Crack-Healing Behavior of Si3N4/SiC Ceramics under Cyclic Stress and Resultant Fatigue Strength at the Healing Temperature

Si₃N₄/SiC composite ceramics were sintered and subjected to three-point bending. A semi-elliptical surface crack of 100 μm surface length was made on each specimen. The crack-healing behavior under cyclic stress of 5 Hz, and resultant cyclic fatigue strengths at healing temperatures of 1100° and 1200°C, were systematically investigated. The main conclusions are as follows: (1) Si₃N₄/SiC composite ceramics have an excellent ability to heal a crack at 1100° and 1200°C. (2) This sample could heal a crack even under cyclic stress at a frequency of 5 Hz. (3) The crack-healed sample exhibited quite high cyclic fatigue strength at each crack-healing temperature, 1100° and 1200°C.     

Solubility of NiO in Al2O3

Solubility of NiO in Al₂O₃ was determined by electron probe microanalysisy A diffusion couple method was used by coupling an NiO-doped Al₂O₃ polycrystal to a pure single crystal of Al₂O₃. The solubility of NiO in Al₂O₃ in air was 230 wt ppm (157 at. ppm of cations) and 170 wt ppm (116 at. ppm) at 2073 and 1973 K, respectively. The solubility of NiO in Al₂O₃ obtained in this work was compared with our previous work of the solubility of MgO in Al₂o₃.     

Diffusion process of amino acids in polymer supports for solid‐phase peptide synthesis as studied by pulsed‐field‐gradient spin‐echo proton nuclear magnetic resonance

The diffusion coefficient (D) values of tert‐butyloxycarbonyl‐glycine, tert‐butyloxycarbonyl‐L ‐tryptophan, tert‐butyloxycarbonyl‐L ‐phenylalanine (Boc‐Phe), and 9‐fluorenylmethoxycarbonyl‐L ‐phenylalanine in Merrifield polystyrene (MPS) gels, poly(ethylene glycol)‐grafted polystyrene (PEG–PS) gels, and crosslinked ethoxylate acrylate (CLEAR) gels, as used in solid‐phase peptide synthesis, were determined by the pulsed‐field‐gradient spin‐echo ¹H‐NMR method. From these experimental results, it was found that the amino acids in MPS gels, PEG–PS gels, and CLEAR gels with N,N‐dimethylformamide‐d₇ (DMF‐d₇) as a solvent had multidiffusion components within a measurement timescale of 10 ms. The D value of Boc‐Phe in polystyrene gels (1% divinylbenzene crosslinked) with tetrahydrofuran‐d₈ was much larger than that in the same gels with DMF‐d₇. Furthermore, the required time in which an amino acid transferred from a reactive site to a reactive site was estimated, within which the solvents and amino acids in the polymer supports diffused in the swollen beads.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 413–421, 2003     

Counter‐ion‐specific helix formation of poly(γ‐methyl L‐glutamate) derivatives containing sulfonate group in aqueous alcohols

Charged polypeptides containing sulfonate groups were prepared by transesterification of poly(γ‐methyl L ‐glutamate) with isethionic acid. The coil–helix transition of the sulfonated polypeptides was investigated in aqueous alcohols. Marked counter‐ion specificity was observed for helix formation: Li⁺ < Na⁺ < Cs⁺ ≦ Rb⁺ ≦ K⁺; this was different to that for poly(L ‐glutamate) (PLG): Cs⁺ ? K⁺ < Li⁺ < Na⁺. Specific helix stabilization by counter‐ion mixing, which has been found for the PLG system, was not observed for the sulfonated polypeptides. The counter‐ion‐ and solvent‐specific helix formation is discussed and compared with that in PLG. © 2001 Society of Chemical Industry     

A novel spherical carbon

We developed a novel spherical carbon material. The spherical carbon is composed of a high density of carbon nanotubes or nanofilaments, and includes an oxidized diamond particle as a core. Syntheses of this carbon in high volume with high selectivity may be possible. It is expected that this carbon will be useful as a catalyst material for fuel cells, electric double-layer capacitors, etc.     

Vector graphics depicting marbling flow

We present an efficient framework for generating marbled textures that can be exported into a vector graphics format based on an explicit surface tracking method. The proposed method enables artists to create complex and realistic marbling textures that can be used for design purposes. Our algorithm is unique in that the marbling paint on the surface of water is represented as an enclosed contour and is advected by fluid flow to deform the marbling silhouette. In contrast to previous methods, in which the shape is tracked with a concentration density field in Eulerian grids, our approach facilitates greater complexity that is free from grid resolution and per-pixel computation while retaining real-time performance. To forestall the propagation of large vertices, we adaptively resample the contours, exploiting the curvature and the turbulence of the fluid as criteria. At the convection phase, we parallelly advect contour particles on a Graphics Processing Unit (GPU) in addition to applying volume corrections. Finally, we quickly remove extremely thin lines in shapes to remove dozens of vertices. We performed our method with an interactive prototype to demonstrate the robustness of the proposed method in several scenarios.     

Preliminary investigation of a vapor-open envelope tailored for subtropical climate

Concerning global warming and resource depletion, the impact of buildings in subtropical regions is becoming even greater due to a high growth rate of urbanized areas. From the viewpoint of building physics, the main problem concerning subtropical climate is the high level of humidity in combination with high temperature. In this study, a flexible building envelope consisting of wood and clay components was developed so that the materials and the assemblies can be easily tailored to comply with local climatic conditions. The movement and accumulation of moisture in the wall was of prime concern. This has been investigated by means of testing full scale walls in a climate chamber and the corresponding one dimensional transient heat and transfer simulation. In order to achieve a consistency between calculation and measurement, the individual materials were tested for their hygric and thermal properties. Based on these findings attempts were made to calculate the behavior of an optimized wall assembly under real climatic conditions of central Japan. As a result, it was shown that the hygrothermal behavior of the envelope is predictable by means of the models and the simulation program used, and that no risk of interstitial condensation and mold growth was predicted under the real climatic conditions of Kyoto.     

Fundamental Behavior of Direct-Coupled Submicrosecond Pulse Energization in Electrostatic Precipitators

The fundamental characteristics of the direct-coupled pulse energization in electrostatic precipitators (EP's) are investigated in a test rig comprised of a coal pulverizing facility, a furnace, a gas cooling system, and an EP. The EP consisted of a corona electrode with barbed wires and a collection electrode with 300-mm duct spacing. This simulates the type of EP normally used in a coal-fired power station. The pulse-energized collection field shows a very high collection performance of more than 99 percent collection efficiency and the performance enhancement compared to the conventional dc energization, causing very severe back corona, becomes as large as H = 2.50.H is the enhancement factor in terms of the Deutsch migration velocity in the case of the very high resistivity dust of rd = 2 x 1013 ?cm at the gas temperature of Tg = 150°C. Even at the lower level of the dust resistivity at Tg = 110°C, where no back corona occurs in the dc-energized collection field, the performance enhancement is as large as H = 1.21. The mechanism of such great performance enhancement is likely to be the result of the very uniform and very intense formation of corona plasmas on the wires as a result of the very fast rise in the pulse voltage applied and a special sawtooth waveform of the operating voltage between the corona and collection electrodes.