Chemical reaction kinetics dataset of Cs-I-B-Mo-O-H system for evaluation of fission product chemistry under LWR severe accident conditions

In order to improve LWR source term under severe accident conditions, the first version of a fission product chemistry database named ‘ECUME’ was developed. The ECUME is intended to include several datasets of major chemical reactions and their effective kinetic constants for representative severe accident sequences. It is expected that the ECUME can serve as a fundamental basis from which fission product chemical models can be elaborated for use in the severe accident analysis codes. The implemented chemical reactions in the first version were those for representative gas species in Cs-I-B-Mo-O-H system from 300 to 3000 K. The chemical reaction kinetic constants were evaluated from either literature data or calculated values using ab-initio calculations. The sample chemical reaction calculation using the presently constructed dataset showed meaningful kinetics effects at 1000 K. Comparison of the chemical equilibrium compositions by using the dataset with those by chemical equilibrium calculations has shown rather good consistency for the representative Cs-I-B-Mo-O-H species. From these results, it was concluded that the present dataset should be useful to evaluate fission product chemistry in Cs-I-B-Mo-O-H system under LWR severe accident conditions, where kinetics effects should be considered.     

Insulation characteristics and its evaluation method of N2 gas for nonstandard lightning impulse waveforms

Until recently, SF₆ gas has widely been used as the best insulating medium in substation equipment. However, SF₆ gas was specified to be a greenhouse gas at COP3 in 1997 because of its high global warming potential (GWP), and alternative insulation gases to SF₆ have been sought for a long time. Alternatives using the natural gases are considered to be suitable, but none of them show better properties for insulation as well as good environmental compatibility. Therefore, it is necessary to rationalize the equipment insulation level and reduce the test voltage of electric power apparatus to as low a level as possible. The actual lightning surge waveform (so‐called nonstandard lightning impulse waveform) occurring in the actual field is different from the standard lightning impulse waveform (1.2/50 μs). There are many cases in which the actual lightning surge waveform has a steep rise and large decay of overvoltage, and the insulation requirements are not as severe as those for the standard lightning impulse waveform. In this paper, we focused our research on N₂ gas as an SF₆ substitute and investigated the insulation characteristics of N₂ gas for a single‐frequency oscillatory waveform with various frequencies from 2.7 to 20.0 MHz and damping ratios. Based on the experimental results, it might be possible to reduce the test voltage of N₂ gas insulation by evaluating the crest value of the actual lightning surge waveform that has been converted into an equivalent standard lightning impulse waveform. © 2009 Wiley Periodicals, Inc. Electr Eng Jpn, 167(2): 10–20, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20754     

Measurement of the internal space charge distribution of ananti-electrostatic discharge polymer

Charged dielectrics can cause an electrostatic discharge (ESD) that damages electronic circuits because of the electromagnetic noise associated with the discharge. Newly developed anti-ESD polymers are expected to be `anti-ESD polymer insulating materials', but the mechanism of their action against ESD has not been explained. Since the anti-ESD polymers contain some kind of polymer solid electrolyte, they should be able to be characterized by the behavior of their internal space charge. By measuring the space charge distribution of an anti-ESD polymer using the pulsed electroacoustic method under DC electric field, we found that the polymer was effective in preventing ESD because the internal space charge near the surface partially compensates the electric field of the external charge on the surface. We also found indications that the internal space charge behavior is related to the dispersion of the polymer solid electrolyte     

Space charge behavior in low density polyethylene at pre-breakdown

It has been known that the electrical breakdown of insulating materials is strongly affected by the formation of space charge in the bulk of the materials. Many researchers have attempted to study the relationship between the space charge and the breakdown; however, it has not been clarified yet. Although the pulsed electroacoustic (PEA) method has been widely used to observe space charge profiles, previous works have not shown clear evidence of the influence of the space charge on the breakdown. Therefore, we have developed a new PEA system with an interval of 0.5 ms to observe the space charge distribution continuously under the ultra-high electric field. Using this system, we observed the space charge dynamics in the low-density polyethylene (LDPE) at and around the breakdown. We also investigated the dependence of the applied electric field on space charge behavior. From the results, it is found that the injected charge packet moved faster and deeper under a relatively lower electric field rather than that under a higher electric field. Furthermore, we found that the maximum electric field in each specimen was almost the same when the breakdown happened in a specimen.     

Measurement of specific movement power application: evaluation of weight lifters

A new dynamometer was developed for the measurement of specific movement power (SMP) exerted by mono- or multi-articular movements. To determine the reproducibility of SMP, two identical test protocols were carried out on separate days for six movement types on seven adult males. The movement types were arm pull (AP), leg rise (LR), knee extension (KE), elbow flexion (EF), hip extension (HE) and squat movement (SQ). Variations in peak power obtained in two tests ranged from 0.7% (AP) to 9.6% (SQ). Coefficients of the test-re-test correlation in peak power ranged from 0.805 (SQ) to 0.961 (AP) and standard errors ranged from 4 W (EF) to 14 W (SQ). SMP in upper extremities increased from 166 W (EF) to 307 W (AP) resulting from the increase in velocity. However, in the movements of lower extremities, SMP increased from 506 W (KE) to 1351 W (SQ) as a result of the increase in force. To evaluate the validity of the SMP, a pull movement in weightlifting was tested and related to the athletic performance on weightlifters. Positive linear correlation (r = 0.862, p<0.001) was observed between SMP and the total weight best records. It is concluded that this newly developed dynamometer has enough reproducibility and validity for evaluating the SMP, which is developed by various joint movement patterns related to the sport. The feasibility of applying this measuring protocol to the testing and training programmes for improving the daily living activities and athletic performances should now be assessed.     

