Geometrical Characteristics and Surface Polarity of Inclined Crystallographic Planes of the Wurtzite and Zincblende Structures

Inclined crystallographic planes of the wurtzite structure were investigated in comparison with the zincblende structure in terms of surface geometry characteristics. The ball–stick model indicates that the semipolar surface possesses a surface polarity resembling the anion polarity, which agrees with the common experimental observations of epitaxial growth preference for the cation-polarity surface over the surface. The wurtzite surface was found to share geometrical similarities with the zincblende {100} surface uniquely among the possible semipolar planes. This finding encourages epitaxial growth on the plane of wurtzite semiconductors, e.g., GaN, with the potential of avoiding atomic step formations typically associated with off-axis crystallographic planes.     

First plasma experiment on spherical tokamak device UTST

The UTST (University of Tokyo Spherical Tokamak) device was constructed for the purpose of exploring the formation of ultrahigh‐beta ST (spherical tokamak) plasma using the double null plasma merging method. When two plasmas merge together to form a single plasma, magnetic field lines reconnect, and magnetic field energy is converted to plasma kinetic energy, increasing the plasma beta. Merging start‐up has been demonstrated in the TS‐3/4, START, and MAST devices using coils inside the vacuum vessel, and the TS‐3 plasma obtained a 50% beta. In order to demonstrate start‐up in a more reactor‐relevant situation, UTST has all poloidal field (PF) coils outside the vacuum vessel. The first plasma experiment on the UTST was begun in December 2007. In the results, the plasma obtained 10 kA by using only the outer PF coils and a single ST was generated in the lower area (z = –0.3 to –1.0 m) close to a washer gun. This result suggests that another washer gun on the top of the UTST can allow the generation of ST in the upper area and merging start‐up by using outer PF coils. © 2012 Wiley Periodicals, Inc. Electr Eng Jpn, 179(2): 20–26, 2012; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21216     

Redox‐Active Polymers Connecting Living Microbial Cells to an Extracellular Electrical Circuit

Microbial electrochemical systems in which metabolic electrons in living microbes have been extracted to or injected from an extracellular electrical circuit have attracted considerable attention as environmentally‐friendly energy conversion systems. Since general microbes cannot exchange electrons with extracellular solids, electron mediators are needed to connect living cells to an extracellular electrode. Although hydrophobic small molecules that can penetrate cell membranes are commonly used as electron mediators, they cannot be dissolved at high concentrations in aqueous media. The use of hydrophobic mediators in combination with small hydrophilic redox molecules can substantially increase the efficiency of the extracellular electron transfer process, but this method has side effects, in some cases, such as cytotoxicity and environmental pollution. In this Review, recently‐developed redox‐active polymers are highlighted as a new type of electron mediator that has less cytotoxicity than many conventional electron mediators. Owing to the design flexibility of polymer structures, important parameters that affect electron transport properties, such as redox potential, the balance of hydrophobicity and hydrophilicity, and electron conductivity, can be systematically regulated.     

圆弧“U”形结构安装座铸造工艺改进

安装座为精铸件,其结构总体呈半圆弧形,一端为“U”形结构,该产品主要工艺难点为圆弧径向及“U”形结构开口端易变形,圆弧径向两端加工后易出现“黑皮”。通过工艺改进运用反变形工艺、工艺拉筋等工艺措施有效解决铸件变形问题,提高产品铸造工艺出品率。     

Resolution enhancement printing with a variable spot-size laser diode

We demonstrate enhanced resolution printing using a variable spot-size laser diode. The near-field spot size of the laser diode can be changed by controlling the refractive-index distribution in the laser stripe through the injected current. The ratio of the minimum-to-maximum spot size is 2.1:1. This technology provides high-resolution printing without increasing the scanning frequency. Smoother character outlines that consist of finer steps are produced with this laser diode. An effective resolution of 1200 dots /in. (dpi) can be obtained by a printer system with 600-dpi resolution.     

Laterally vibrating MEMS resonant vacuum sensor based on cavity-SOI process for evaluation of wide range of sealed cavity pressure

Microsystem Technologies - This paper reports a laterally vibrating MEMS resonant vacuum sensor which senses ambient pressure based on the squeeze-film damping effect. The single-anchored...     

Analysis of constant-volume shear tests based on precise measurement of stresses in powder beds

This study demonstrates a new constant-volume shear test configuration to analyze the stresses in powder beds and evaluate powder flowability. A novel cylindrical shear cell geometry and load cell arrangement allowed precise measurement of the normal stress acting on the shear planes of the powder beds. The stress transmission ratio between the top and shear planes decreased with increasing ratio of the powder bed height in the upper section of the shear cell to the shear cell diameter. This was due to friction between the powder bed and the side wall of the upper section of the shear cell. Using the measured values of the normal stress on the shear planes, the effects of the powder bed height and shear cell diameter were eliminated from the data. In addition, to evaluate the shear properties of the powder beds, the powder yield locus, consolidation yield locus, critical state line, shear cohesion, and void fraction were obtained from a single shear test. The powder yield locus data were used to obtain flow functions.     

Characterization of mixing performance in a microreactor and its application to the synthesis of porous coordination polymer particles

Here we quantitatively evaluated the mixing performance of a tailor-made microreactor with central-collision type through the iodide/iodate chemical test reaction, and applied the microreactor to the synthesis of zeolitic imidazolate framework-8 (ZIF-8), which is a subclass of porous coordination polymers (PCPs) or metal organic frameworks (MOFs). The chemical test reaction demonstrated excellent mixing performance of the microreactor with a characteristic mixing time shorter than 1 ms, which is approximately 100 times faster than those of a batch reactor and a millimeter-sized Y-shaped mixer. Taking advantage of the rapid and uniform mixing, the microreactor successfully produced ZIF-8 particles with high reproducibility by simply mixing aqueous solutions of zinc nitrate and 2-methylimidazole. The synthesis at room temperature resulted in ZIF-8 particles with chamfered cube shape, while a lower temperature of 5 °C produced raspberry-type spherical particles. We confirmed that prepared ZIF-8 particles have BET surface area of ～1500 m²/g and exhibit the gate adsorption behavior caused by the structural transition of the ZIF-8 framework.     

Quantitative analysis of agglomerates levitated from particle layers in a strong electric field

The electrification, agglomeration, and levitation of particles in a strong electric field were analyzed experimentally and theoretically. Particle layers of glass, alumina, and ferrite were formed on a plate electrode and an external voltage was applied. Microscopic observations of the agglomerates levitated from the particle layers revealed that the number of primary particles constituting an agglomerate is affected by particle diameter and electrical resistance, but not by the applied electric field. The electric field distributions in the system were calculated by considering the charges and geometries of the agglomerates formed on the particle layers. The charges of the agglomerates were obtained experimentally. All forces acting on the agglomerates (i.e., gravitational forces, Coulomb forces, interaction forces between polarized particles, image forces, and gradient forces) were analyzed under different conditions, including various electric field distributions and charges of agglomerates. Furthermore, the critical conditions for the levitation of the agglomerates were evaluated using a force balance.