分光光度法同时测定油脂中氢过氧化物和醛含量

采用分光光度法同时测定油脂中氢过氧化物和醛含量,对有关参数进行了研究和优化。结果表明:N,N-二甲基对苯二胺为显色剂,乙酸为催化剂,40℃下反应40 min,用Kaiser法得出的最佳分析波长350、408 nm处可同时准确测定油脂中的氢过氧化物和丙二醛的含量;在120℃进行氧化,并对不同氧化程度的大豆油和鳄梨油中的氢过氧化物和丙二醛含量进行测定,测定结果与标准方法对比无显著性差异。     

杨木胶合板动态杨氏模量的检测与分析

基于LabVIEW软件采用共振法和敲击法测定杨木胶合板的动态杨氏模量,并与其静态力学性能对比。结果表明:敲击法和共振法得到的动态杨氏模量值较为接近;共振法得到的动态杨氏模量与胶合板的静曲强度、弹性模量呈显著线性回归;杨木胶合板的动态杨氏模量与取样方向有关,沿表板纹理纵向测定值大于横向测定值,且纵向动态杨氏模量与密度呈显著线性相关。     

Highly Flexible and Stretchable Nanowire Superlattice Fibers Achieved by Spring‐Like Structure of Sub‐1 nm Nanowires

Conventional inorganic nanowire (NW) fibers are usually not stretchable and elastic, which may limit their practical applications. Inspired by the similarity between inorganic sub‐1 nm NWs and polymer chains in dimension, and helical spring‐like structure of cellulose in cherry bark, highly flexible and stretchable NW superlattice fibers composed of sub‐1 nm GdOOH NWs are fabricated. The NW fibers could be twined, bent, twisted, and tied without any damage. When the strain is less than 10%, the fibers present elastic deformation. The elongation at break of the fibers usually reaches ≈40–50% and the highest elongation could reach ≈86%. Excellent flexibility and stretchability of the NW fibers are attributed to the well‐aligned spring‐like NWs assembled superlattice, which are demonstrated by scanning electron microscopy tests, synchrotron small‐angle X‐ray scattering, and obvious birefringence. Moreover, NW‐nanoparticle (NP) fibers are fabricated, inspired by inorganic nanoparticle–reinforced polymers. The strength is improved compared with the NW fibers. Based on this work, it is possible to fabricate multifunctional, flexible, and stretchable inorganic NW materials composed of different inorganic sub‐1 nm NWs, which may be useful in practical applications.     

Effect of annealing treatment on optical properties and microstructural variation of $$\hbox {WO}_{3}/\hbox {Ag}/\hbox {WO}_{3}$$ multilayer nano-films

Structural and optical properties of \(\text {WO}_{3}/\text {Ag}/\text {WO}_{3}\) nano-multilayer composites were investigated for heat mirror applications. \(\text {WO}_{3}/\text {Ag}/\text {WO}_{3}\) thin films were fabricated through a physical vapour deposition method by using electron-beam evaporation at the vacuum chamber at 10\(^{-5}\) Torr. \(\text {WO}_{3}\) nano-layer was fabricated at 40 nm. Annealing treatment was carried out at 100, 200, 300 and 400\(^{\circ }\)C for 1 h after the deposition of first layer of \(\text {WO}_{3}\) on the glass. On \(\text {WO}_{3}\) film, Ag nano-layers with 10, 12 or 14 nm thickness were deposited. Individual layers morphology was investigated using atomic force microscopy (AFM) and deduced that a smoother layer can be achieved after the annealing at 300\(^{\circ }\)C. Ellipsometry analysis was executed to determine both layers, Ag film thickness and inter-diffusion between the \(\text {WO}_{3}\)–Ag–\(\text {WO}_{3}\) layers. It was inferred that there was almost no interfering among the \(\text {WO}_{3}\)–\(\text {WO}_{3 }\) layers in the samples with 12 and 14 nm Ag thickness; while silver was deposited on the annealed \(\text {WO}_{3}\) layer at 300\(^{\circ }\)C. UV–visible spectrophotometer showed that the annealing treatment of the first \(\text {WO}_{3}\) layer enhanced the transparency of films in the visible region. The innovations of the present study have been based on the annealing of the films and finding an optimum thickness for the Ag film at 12–14 nm. Heat mirrors efficiency was assessed according to the principle of their optical behaviour and optimum performance obtained for 14 nm of Ag film, deposited on annealed tungsten oxide at 300\(^{\circ }\)C.     

