Materials for supercapacitors: When Li-ion battery power is not enough

Supercapacitors, also known as electrochemical capacitors, have witnessed a fast evolution in the recent years, but challenges remain. This review covers the fundamentals and state-of-the-art developments of supercapacitors. Conventional and novel electrode materials, including high surface area porous carbons for electrical double layer capacitors (EDLCs) and transition metal oxides, carbides, nitrides and their various nanocomposites for pseudocapacitors – are described. Latest characterization techniques help to better understand the charge storage mechanisms in such supercapacitors and recognize their current limitations, while recently proposed synthesis approaches enable various breakthroughs in this field.     

Improving the SMAC atmospheric correction code by analysis of Meteosat Second Generation NDVI and surface reflectance data

In order to obtain high quality data, the correction of atmospheric perturbations acting upon land surface reflectance measurements recorded by a space-based sensor is an important topic within remote sensing. For many years the Second Simulation of the Satellite Signal in the Solar Spectrum (6S) radiative transfer model and the Simplified Method for Atmospheric Correction (SMAC) codes have been used for this atmospheric correction, but previous studies have shown that in a number of situations the quality of correction provided by the SMAC is low. This paper describes a method designed to improve the quality of the SMAC atmospheric correction algorithm through a slight increase in its computational complexity. Data gathered from the SEVIRI aboard Meteosat Second Generation (MSG) is used to validate the additions to SMAC, both by comparison to simulated data corrected using the highly accurate 6S method and by comparison to in-situ and 6S corrected SEVIRI data gathered for two field sites in Africa. The additions to the SMAC are found to greatly increase the quality of atmospheric correction performed, as well as broaden the range of atmospheric conditions under which the SMAC can be applied. When examining the Normalised Difference Vegetation Index (NDVI), the relative difference between SMAC and in-situ values decreases by 1.5% with the improvements in place. Similarly, the mean relative difference between SMAC and 6S reflectance values decreases by a mean of 13, 14.5 and 8.5% for Channels 1, 2 and 3 respectively. Furthermore, the processing speed of the SMAC is found to remain largely unaffected, with only a small increase in the time taken to process a full SEVIRI scene. Whilst the method described within this paper is only applicable to SEVIRI data, a similar approach can be applied to other data sources than SEVIRI, and should result in a similar accuracy improvement no matter which instrument supplies the original data.     

Dynamical information fusion of heterogeneous sensors for 3D tracking using particle swarm optimization

This paper presents a new method for three dimensional object tracking by fusing information from stereo vision and stereo audio. From the audio data, directional information about an object is extracted by the Generalized Cross Correlation (GCC) and the object’s position in the video data is detected using the Continuously Adaptive Mean shift (CAMshift) method. The obtained localization estimates combined with confidence measurements are then fused to track an object utilizing Particle Swarm Optimization (PSO). In our approach the particles move in the 3D space and iteratively evaluate their current position with regard to the localization estimates of the audio and video module and their confidences, which facilitates the direct determination of the object’s three dimensional position. This technique has low computational complexity and its tracking performance is independent of any kind of model, statistics, or assumptions, contrary to classical methods. The introduction of confidence measurements further increases the robustness and reliability of the entire tracking system and allows an adaptive and dynamical information fusion of heterogenous sensor information.     

Stable splitting scheme for general form of associated plasticity including different scales of space and time

An efficient implementation of the operator split procedure for boundary value solution with plastic flow computation is presented for a general form of associated plasticity model. We start with the general form of phenomenological model of plasticity where the yield criterion is not restricted to a simple (quadratic) form, and the elasticity tensor does not have constant entries. We then turn to the multi-scale model of plasticity which employs the fine scale representation of the plastic deformation along with the homogenization procedure for stress computation. We also visit the plasticity model with rate sensitive plastic response where plastic flow computation is carried out at fine scale in time. We proved herein the sufficient and necessary conditions for the proposed operator split procedure to converge, for any such general form of associated plasticity. Moreover, we presented a systematic manner for constructing the main ingredients for the plastic flow computation and the global Newton’s iteration, such as the consistent elastoplastic tangent.     

