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141.
Utilizing the solvothermal synthesis technique, lithium intercalated tungsten disulfide LixWS2 with x > 1 was obtained, which was allowed to react with water to the formation of single-molecule-layer suspension of tungsten disulfide. The layered nanocomposites PEG, PEO/WS2, intercalating poly(ethylene glycol) (PEG, MW ≈ 1 × 103, 6 × 103, 1 × 104) and poly(ethylene oxide) (PEO, MW ≈ 3 × 105) into the tungsten disulfide host galleries, were prepared using the improved exfoliation-adsorption technique. It was revealed that the intercalated polymers within the host galleries are in a double-layer arrangement with an interlayer expansion of about 9 Å. Despite high conductivity of the host material, those of the PEG, PEO/WS2 nanocomposites were found to be high in the order of 1 × 10−2 to 10−3 S cm−1 at ambient temperature, resulted from the guest-host charge transfers. 相似文献
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143.
Zhou D Lagoja IM Rozenski J Busson R Van Aerschot A Herdewijn P 《Chembiochem : a European journal of chemical biology》2005,6(12):2298-2304
Oligonucleotides that contain up to three aminopropyl nucleoside analogues have been synthesized. Dimers of aminopropyl adenine and thymidine were prepared and used as building blocks by applying phosphoramidite chemistry. Both R and S isomers of the aminopropyl nucleosides were used. This incorporation led to a reduction of thermal stability of double-stranded DNA. Furthermore, the (R)-adenine analogue, which yielded (S)-APNA, can be considered as a candidate for universal base pairing. 相似文献
144.
利用燃烧学理论及其相关知识对富氧燃烧技术的特点进行了详细的理论分析.在此基础上针对某公司拟在石灰回转窑中应用该技术的工程案例进行了计算,提出了3种不同的技改方案,并对其经济性进行了预测.结果表明在不改变现有燃烧设备的条件下,采用焦炉煤气和转炉煤气混合富氧的方案,氧体积分数控制在21.4%时最为合理;采用焦炉煤气和高炉煤气混合富氧的方案,氧体积分数控制在23.0%时最为合理;从成本分析前者更具有竞争性.如果对现有燃烧设备进行改造,建议采用转炉煤气和高炉煤气混合富氧的方案,氧体积分数控制为28.0%时,成本节约潜力最大,对该公司最有实用意义,此时对应的煤气流量约为20 km3/h. 相似文献
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147.
The partition coefficients of ethylene between hydrate and vapor for methane + ethylene + water and methane + ethylene + SDS + water systems 总被引:1,自引:0,他引:1
The hydrate formation of CH4+C2H4 mixture was studied experimentally in two different cases, with and without the presence of sodium dodecyl sulfate (SDS) in water. The results manifested that the presence of SDS could not only accelerate the hydrate formation process, but also increase the partition coefficient of ethylene between hydrate and vapor drastically. The partition coefficients of ethylene between hydrate and vapor for methane + ethylene + water with the presence of 500 ppm SDS in water were then systematically measured. The experimental temperature ranged from 273.15 to 278.15 K, the pressure ranged from 2.5 to 5.5 MPa, the initial gas-liquid volume ratio ranged from 95 to 240 standard volumes of gas per volume of liquid, and the mole percentage of ethylene in feed gas mixture ranged from 5.28% to 79.36%. The results demonstrated that ethylene could be enriched in hydrate phase and partition coefficients were increased with the presence of SDS in water. This conclusion is of industrial significance; it implies that it is feasible to recover ethylene from gas mixture, e.g., various kinds of refinery gases or cracking gases in ethylene plant, by forming hydrate. 相似文献
148.
Electrolytic recovery of chlorine from hydrogen chloride gas with fused molten salt electrolyte LiCl/KCl 总被引:1,自引:0,他引:1
A method of electrolytic recovery of chlorine from hydrogen chloride gas based on the fused molten salt LiCl/KCl is under development. For the feasibility study, described here, a reticulated vitreous carbon (or porous carbon) cathode was immersed in a low-melting eutectic of LiCl/KCl. A graphite rod was used as the anode. Gaseous dilute hydrogen chloride, in a mixture with nitrogen, was reduced to elemental hydrogen and chloride at the cathode, and chlorine was produced at the anode. At stoichiometric current, current efficiency is greater than 90%. The removal efficiency is as high as 97%.Patent pending (May 1995). 相似文献
149.
150.
介绍了国外利用天然气生产油口的生产工艺,探讨了山西省利用丰富的煤层气资源发展合成油的可能性和优势,并提出了相应的发展建议。 相似文献