Self organisation and photoinduced charge transfer in single-wall carbon nanotubes embedded in a thermotropic liquid crystal polymer

A hybrid material composed by a thermotropic liquid crystal (LCP) polymer (HBA–PET) and single wall carbon nanotubes has been produced in order to study the interaction at the interface matrix/filler for possible applications in electronics and optics. The nanocomposites are characterized by a mosaic-like morphology, with regions of randomly placed LC fibers intercalated with regions formed by aligned polymer fibers, that trigger in turn the alignment of carbon nanotube bundles by means of P stacking interaction. Moreover an effective electronic interaction between the nanocomposite components is demonstrated by combining use of photoluminescence and Raman spectroscopy. The photoinduced charge transfer between SWCNT and polymer could be explain on the basis of the injection of holes (generated in the polymer by light absorption), into the SWCNT valence band and followed by a radiationless decay of the excited polymer’s electron.     

Critical N concentration can vary with growth conditions in forage grasses: implications for plant N status assessment and N deficiency diagnosis

The N nutrition index (NNI, defined as the actual shoot N concentration relative to a reference critical value, N_ref) is a valuable tool to analyze the N nutrition status of crops. We present empirical evidence obtained for a range of forage grass species and environmental conditions with the aim to contribute to verify the NNI as a tool to diagnose N deficiency and to examine responses to N fertilization. Ten N fertilization experiments were conducted in the SE of the Pampa region (Argentina) and included (1) perennial (Festuca arundinacea Schreb. Thinoppyron ponticum (Podp.) Barkworth and Dewey) and annual (Lolium multiflorum Lam., Avena sativa L. Bromus catharticus H.B.K.) grasses, (2) autumn, winter and spring regrowths, and (3) good and poor quality soils. Experiments comprised four to six N fertilization rates, each including five to seven sequential harvest dates. Plots were replicated in three or four complete randomized blocks. All experiments were rainfed and adequately provided with phosphorus. The critical N concentration (N_cr) -that is the minimum plant N concentration required to reach maximal accumulated shoot biomass- was determined for each harvest date. Observed N_cr were then compared to values predicted by the general reference curve (N_ref) proposed elsewhere. In six of the ten experiments measured N_cr agreed with predicted N_ref. Thus, the present study extends to marginal soils, to species adapted to such environment, and to winter growth conditions the empirical support for the use of N_ref in the quantification of pasture N deficiency. But N_cr was lower than N_ref in four experiments in which growth conditions were not adequate for reaching potential growth rates. Therefore, it is suggested that when factors other than N are expected to limit pasture growth, an N_cr lower than N_ref should be considered. In all experiments, a direct relationship between accumulated shoot biomass and NNI was found, radiation use efficiency (RUE) being more negatively affected than photosinthetically active radiation interception (PARi) by N deficiency. Reductions in the latter were relevant only from moderate to severe N deficiency. Notably, the NNI achieved at initial stages of regrowth (150-200°C day after the fertilization date) was highly associated with the N nutritional status along the regrowth and, therefore, confirming NNI as a promising tool for diagnostic purposes.     

Redox-active electrolyte for carbon nanotube-based electric double layer capacitors

The specific capacitance of the MWCNTs was improved by the addition of an electrochemically active compound (indigo carmine) to an electrolyte generally used in electric double layer capacitors. The pseudocapacitive contribution of the IC trebled the specific capacitance values of the MWCNTs at low current densities (from 17 Fg⁻¹ to 50 Fg⁻¹). The good resistance obtained for the MWCNT-based capacitor was not modified with the use of this novel redox-active electrolyte. A reversible process associated to the redox reaction of IC was found to be responsible for the capacitance increase observed. Therefore, a combined effect of double layer formation and pseudocapacitive phenomena is presented. Long-term cycling experiments performed showed good stability with a reduction of the initial capacitance values of 30% after 10,000 galvanostatic cycles at 360 mAg⁻¹. The efficiency of the cell was close to 100% throughout the experiment.     

Origin of rheological behavior and surface/interfacial properties of some semi-alicyclic polyimides for biomedical applications

High-performance alicyclic-containing polyimides for advanced applications, derived from 5-(2,5-dioxotetrahydrofurfuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic acid anhydride or bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride and two flexible aromatic diamines, were synthesized by a classical two-step polycondensation reaction and analyzed by rheological method. The results were discussed according to the chemical structure of polyimides and their different properties, such as flexibility, hydrophobicity and surface morphology. It has been showed that the obtained parameters, controlled by the interactions occurring in the polyimide systems, can be correlated with the adhesion/cohesion of blood components and plasma proteins. Thus, the results of the work of spreading proteins on the hydrophobic polyimide surfaces indicated that albumin is not absorbed preferentially, while fibrinogen is characterized by a higher degree of adhesion on the surfaces, and also that selective adsorption of plasma proteins modifies blood compatibility. In addition, these results and the ascertained antimicrobial activity of the studied polyimides contribute to the development of new applications in the bio-technical field.     

Influence of CYP1A2 and NAT2 Metabolic Phenotypes on Smokers' Urinary Mutagenicity

The influence of the metabolic phenotypes NAT2 and CYP1A2 on urinary mutagenicity of 118 smokers was studied. Mutagenicity of urine samples was determined by Ames test (preincubation plate incorporation assay on YG1024 Salmonella typhimurium strain with S9 mix). Urinary nicotine plus its metabolites were determined to check cigarette smoke intake. The N -acetyltransferase (NAT2) and cytochrome P450 1A2 (CYP1A2) phenotypes were measured by the molar ratio of urinary caffeine metabolites, determined by HPLC analysis. Urinary mutagenicity was significantly higher in smokers CYP1A2 extensive (EM) than in CYP1A2 poor metabolizers (PM) (Mann-Whitney U test, p = 0.020). Linear multiple regression analysis shows that an increase in urinary mutagenicity levels was significantly related to cigarette smoke intake and to CYP1A2 N -hydroxylation activity ( t = 5.06, p < 0.001, and t = 2.33, p = 0.021), but not to NAT2 acetylation phenotype. In conclusion, phenotypic differences in metabolic activation of tobacco smoke mutagens are able to modulate the presence of mutagens in urine of cigarette smokers and, consequently, the potential genotoxic risk.