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141.
An intense 14 MeV neutron source facility named OKTAVIAN was installed in the A15 building,Osaka University in 1981.Along the operation period,new radioisotopes with various half-life have been produced as neutron activation products in its concrete wall shield.In this work,we investigated the concrete wall in the heavy irradiation room of OKTAVIAN using gamma spectrometry method to discover the presence of radioisotope having large half-life value (long-lived radioisotope) as neutron activation products.Computational simulations were performed prior to measurement to predict the presence of long-lived radioisotopes by employing MCNP5 and FISPACT codes.A pre-calibrated Germanium detector with high energy resolution was employed to measure the concrete.Several long-lived activation products have been observed such as 152Eu,54Mn,65Zn,22Na and 60Co.The activity of each radioisotope was derived after estimating the detector efficiency using MCNP5.As a result of the measurement and analysis,the followings are concluded:(1) Though presence of activation products represents radiological risk to everyone who performs an experimental activity in the irradiation room of the OKTAVIAN facility,the present result shows that past experiments were carried out safely without any significant additional exposure dose coming from the wall for the last 38 years.(2) The approximated total fluence of D-T neutrons to the wall was successfully estimated from the produced radioisotope,152Eu,because it has the longest half-life of 13.5 years among the observed radioisotopes.(3) From the results of (1) and (2),it could be possible to estimate the total activity of the concrete wall in the OKTAVIAN facility,which is very essential and important information,because this would be very valuable for decommissioning or disposal of the facility in the future.  相似文献   
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143.
A novel fluorine‐containing telechelic polyimide end‐capped with acetylene group which derived from 4,4‐(hexafluoroisopropylidene) diphthalic anhydride (6FDA), 3,4‐diaminodiphenyl ether (DADE), and 4‐(2‐phenylethynyl) phthalic anhydride (PEPA) was synthesized using polycondensation. The physical and CO2 permeation properties of its crosslinked membranes prepared by the cyclotrimerization reaction of the acetylene groups at the polymer chain end using tantalum (V) chloride (TaCl5) as a catalyst under thermal treatment was investigated in terms of CO2‐induced membrane plasticization. The crosslinked membranes showed a gel content in organic solvent, which was good solvent of noncrosslinked membranes, and improved their thermal stability. Based on the measurement of the high‐pressure time dependence on CO2 permeation, the crosslinked 6FDA–DADE–PEPA membranes exhibited more resistance to CO2‐induced plasticization than noncrosslinked 6FDA–DADE and thermal treated 6FDA–DADE–PEPA. Furthermore, the increase in TaCl5 content resulted in more resistance to plasticization. The cyclotrimerization reaction of the acetylene groups at the polymer chain ends using a transition metal catalyst under thermal treatment was found to be more effective than conventional thermal treatments for suppressing membrane plasticization without the membrane densification. POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers  相似文献   
144.
Volatility of 137 Cs and 106Ru from borosilicate glass containing actual high-level waste was measured in an almost closed stainless-steel canister. The temperature dependence of the volatility of 137Cs was close to that obtained in our previous study using 134Cs. The volatility of 106Ru was about one-fifth that of 137Cs at 600° and 800°C. The air contamination by 137Cs and 106Ru in the canister at 400°C was estimated at 1.8 × 102 and 2 × 10 Bq/cm3, respectively, when it was assumed that the glass contained a realistic amount of 137Cs and 106Ru expected in commercial waste glass. These results are useful for predicting safety in a storage facility under operation.  相似文献   
145.
The viscosity and solubility of nitrogen in Y2O3–Al2O3–SiO2 melts have been systematically examined. The effects of nitrogen content on viscosity for Y-Al-Si-O-N melts and on Vickers hardness of oxynitride glasses also have been examined. Although the viscosity of Y2O3–Al2O3–SiO2 melts was decreased, the solubility of nitrogen into the melts was increased with increased Y2O3 content. These results indicated that the yttrium ion behaved as a network modifier. Therefore, the structural units for viscous flow became small, and the amount of nonbridging oxygen increased in the melts when the Y2O3 content increased. The viscosity of Y-Al-Si-O-N melts and Vickers hardness of oxynitride glasses remarkably increased with increased nitrogen content. These results suggested that the substitution of nitrogen for oxygen in the melts may have led to a high average coordination of nonmetal atoms and that the increased cross-linking produced a more rigid glass network.  相似文献   
146.
In situ measurements of the ionic conductivity were performed on polyethers, poly(ethylene oxide) (PEO) and poly(oligo oxyethylene methacrylate) (PMEO), with lithium triflate (LiCF3SO3) as crystalline and amorphous electrolytes, and at CO2 pressures up to 20 MPa. Both PEO and PMEO systems in subcritical and supercritical CO2 increased more than five fold in ionic conductivity at 40 °C composed to atmospheric pressure. The pressure dependence of the ionic conductivity for PEO electrolytes was positive under CO2, and increased by two orders of magnitude under pressurization from 0 to 20 MPa, whereas it decreases with increasing pressure of N2. The enhancement is caused by the plasticizing effect of CO2 molecules that penetrate into the electrolytes.  相似文献   
147.
This study aims to improve human jumping capabilities from an engineering perspective by proposing a supportive device, as in a robot suit. The robot expresses a time-oriented optimal torque pattern, which is the most efficient jumping motion and timing, of each joint that can jump the highest using a motor. Then humans learn the most efficient jumping motion. To actualize the most efficient jumping motion, we observe human jumping motions and analytically calculate the most efficient torque patterns based on them. This work was presented in part at the 13th International Symposium on Artificial Life and Robotics, Oita, Japan, January 31–February 2, 2008  相似文献   
148.
The composite films of methylsiloxane inorganic-organic hybrid and MoS2 particles have successfully been fabricated by electrophoretic deposition of MoS2 particles in a mixed solution of methyl ethyl ketone (MEK) and inorganic-organic hybrid sol. The addition of 20 vol% hybrid sol into a MEK suspension increased the amount of MoS2 deposition twice as much as that of MoS2 deposition in MEK alone. The fraction of particles deposited on a substrate in MEK-20 vol% sol was estimated to be much larger than that in MEK. The hydrolyzed methyltriethoxysilane in a hybrid sol modified MoS2 particles, resulting in lower negative zeta potential, which reduces the repulsion force among particles and makes the incorporation of particles into a deposition film easier. The surface modification also enables the incorporation of particles into a deposit by the interaction of surface modifiers. These factors enhance the incorporation of MoS2 particles in electrophoretic deposition in MEK-sol.  相似文献   
149.
In this paper, we proposed a novel single-sided magnet voice coil motor (VCM) design that can reduce out-of-plane force. Out-of-plane force of a VCM causes the actuator vibration, which results in settling vibration and acoustic noise. The proposed single-sided magnet VCM consists of a round coil and an axe-shaped magnet. We designed the optimized configuration by using numerical magnetic field simulation and compared its performance with those of a conventional VCM. Torsional moment was reduced by 90% at the worst position of the middle track, and bending moment was reduced by 50% at the worst position of the inner track compared with a conventional VCM. Rotational moment in our VCM was almost the same as that of the conventional one. We manufactured an actuator with the new design VCM and confirmed that the new single-sided magnet VCM shows a good performance as expected, although its magnet volume and coil resistance were almost the same as a conventional design. The measured frequency response of the actuators from the coil current to the head displacement showed that the coil torsional mode vibration of the proposed VCM is reduced remarkably.  相似文献   
150.
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