Low-temperature catalytic combustion of benzene over Zr–Mn mixed oxides synthesized by redox-precipitation method

Journal of Materials Science - Zr-Mn mixed oxides with various Zr/Mn molar ratios were synthesized by redox-precipitation method and applied to benzene catalytic combustion. The results showed that...     

Direct Detection of Local Electric Polarization in the Interfacial Region in Ferroelectric Polymer Nanocomposites

Ferroelectric polymer nanocomposites are widely used in capacitive energy storage, electrocaloric refrigeration, and mechanical energy harvesting due to their exceptional electric polarization property and ease of fabrication. It is generally considered that the abnormal performance of ferroelectric nanocomposites stems from the interfacial region between the polymer matrix and embedded nanoparticles. However, direct evidence of the distinct local electric polarization property at the interfacial region is not yet accessible. Herein, a modified Kelvin probe force microscopy (KPFM) method with nanoscale spatial resolution is reported for direct detection of local polarization property at the matrix/particle interface in ferroelectric nanocomposites. Typical ferroelectric nanocomposites are studied using the present method. It is quantitatively probed that the electric polarization at matrix/particle interfacial region is higher than the polymer matrix under applied electric fields. Taking into account the enhanced local electric polarization gauged by the modified KPFM, the dielectric property of ferroelectric polymer nanocomposites matches with bulk experimental characterizations, indicating that the established method is reliable. It is anticipated that the present method, opening up new possibilities in understanding the matrix/particle interfacial region, may help with judicious design and engineering of high‐performance ferroelectric polymer nanocomposites.     

一类新型保健食品—低聚糖

低聚糖作为甜味剂有着优越的功能：难消化,低能量,增加肠内双歧杆菌,降低血液中的油脂和胆固醇,改善肠内微生物群,促进动物生长,防龋齿,防糖尿病等．本文对低聚糖及其生产方法．低聚糖作食品添加剂的功能作了简单介绍．     

Two-stage Photograph Cartoonization via Line Tracing

Cartoon is highly abstracted with clear edges, which makes it unique from the other art forms. In this paper, we focus on the essential cartoon factors of abstraction and edges, aiming to cartoonize real-world photographs like an artist. To this end, we propose a two-stage network, each stage explicitly targets at producing abstracted shading and crisp edges respectively. In the first abstraction stage, we propose a novel unsupervised bilateral flattening loss, which allows generating high-quality smoothing results in a label-free manner. Together with two other semantic-aware losses, the abstraction stage imposes different forms of regularization for creating cartoon-like flattened images. In the second stage we draw lines on the structural edges of the flattened cartoon with the fully supervised line drawing objective and unsupervised edge augmenting loss. We collect a cartoon-line dataset with line tracing, and it serves as the starting point for preparing abstraction and line drawing data. We have evaluated the proposed method on a large number of photographs, by converting them to three different cartoon styles. Our method substantially outperforms state-of-the-art methods in terms of visual quality quantitatively and qualitatively.     

基于剪枝技术和鲁棒蒸馏融合的轻量对抗攻击防御方法

对抗训练是一类常用的对抗攻击防御方法,其通过将对抗样本纳入训练过程,从而有效抵御对抗攻击。然而,对抗训练模型的鲁棒性通常依赖于网络容量的提升,即对抗训练所获得的网络为防御对抗攻击而大幅提升网络的模型容量,对其可用性造成较大约束。因此,如何在保证对抗训练模型鲁棒性的同时,降低模型容量,提出轻量对抗攻击防御方法是一大挑战。为解决以上问题,提出一种基于剪枝技术和鲁棒蒸馏融合的轻量对抗攻击防御方法。该方法以对抗鲁棒准确率为优化条件,在对预训练的鲁棒对抗模型进行分层自适应剪枝压缩的基础上,再对剪枝后的网络进行基于数据过滤的鲁棒蒸馏,实现鲁棒对抗训练模型的有效压缩,降低其模型容量。在CIFAR-10和CIFAR-100数据集上对所提出的方法进行性能验证与对比实验,实验结果表明,在相同 TRADES 对抗训练下,所提出的分层自适应剪枝技术相较于现有剪枝技术,其剪枝所得到的网络结构在多种 FLOPs 下均表现出更强的鲁棒性。此外,基于剪枝技术和鲁棒蒸馏融合的轻量对抗攻击防御方法相较于其他鲁棒蒸馏方法表现出更高的对抗鲁棒准确率。因此,实验结果证明所提方法在降低对抗训练模型容量的同时,相较于现有方法具有更强的鲁棒性,提升了对抗训练模型在物联网边缘计算环境的适用性。