Multi-spectral fusion for surveillance systems

Surveillance systems such as object tracking and abandoned object detection systems typically rely on a single modality of colour video for their input. These systems work well in controlled conditions but often fail when low lighting, shadowing, smoke, dust or unstable backgrounds are present, or when the objects of interest are a similar colour to the background. Thermal images are not affected by lighting changes or shadowing, and are not overtly affected by smoke, dust or unstable backgrounds. However, thermal images lack colour information which makes distinguishing between different people or objects of interest within the same scene difficult.By using modalities from both the visible and thermal infrared spectra, we are able to obtain more information from a scene and overcome the problems associated with using either modality individually. We evaluate four approaches for fusing visual and thermal images for use in a person tracking system (two early fusion methods, one mid fusion and one late fusion method), in order to determine the most appropriate method for fusing multiple modalities. We also evaluate two of these approaches for use in abandoned object detection, and propose an abandoned object detection routine that utilises multiple modalities. To aid in the tracking and fusion of the modalities we propose a modified condensation filter that can dynamically change the particle count and features used according to the needs of the system.We compare tracking and abandoned object detection performance for the proposed fusion schemes and the visual and thermal domains on their own. Testing is conducted using the OTCBVS database to evaluate object tracking, and data captured in-house to evaluate the abandoned object detection. Our results show that significant improvement can be achieved, and that a middle fusion scheme is most effective.     

Hard multidimensional multiple choice knapsack problems, an empirical study

Recent advances in algorithms for the multidimensional multiple choice knapsack problems have enabled us to solve rather large problem instances. However, these algorithms are evaluated with very limited benchmark instances. In this study, we propose new methods to systematically generate comprehensive benchmark instances. Some instances with special correlation properties between parameters are found to be several orders of magnitude harder than those currently used for benchmarking the algorithms. Experiments on an existing exact algorithm and two generic solvers show that instances whose weights are uncorrelated with the profits are easier compared with weakly or strongly correlated cases. Instances with classes containing similar set of profits for items and with weights strongly correlated to the profits are the hardest among all instance groups investigated. These hard instances deserve further study and understanding their properties may shed light to better algorithms.     

Infinite factorization of multiple non-parametric views

Combined analysis of multiple data sources has increasing application interest, in particular for distinguishing shared and source-specific aspects. We extend this rationale to the generative and non-parametric clustering setting by introducing a novel non-parametric hierarchical mixture model. The lower level of the model describes each source with a flexible non-parametric mixture, and the top level combines these to describe commonalities of the sources. The lower-level clusters arise from hierarchical Dirichlet Processes, inducing an infinite-dimensional contingency table between the sources. The commonalities between the sources are modeled by an infinite component model of the contingency table, interpretable as non-negative factorization of infinite matrices, or as a prior for infinite contingency tables. With Gaussian mixture components plugged in for continuous measurements, the model is applied to two views of genes, mRNA expression and abundance of the produced proteins, to expose groups of genes that are co-regulated in either or both of the views. We discover complex relationships between the marginals (that are multimodal in both marginals) that would remain undetected by simpler models. Cluster analysis of co-expression is a standard method of screening for co-regulation, and the two-view analysis extends the approach to distinguishing between pre- and post-translational regulation.     

Development of a biological detection platform utilizing a modular microfluidic stack

The goal of this project is to build a miniaturized, user-friendly cytometry setup (Datta et al. in Microfluidic platform for education and research. COMS, Baton Rouge, 2008; Frische et al. in Development of an miniaturized flow cytometry setup for visual cell inspection and sorting. Baton Rouge, Project Report, 2008) by combining a customized, microfluidic device with visual microscope inspection to detect and extract specific cells from a continuous sample flow. We developed a cytological tool, based on the Coulter particle counter principle, using a microelectrode array patterned on a borosilicate glass chip as electrical detection set-up which is fully embedded into a polymeric multi-layer microfluidic stack. The detection takes place between pairs of coplanar Cr/Au microelectrodes by sensing an impedance change caused by particles continuously carried within a microfluidic channel across the detection area under laminar flow conditions. A wide frequency range available for counting provides information on cell size, membrane capacitance, cytoplasm conductivity and is potentially of interest for in-depth cell diagnostic e.g. to detect damaged or cancerous cells and select them for extraction and further in-depth analysis.