用两亲聚合物制备大颗粒苯丙乳液

分别以两亲聚合物P(C9-AA)和P(DCPD-St-α-St-AA)作乳化荆，研究了制备大颗粒(约1μm)及具有一定稳定性的苯丙乳液的方法，讨论了乳化剂，温度及引发剂用量对乳液性能的影响。结果表明，以P(C9-AA)作乳化剂时，引发剂用量为单体质量的1．2％，90℃时可以合成性能良好的苯丙乳液；以P(DCPD-St-α-St-AA)作乳化荆时，引发剂用量为单体质量的1．2％，80℃时可以合成性能良好的苯丙乳液。     

浅论太阳电池在通信工程中的应用

介绍了太阳电池应用的一般要求和太阳能供电系统的组成及运行，给出了工程设计个常用的太阳电池容量计算方法，并提出太阳能供电系统运行维护注意事项。     

数字振荡器的实现原理与仿真编程

鉴于数字信号处理中的实时应用问题，探讨了数字滤波器的实时实现原理，包括离散时间网络结构的作用和离散时间信号处理的特点，重点介绍了实时应用中实现数字滤波器的基本思想，运用MATLAB和所导出的通用数字振荡器的系统函数对一个非正弦数字振荡器进行了仿真编程，还讨论了有关实时处理的几个重要的系统性质，表达了作者对于当前学习和应用数字信号处理方法的观点。     

Preparation of trichlorosilane by plasma hydrogenation of silicon tetrachloride

We have studied silicon tetrachloride hydrogenation in an rf (40.68 MHz) plasma and have determined the trichlorosilane yield as a function of the molar energy input, H₂: SiCl₄ molar ratio, and pressure. The highest trichlorosilane yield achieved is 60%, and the minimum energy input is 0.3 kW h per mole of SiHCl₃.     

Soft X-ray emission from the plasma of a conductor exploding in a strong longitudinal magnetic field

Previous experiments with the electric explosion of conductors in a strong (50 T) longitudinal magnetic field showed the formation of a relatively low-density plasma around the central part of the explosion channel, which exhibited expansion at a velocity on the order of 10–20 km/s [1, 2]. Expansion of the plasma was accompanied by displacement of the magnetic field from the explosion channel, which was manifested by a diamagnetic signal. An analysis of the plasma energy balance is hindered by the lack of reliable data about radiative energy losses. Here, we report the first experimental results on the radiation pulse kinetics and the first estimates of the radiation energy.     

An NMR magnetometer with frequency modulation

An NMR tracking magnetometer, in which the frequency modulation is used instead of the traditional magnetic modulation, is described. Owing to the proposed digital compensation of modulation shifts, the tracking error is negligibly small and does not exceed the corresponding error for NMR magnetometers with magnetic modulation. The absence of the modulation rings decreases the sizes of the sensors to the utmost and excludes their effect on the surrounding systems. 50%-deuteron saturated solution of lithium chloride in water of 50% deuterons, which is used as a sensor substance, allows one to measure magnetic fields of 0.0625 to 15.3 T with a 10^?7 relative error at the most.     

Effect of the absence of lipoxygenase isoenzymes on the storage characteristics of rice grains

Three varieties of paddy rice with and three varieties without lipoxygenase (LOX) isoenzymes were stored at room temperature, in dark conditions for 42 months. Insect damage and viability were investigated during that time. Varieties without LOX-1,2 and their offspring were screened with a rapid method of estimating LOX isoenzymes, and subjected to an accelerated-ageing experiment. The results indicated that in varieties without LOX-1,2, after long storage, rice quality was normal, but for varieties with LOX-1,2, rice quality deteriorated. With increase of storage time, the germination rate of the seed of most varieties decreased greatly except for varieties without LOX-1,2 where there was almost no change in the germination rate. In varieties without LOX-1,2 and their offspring, after an accelerated ageing experiment the germination rate of some varieties changed slowly, but with others, the germination rate changed quickly. This indicated that a definitive factor, which influenced the life of seeds, may be the loss of LOX-1,2. During storage, there was also a significant difference in the degree of insect damage. In varieties without LOX-3 insect damage was lower, but in varieties with LOX-3 insect damage was higher. Therefore, the absence of LOX-3 may be very important in insect resistance in rice grain.     

三元催化转化器中的现象分析与研究

在介绍和分析国内外研究现状的基础上，论述了三元催化转化器中的传递现象及化学反应动力学．探讨了三元催化转化器在暖机过程中有害物质的催化转化模型，并建议采用数学模型的方法对催化器在发动机所有工况下的工作过程进行模拟。     

Photocatalytic degradation of 2,2‐bis(4‐hydroxy‐3‐methylphenyl) propane (BPP) based on molecular recognition interaction

BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO₂/UV–visible (λ_max = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 10³ L mol^?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO₂/UV–visible (λ_max = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO₂/UV‐visible (λ_max = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry