Metal micro-/nano hollow spheres have been widely applied in numerous fields during the last decade. This review will only focus on the synthetic strategies to synthesize hollow spherical structures in the enhancement of their electrocatalytic activity, especially the metal hollow spherical materials. We present a comprehensive overview of synthetic strategies for metal hollow spherical structures which have been approached specifically in electrochemical reactions. These synthetic methods are mainly categorized as hard templates, soft templates, sacrificial templates and without templates. The review further includes electrocatalytic approaches of hollow spherical metals in different electrochemical processes, especially the methanol electro-oxidation reaction for methanol fuel cell application and hydrogen and oxygen evolution reactions in water electrolyzer, as metal hollow spherical materials are especially applied in these specific reactions. 相似文献
The effect of removing anti‐nutritional factors from n‐hexane‐extracted mustard meal using 80% isopropanol (to reduce thioglucosides, phenolics, etc.) on growth, food efficiency ratio, serum and liver lipid profiles and protein content of young rats was examined. For this n‐hexane‐extracted mustard meal was extracted with 80% isopropanol giving a fraction with 68% protein and low residual thioglucoside (0.5%) as well as phenolic (0.3%) content. This isopropanol‐extracted mustard seed protein fraction reduced the growth of young rats slightly when compared with casein. The food efficiency ratio between rats fed isopropanol‐extracted mustard seed protein or casein did not differ, nor did the protein composition affect serum total cholesterol, triglyceride, HDL‐cholesterol, LDL‐cholesterol, VLDL‐cholesterol and LDL‐C/HDL‐C ratio. However, rats fed isopropanol‐extracted mustard seed protein showed a significantly lower (p<0.05) liver cholesterol concentration than rats fed casein. Liver triglyceride and phospholipid concentrations did not differ between rats fed the two proteins, nor was serum protein affected. This study indicates that extraction of hexane‐extracted mustard meal with 80% isopropanol reduced a number of anti‐nutritional factors like thioglucoside and phenolics. Furthermore the nutritional quality of mustard seed protein fraction is comparable to casein in respect to growth, food efficiency ratio, serum lipid and protein concentrations and organ weights. 相似文献
The authors have successfully designed and developed an Electrochemical Machining set-up with a microprocessor-controlled stepper motor drive control unit for providing variable and automatic tool feed rates and also with an electronic circuit for auto-sensing of changes of the ECM gap condition during the course of machining, so as to actuate the auto-feedback control of the tool feed-rate and thus secure constant current Electrochemical Machining.
The present paper also highlights various research results with the auto-feed ECM system for analysing the effect of some of the process variables, e.g. the electrolyte flow rate, the electrolyte concentration, the current density and the applied voltage, on the various surface-roughness parameters and bearing properties of the machined surface, as measured with the help of a computerised Talysurf unit. The test results indicate clearly the optimal parametric combinations that are needed for enhanced metal removal and better surface finish and other surface topographical characteristics, with the present design of auto-tool-feed control. It is evident from the test results that the present study on ECM will be quite useful and a step forward for proceeding with further applied research for achieving effective utilisation of ECM in practice, with better surface-quality characteristics so as to meet the needs of modern manufacturing industry. 相似文献
Coal fired electric power plants produce large volumes of fly ash and other coal combustion by-products (CCBs) every year. Although almost 50% of the fly ash produced in the US is recycled for beneficial use, most of the ash material is disposed in dry landfills and ash lagoon impoundments. Fly ash may contain hazardous leachable trace elements such as As, B, Cr, Mo, Ni, Se, Sr and V which have a negative impact on the environment due to potential leaching by acid rain and groundwater with time. Many of the older CCB disposal facilities are unlined and unmonitored and as a result the EPA is currently developing national standards for monitoring CCB disposal sites. The cost to the US electric power industry could exceed one billion dollars if existing and closed CCB disposal facilities come under regulation. Thus simple, low-cost and effective in situ chemical treatment techniques are needed to stabilize hazardous leachable trace elements in the coal combustion by-product (CCB) materials. This paper reports the results of experiments designed to chemically treat fly ash with ferrous sulfate solutions to immobilize hazardous leachable trace elements after disposal.The current study is focused on three acidic and one alkaline fly ash samples collected from electric power plants located in the southeastern United States that were treated with two ferrous sulfate treatment solutions. The first treatment solution contained ferrous sulfate (FS) to give 322 mg/L of dissolved iron, while the second treatment solution contained the same concentration of ferrous sulfate along with excess calcium carbonate (FS + CC) to buffer the pH. Fly ash treatment experiments were carried out at solid:liquid (S:L) ratios of 1:3 and 1:30. The effectiveness of the treatment methods was evaluated by sequentially leaching the treated and the untreated fly ash samples using a synthetic acid rain (SAR) solution (US EPA Method 1312B SPLP fluid) as the leachate. The best overall treatment result was shown by the unbuffered ferrous sulfate solution at the 1:30 S:L ratio, which substantially reduced the mobility of the oxyanion trace elements. The overall mobility reduction achieved for As was 23-72%, B mobility was reduced by 43-80%, Cr by 45-77%, Mo by 21-90%, Se by 41-85% and V by 41-53% The unbuffered ferrous sulfate treatment was not effective for immobilization of the cationic trace elements Ni and Sr. 相似文献
The effect of turbulence on several freshwater diatom taxa was investigated and our findings are described herein. We have
compared diatom morphology in shallow natural systems that experience turbulence due to wind and in river/waterfall systems
where turbulence is due to high flow rates. We have also introduced turbulence into diatom laboratory cultures by mechanical
shaking and by forcing air into the media. In particular, we have studied diatoms in five independent environments or cultures:
the freshwater diatoms Tabellaria and Eunotia in equatorial lakes experiencing extreme seasonal variability in depth; two freshwater diatom monocultures of Aulacoseira granulata var angustissima and Melosira varians in the laboratory; and a freshwater diatom community possessing equal amounts (by number) of elongated and non-elongated
diatoms (mostly Nitzschia and mostly Cyclotella, respectively) in the laboratory. We have demonstrated the effect of turbulence on freshwater diatom frustule morphologies
and, perhaps more importantly, the effect of turbulence on freshwater diatom species population after controlled perturbation
of the organisms’ environment. It has been widely reported that symmetry is often preferred in biological evolution, however
here we have observed a preference towards asymmetry for the survival of diatoms in the presence of environmental stress (in
particular, turbulence). We also note that to date there have been no systematic attempts to manipulate diatom frustules using
external stimuli. We therefore present a proof-of-concept study in order to demonstrate: (i) that diatom morphologies can
be manipulated by controlled simple external triggers (chemical and physical) (ii) that population balance (i.e. natural selection)
can be controlled via simple external triggers (chemical and physical). This approach could open up an entire new field of future studies wherein
controlled environmental perturbations are used to manipulate the structure, form, growth and reproduction of biological species. 相似文献