Evaluation of various carbon materials supported Pt catalyts for aqueous-phase reforming of lignocellulosic biomass hydrolysate

Currently, under huge pressure from energy demands and environmental problems, much attention is being paid to produce fuel and chemicals from lignocellulosic biomass. In this matter, development of active and also recyclable catalysts are essential. In the present study, various types of carbon supported Pt reforming catalysts were prepared for use in gasification of wheat straw biomass hydrolysate by aqueous-phase reforming. The supports tested were various carbon materials having different surface and structures that were activated carbon (AC), single- and multi-walled carbon nanotubes (SWCNT and MWCNT), superdarco carbon (SDC) and graphene oxide (GO). The catalysts prepared using these supports were evaluated based on gasification yield, carbon amount consumed in the process, sugar alcohols formation and breaking down of organic compounds in the hydrolysate.     

Application of failure mode and effect analysis model to foodservice systems operated by chefs in practice and by chefs from a culinary school in Turkey

Failure mode and effect analysis (FMEA) methodology has been applied for the risk assessment of basic foodservice systems operated by the “chefs in practice” and by the “chefs from a culinary school” in Turkey. Firstly, the preliminary hazard analysis was done to predict the potential failure modes in the food flow of basic foodservice systems. Each step in the process, from receiving of raw ingredient to table, was analyzed. The risk priority numbers (RPN) were calculated for each failure mode. The corrective actions were suggested to lower the RPN values below the acceptable limit of 120. The data collected in this study compared to the data from a study carried out with “chefs in practice” about basic food safety issues. The significant difference was observed between “the chefs in practice” and “the chefs with formal culinary education”. Majority of chefs from a culinary school have scored better in many food safety issues, so thus the corrective actions in the FMEA table. The results clearly point out the urgent need for FMEA integration and for food handler education in current foodservice establishments in Turkey.     

Formulation and in vitro evaluation of bisphosphonate loaded microspheres for implantation in osteolysis

Chitosan and poly(lactide-co-glycolide) acid (PLGA) microspheres loaded with alendronate sodium (AS) were prepared for orthopedic as well as dental applications. In orthopedics the aim was to make the total joint prostheses stay in the body for a long time without causing bone tissue loss, while in dentistry it was aimed to treat the alveolar bone resorption caused by periodontitis and also to make the dental treatment using implants easier by reducing the bone loss in patients with osteoporosis. Solvent evaporation method was used to prepare AS loaded PLGA microspheres and emulsion polimerization method was used to prepare AS loaded chitosan microspheres. Particle size, loading efficacy, surface characteristics, and in vitro release characteristics were examined on prepared formulations. After the examination of the scanning electron microscopy photographs of microspheres, chitosan microspheres were observed to have spherical structure and smooth surface characteristics while PLGA microspheres were observed to have spherical porous surface structure. Loading efficacy was found to be 3.30% for chitosan microspheres and 7.70% for PLGA microspheres. It was observed that 85% of AS had been released at the end of the third day from chitosan microspheres whereas 58% was released at the end of the fifth day from PLGA microspheres. It was found that chitosan microspheres gave first order release while PLGA microspheres gave zero order release.     

Sub-nanomolar sensing of ionic mercury with polymeric electrospun nanofibers

Ethyl cellulose (EC) based electrospun nanofibers were exploited for sub-nanomolar level optical chemical sensing of ionic mercury. An azomethine ionophore was used as Hg (I) and Hg (II) sensing material. Ethyl cellulose nanofibers with varying amounts of the ionic liquid; 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF₄) were prepared and characterized. The nanofibers were fabricated by electrospinning technique. The offered chemosensor allow determination of mercury ions in a large linear working range between 1.0 × 10⁻¹⁰ and 1.0 × 10⁻⁴ mol L⁻¹. Limit of detection was found to be 0.07 nM which makes this technique alternative to cold-vapor atomic absorption spectrometry (CV-AAS), flame emission methods and to inductively coupled plasma-mass spectrometry (ICP-MS).     

Hydrolysis of kenaf (Hibiscus cannabinus L.) stems by catalytical thermal treatment in subcritical water

The present study was designed to solubilize/hydrolyze lignocellulosic biomass of kenaf stems in subcritical water, in an environmentally friendly manner. The hydrolysis efficiency was examined with respect to several parameters such as sonication of biomass-water mixture before thermal treatment, changing temperature and pressure of the hydrolysis process, adding carbon dioxide or nitrogen as pressurizing gas.The molar mass of polysaccharide fractions in the sonication pretreated solutions notably decreased because of effective degradation. The extent of hydrolysis was more effective at higher temperatures and under carbon dioxide atmosphere rather than nitrogen as the pressurizing gas. In comparison to untreated sample, 200 °C-subcritical water-treated kenaf stems had significant morphological and structural changes on plant cell wall surface that was further distorted at 250 °C.     