Preparation of detergent-lipase complexes utilizing water-soluble amphiphiles in single aqueous phase and catalysis of transesterifications in homogeneous organic solvents

A novel method of preparing detergent-enzyme complexes that can be employed in organic media was developed utilizing newly synthesized water-soluble nonionic gemini-type detergents, N,N-bis(3-D-gluconamidopropyl)-3-(dialkyl-L-glutamatecarbonyl)propanamides (BIG2CnCA: n = 10,12,14,16,18) and N,N-bis(3-D-lactonamidopropyl)-3-(dialkyl-L-glutamatecarbonyl)propanamides (BIL2CnCA: n = 16,18), and nonionic twin-headed detergents, N,N-bis(3-D-gluconamidopropyl)alkanamides (BIG1Cn: n = 12,14,16,18,delta9). This method simply entails mixing a selected enzyme with an appropriate detergent in an aqueous solution followed by lyophilization, and it offers the advantages of enhanced enzymatic activity in organic solvents and eliminates both enzyme loss and the necessity for an organic solvent in the preparation stage. Using various modified lipases originating from Aspergillus niger (Lipase A), Candida rugosa (Lipase C), Pseudomonas cepacia (Lipase P), and porcine pancreas (PPL), prepared using the novel method and detergents, including conventional synthesized nonionic detergents such as dialkyl N-D-glucona-L-glutamates (2CnGE: n = 12,18delta9) and octanoyl-N-methylglucamide (MEGA-8), enantioselective transesterifications of 6-methyl-5-hepten-2-ol (sulcatol) and 2,2-dimethyl-1,3-dioxolane-4-methanol (solketal) with a vinyl or isopropenyl carboxylate were carried out in an organic solvent. The modified lipase activity was influenced by both the lipases and the structure of the detergents. The value for the hydrophile-lipophile balance (HLB) of the detergent provided a means of correlating the structure and the obtained modified lipase activity. For detergents of the same class with a HLB value of approximately 9 and 12, the highest activity was obtained for Lipase A and Lipase P, and Lipase C and PPL, respectively. Among detergents of the same HLB value tested, the gemini-type detergents possessing the most bulky head and tail were most effective as a modifier for lipases of all types. The preparation and reaction conditions for these novel gemini-type detergent-modified lipases were optimized using BIG2C12CA (HLB = 9.4) by studying the effect of the detergent/lipase ratio and the nature of organic solvents on the complex formation. The high enzymatic activities of the BIG2C12CA-modified lipases were independent of the solubility of the lipases in organic solvents, unlike in the case of 2CnGE-modified lipases prepared using the conventional suspension system.     

Separation of lactoferrin-a and -b from bovine colostrum

Bovine lactoferrin was separated into lactoferrin-a and lactoferrin-b from bovine colostrum. Lactoferrin-a was eluted at 0.38 M NaCl and lactoferrin-b was eluted at 0.43 M NaCl by carboxymethyl cation-exchange chromatography at pH 7.7, 0.05 M phosphate buffer. The molecular weights were estimated at 84,000 for lactoferrin-a and 80,000 for lactoferrin-b. Lactoferrin-a contents were 258.0 mg/L and lactoferrin-b contents were 524.3 mg/L of colostrum for cow 19. From colostrum to normal milk, total lactoferrin was from 17.1 to 129.4 mg/L during the normal lactational period; however, lactoferrin did not separate clearly into lactoferrin-a and lactoferrin-b. The lactoferrin-a measured from six cows was 258.0, 114.0, 112.8, 64.0, 59.7, and 22.4 mg/ L and the lactoferrin-b 524.3, 331.8, 184.7, 170.7, 129.3, and 44.0 mg/L, respectively. The average was 105.2 mg (31.3%) for lactoferrin-a and 230.8 mg (68.7%) for lactoferrin-b.     

High-resolution PEA charge distribution measurement system

The pulsed electroacoustic (PEA) method is widely known to be an excellent method for measuring the space charge distribution that accumulates in thick dielectric materials (1 to 5 mm). We have refined the PEA measurement system for use on thin dielectric materials. With FFT deconvolution to compensate for the frequency characteristics of the piezoelectric sensor, the resolution in the depth direction is improved to ~3 μm. This improved system is thus expected to be useful for the quantitative and nondestructive measurement of the space charge distribution in dielectric films     

Mechanical and AC loss properties in mono-and multi-filamentary Bi-223 Ag-sheathed tapes

The evaluation of the bending strain tolerance and AC loss properties for monoand multi-filamentary Bi-2223 Ag-sheathed tape were carried out at liquid nitrogen temperature. For tapes with a filament number of over 19, the critical current (I_c) was maintained at the same values up to the bending strain of 0.3%, although the I_c of the mono-filamentary tape at the condition of 0.2% strain degraded to 90% of the value for the no-strain condition. The AC loss of the monofilamentary tape was the hysteresis type. On the contrary, the AC loss of the multi-filamentary tape was substantially dominated by the eddy current loss in the Ag matrix.