine. The C? Ag bond is usually short‐lived, and a C? Ag? C organometallic bond immediately forms with an adjacent molecule. The existence of the bonded Ag atoms strongly affects the bending angle and adsorption height of the molecular unit. Density functional theory calculations reveal the bending mechanism, which reveals that charge from the terminus of the molecule is transferred via the Ag atom into the organometallic bond and strengths the local adsorption to the substrate. Such deformations vanish when the Ag atoms are removed by annealing and C? C bonds are established. 相似文献
34.
Sylwia Nowakowska Aneliia Wäckerlin Ignacio Piquero‐Zulaica Jan Nowakowski Shigeki Kawai Christian Wäckerlin Manfred Matena Thomas Nijs Shadi Fatayer Olha Popova Aisha Ahsan S. Fatemeh Mousavi Toni Ivas Ernst Meyer Meike Stöhr J. Enrique Ortega Jonas Björk Lutz H. Gade Jorge Lobo‐Checa Thomas A. Jung 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(28):3757-3763
35.
Mitaku Shigeki; Hirokawa Takatsugu 《Protein engineering, design & selection : PEDS》1999,12(11):953-957
The average hydrophobicity of a polypeptide segment is consideredto be the most important factor in the formation of transmembranehelices, and the partitioning of the most hydrophobic (MH) segmentinto the alternative nonpolar environment, a membrane or hydrophobiccore of a globular protein may determine the type of proteinproduced. In order to elucidate the importance of the MH segmentin determining which of the two types of protein results froma given amino acid sequence, we statistically studied the characteristicsof MH helices, longer than 19 residues in length, in 97 membraneproteins whose three-dimensional structure or topology is known,as well as 397 soluble proteins selected from the Protein DataBank. The average hydrophobicity of MH helices in membrane proteinshad a characteristic relationship with the length of the protein.All MH helices in membrane proteins that were longer than 500residues had a hydrophobicity greater than 1.75 (Kyte and Doolittlescale), while the MH helices in membrane proteins smaller than100 residues could be as hydrophilic as 0.1. The possibilityof developing a method to discriminate membrane proteins fromsoluble ones, based on the effect of size on the type of proteinproduced, is discussed. 相似文献
36.
Takashi Tatsumi Shigeki Kunitomi Jun Yoshiwara Atsushi Muramatsu Hiro-o Tominaga 《Catalysis Letters》1989,3(3):223-226
In the reaction of CO-H2-NH3 on Mo/SiO2 catalysts, HCN is formed and is considered to be the principal intermediate for the formation of CH3CN. At low temperature methylamine is also formed. 相似文献
37.
38.
Shigeki Tasaka Yoshihiro Sato Nobuhito Tateyama Hisahiko Sugimoto Fumihito Fumuro Kaoru Hoshino 《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》1985,236(2):400-409
A new multiple scanning method is developed and applied to detect cosmic heavy nuclei. The plastic track detectors CR-39 exposed to cosmic heavy nuclei are over-etched in 8.0N NaOH for 94 h at 80°C. We found that the etched cones can easily be scanned on the plastic plates without using an optical microscope. The trajectories of heavy nuclei can be reconstructed with the naked eyes by superposing four or more over-etched plates. The charge detection threshold is obtained by this method, and appears to be 10. The charge resolution is estimated to be 1.0 charge units for iron nuclei. By adopting this method, the scanning time is much shortened and CR-39 plastic chamber size can easily be scaled up. The method is very useful for detecting particles with low flux intensity, like for searching magnetic monopoles or for measuring the high energy spectra of cosmic heavy nuclei. 相似文献
39.
40.
Cooking up an interactive olfactory game display. 总被引:2,自引:0,他引:2
Takamichi Nakamoto Shigeki Otaguro Masashi Kinoshita Masahiko Nagahama Keita Ohinishi Taro Ishida 《Computer Graphics and Applications, IEEE》2008,28(1):75-78
It's long been possible to give users outside an actual environment that environment's visual and auditory information and thus contribute to establishing presence. However, we've yet to establish much presence when users require olfactory information - such as in environments focused on foods, flowers, perfumes, or, in some cases, more offensive smells. Recently, several VR researchers have become interested in olfaction and olfactory displays that present smells in virtual environments (VEs). In this article, we describe our interactive olfactory display. One of our development goals is to confirm the assumption that users' interactions with the system increases presence. Thus, we used our interactive olfactory display to develop a cooking game in collaboration with electronic engineers and artists. 相似文献