Characterization and thermoluminescence behavior of beta irradiated NaBaBO3 phosphor synthesized by combustion method

NaBaBO₃ host material was synthesized using the combustion method. In order to optimize the performance of the material, effects of sintering temperatures varying from 600° to 1000?°C were investigated. The sintering temperature and dwell time were found to have pronounced effects on the pure NaBaBO₃ material. X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) techniques were used to confirm the phase formation and examine the surface morphology of the prepared powder material, respectively. TL behavior of NaBaBO₃ was studied at various beta doses. It is seen that the sample exhibits well resolved TL glow peak at a peak temperature about 175?°C and corresponding TL intensity increases with the increasing beta dose. However, TL glow peak slightly shifts to lower temperature with the increasing beta dose level. This is the first TL report of a phosphor with a NaBaBO₃ host. The TL kinetic parameters were estimated by the peak shape (PS) method and CGCD software. TL glow curves of NaBaBO₃ consist of several traps and exhibited second order kinetics. A possible TL mechanism was also discussed using the energy level model. The obtained results can provide valuable knowledge related to the investigation of the intrinsic nature characteristics of NaBaBO₃ in research fields pertaining to dosimetry.     

Progression of color decision making in introductory design education

Color comprises both subjective and objective aspects within its contextual nature. Research on color design tends to explore this seemingly contradictory concerns from theoretical point of view, as well as architectural and design practice. The aim of this study was to observe subjective, intuitive or heuristic and objective, knowledge‐based or analytical attitudes toward color in design education. In the study 84 introductory design students were surveyed progressively to understand their color decision criteria after completion of three 2‐dimensional colored exercises, specific in terms of color education. Students' responses to open‐ended questions were coded according to the 5 categories, under 2 decision making processes derived from the literature; heuristic approach: preferential and symbolic criteria, and analytic reasoning: formal, thematic, and systematic criteria. A distinction between associative and emotional aspects of symbolic criteria was also revealed by the data analysis. The findings showed a shift from heuristic responses to analytic reasoning, as expected. Additionally, it is also investigated that students not only used heuristic approaches but also analytical components (formal and systematic) of color decision making in varying degrees as well, even before any color subjects covered. Thematic color decisions became a major part of the students' design considerations upon completion of color subjects. The observed increase in the number of color criteria interrelated by the students' among almost all categories explicated a complex decision making process particularly in color design and education. These findings were expected to lead to some further understanding in color decision making in design.     

A Comparison of Single- and Multi-Objective Programming Approaches to Problems with Multiple Design Objectives

In this paper, we propose and compare single- and multi-objective programming (MOP) approaches to the language model (LM) adaptation that require the optimization of a number of competing objectives. In LM adaptation, an adapted LM is found so that it is as close as possible to two independently trained LMs. The LM adaptation approach developed in this paper is based on reformulating the training objective of a maximum a posteriori (MAP) method as an MOP problem. We extract the individual at least partially conflicting objective functions, which yields a problem with four objectives for a bigram LM: The first two objectives are concerned with the best fit to the adaptation data while the remaining two objectives are concerned with the best prior information obtained from a general domain corpus. Solving this problem in an iterative manner such that each objective is optimized one after another with constraints on the rest, we obtain a target LM that is a log-linear interpolation of the component LMs. The LM weights are found such that all the (at least partially conflicting) objectives are optimized simultaneously. We compare the performance of the SOP- and MOP-based solutions. Our experimental results demonstrate that the ICO method achieves a better balance among the design objectives. Furthermore, the ICO method gives an improved system performance.     

Anodic behaviour of fulvestrant and its voltammetric determination in pharmaceuticals and human serum on highly boron-doped diamond electrode using differential pulse adsorptive stripping voltammetry

The electrochemical oxidation of fulvestrant was made on highly boron-doped diamond electrode using differential pulse adsorptive stripping voltammetry. The highest current intensities were obtained by applying +1.10 V during 150 s for boron-doped diamond electrode. For boron-doped diamond electrode, linear responses were obtained for the concentrations between 1 × 10⁻⁶ and 8 × 10⁻⁵ M in standard samples and between 1 × 10⁻⁶ and 4 × 10⁻⁵ M in serum samples. The repeatability of the method was 0.55 RSD% for differential pulse adsorptive stripping voltammetry. The analytical values of the method are demonstrated by quantitative determination of fulvestrant in pharmaceutical formulations and human serum, without the need for separation or complex sample preparation, since there was no interference from the excipients and endogenous substances. Selectivity, reproducibility, and accuracy of the developed methods were demonstrated by recovery studies.     

Changes in Total Polar Compounds,Peroxide Value,Total Phenols and Antioxidant Activity of Various Oils Used in Deep Fat Frying

In this study, the effect of deep fat frying on oil degradation, total phenols (TP) and total antioxidant activity (TAA) of hazelnut, corn, soybean and olive oils were investigated. Oil degradation and oxidation were monitored by measuring the total polar compounds (TPC) and the peroxide value (PV). The amount of TPC in corn, soybean and olive oils increased significantly with the time increment (p < 0.05). The PV of the oils did not exceed the maximum acceptable limit of 10 mequiv O₂/kg after 125 min frying except for hazelnut oil (10.64 mequiv O₂/kg). Deep-fat frying did not cause any significant change in the TP of corn oil, soybean oil and olive oil (p < 0.05). A significant decrease in the antioxidant activity was observed after 50 min frying using hazelnut oil and corn oil (p < 0.05). However, the antioxidant activity of soybean oil and olive oil significantly decreased after 75 and 25 min frying, respectively.