Tailoring the Performances of Lead Halide Perovskite Devices with Electron‐Beam Irradiation

Lead halide perovskites are intensively studied in past few years due to their potential applications in optoelectronic devices such as solar cells, photodetectors, light‐emitting diodes (LED), and lasers. In addition to the rapid developments in material synthesis and device fabrication, it is also very interesting to postsynthetically control the optical properties with external irradiations. Here, the influences of very low energy (10–20 keV) electron beam of standard electron beam lithography are experimentally explored on the properties of lead halide perovskites. It is confirmed that the radiolysis process also happens and it can selectively change the photoluminescence, enabling the direct formation of nanolaser array, microsized light emitter array, and micropictures with an electron beam writer. Interestingly, it is found that discontinuous metallic lead layers are formed on the top and bottom surfaces of perovskite microplate during the radiolysis process, which can act as carrier conducting layers and significantly increase the photocurrent of perovskite photodetector by a factor of 217%. By using the electron beam with low energy to modify the perovskite, this method promises to shape the emission patterns for micro‐LED with well‐preserved optical properties and improves the photocurrent of photodetector.     

晶圆FAB厂罗茨真空泵用永磁电机研发设计与实验

为满足在晶圆FAB厂内使用罗茨真空泵的工程需求及性能要求, 本文设计了一台1.5 kW小体积高速永磁同步电机并将其作为罗茨真空泵用驱动电机。采用多极少槽的极槽配合方案, 减少变频器及供电装置中高次谐波对电机运行性能和损耗温升的影响。基于场路耦合思想及商业有限元软件, 完成了电机拓扑结构及电磁设计, 仿真结果验证了电磁设计及结构的合理性;通过三维温度场研究, 表明该设计可应用于真空泵类工程之中。最后对样机进行了电机性能实验, 实验数据与设计指标比较吻合, 对罗茨真空泵进行性能测试实验, 进一步验证了罗茨真空泵驱动用高速永磁电机设计的合理性, 新研发电机满足泵的各项性能指标要求, 研究工作具有工程实用价值。     

浅析机械电气设备中TN系统中间接接触的防护问题

本文对GB5226.1-2008《机械电气安全机械电气设备第1部分:通用技术条件》(简称"标准")中关于机械电气设备中TN系统的间接接触防护的条件要求及检测方法进行了详细的论述。介绍了接地故障回路阻抗的测量方法,分析了减小触摸电压作保护的条件。举例分析了机械电气装备的接地故障阻抗安全测量和判定。     

结合基元对比度与边界先验的显著性区域检测

研究了对完成计算机视觉任务有重要作用的视觉显著性检测,考虑到单纯依靠对比度计算进行显著性检测具有一定的局限性,提出了一种结合基元对比度与边界先验信息的显著性区域检测算法。该算法通过Mean-Shift分割构造图像基元结构,以图像基元为基础,利用图像颜色和亮度两种特征获得基元对比度显著图,再利用图像边界先验条件得到边界显著图;为了突出显著性目标,采用一种新的融合方式将以上检测结果进行融合,最后对显著图像进行多尺度增强操作,以获得更加高质量的显著性图。在国际公开数据集上的实验表明,该算法与现有的较成熟的方法相比,基本符合人眼的主观判断,具有较高的精度召回率。     

Polymeric Micelle‐Mediated Delivery of DNA‐Targeting Organometallic Complexes for Resistant Ovarian Cancer Treatment

Three half‐sandwich iridium and ruthenium organometallic complexes with high cytotoxicity are synthesized, and their anticancer mechanisms are elucidated. The organometallic complexes can interact with DNA through coordination or intercalation, thereby inducing apoptosis and inhibiting proliferation of resistant cancer cells. The organometallic complexes are then incorporated into polymeric micelles through the polymer‐metal coordination between poly(ethylene glycol)‐b‐poly(glutamic acid) [PEG‐b‐P(Glu)] and organometallic complexes to further enhance their anticancer effects as a result of the enhanced permeability and retention effect. The micelles with particle sizes of ≈60 nm are more efficiently internalized by cancer cells than the corresponding complexes, and selectively dissociate and release organometallic anticancer agents within late endosomes and lysosomes, thereby enhancing drug delivery to the nuclei of cancer cells and facilitating their interactions with DNA. Thus, the micelles display higher antitumor activity than the organometallic complexes alone with a lack of the systemic toxicity in a mouse xenograft model of cisplatin‐resistant human ovarian cancer. These results suggest that the polymeric micelles carrying anticancer organometallic complexes provide a promising platform for the treatment of resistant ovarian cancer and other hard‐to‐treat solid tumors.     

A Numerical Gas Fracturing Model of Coupled Thermal,Flowing and Mechanical Effects

Gas fracturing, which overcomes the limitation of hydraulic fracturing, is a potential alternative technology for the development of unconventional gas and oil resources. However, the mechanical principle of gas fracturing has not been learned comprehensively when the fluid is injected into the borehole. In this paper, a damagebased model of coupled thermal-flowing-mechanical effects was adopted to illustrate the mechanical principle of gas fracturing. Numerical simulation tools Comsol Multiphysics and Matlab were integrated to simulate the coupled process during the gas fracturing. Besides, the damage evolution of drilling areas under several conditions was fully analyzed. Simulation results indicate that the maximum tensile stress, which occurs in the upper and lower of the injection hole, decreases with the increase of the tectonic stress coefficient (TSC). As the TSC increases, shear fractures increase, a crushed area is gradually formed and the seepage area increases rapidly. The influence of TSC on fracture expansion is concluded as follows: with the decrease of TSC, the relative width of fractures decreases whilst the depth increases. It indicates that thermal stress and pore pressure promote the expansion of tensile fractures but restrain the expansion of shear fractures. Therefore, a relatively lower injection gas pressure is required to obtain the same degree of fracturing with a coupled thermal gradient.     

Highly Efficient and Color-Stable Thermally Activated Delayed Fluorescence White Light-Emitting Diodes Featured with Single-Doped Single Emissive Layers

Despite their merits of environmental friendliness, low cost, and large-scale production, thermally activated delayed fluorescence (TADF) based white organic light-emitting diodes (WOLEDs) for daily lighting applications still face the formidable challenges of structural simplification and controllable exciton allocation. Here, the state-of-the-art full-TADF WOLEDs with features of the single-doped single emissive layers (EMLs) and ultrasimple trilayer structure are demonstrated. The EMLs are binary systems as yellow TADF emitter (4CzTPNBu) doped blue TADF matrix (ptBCzPO₂TPTZ) with the large steric hindrance and mismatched frontier molecular orbital energy levels to effectively restrain excessive blue-to-yellow triplet exciton transfer and host-dopant interaction induced triplet quenching. Simultaneously, Förster resonance energy transfer is utilized to optimize exciton allocation for the balance of blue and yellow emissions, giving rise to the photoluminescence quantum yield beyond 90%. Consequently, these single-doped EMLs endow their cool white, pure white, and warm white diodes with the high-quality and ultrastable white light and the 100% exciton utilization efficiencies through the extremely simple structures, making them competent for the diverse daily lighting applications.