全文获取类型
收费全文 | 502篇 |
免费 | 38篇 |
国内免费 | 11篇 |
专业分类
电工技术 | 13篇 |
综合类 | 2篇 |
化学工业 | 132篇 |
金属工艺 | 11篇 |
机械仪表 | 27篇 |
建筑科学 | 29篇 |
矿业工程 | 1篇 |
能源动力 | 39篇 |
轻工业 | 48篇 |
水利工程 | 8篇 |
石油天然气 | 8篇 |
武器工业 | 2篇 |
无线电 | 36篇 |
一般工业技术 | 101篇 |
冶金工业 | 22篇 |
原子能技术 | 3篇 |
自动化技术 | 69篇 |
出版年
2024年 | 5篇 |
2023年 | 14篇 |
2022年 | 19篇 |
2021年 | 38篇 |
2020年 | 19篇 |
2019年 | 30篇 |
2018年 | 25篇 |
2017年 | 21篇 |
2016年 | 27篇 |
2015年 | 15篇 |
2014年 | 23篇 |
2013年 | 49篇 |
2012年 | 36篇 |
2011年 | 32篇 |
2010年 | 25篇 |
2009年 | 28篇 |
2008年 | 21篇 |
2007年 | 28篇 |
2006年 | 19篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 6篇 |
2002年 | 8篇 |
2001年 | 9篇 |
2000年 | 11篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 6篇 |
1993年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有551条查询结果,搜索用时 15 毫秒
91.
Poly‐electrolyte N‐vinyl 2‐pyrrolidone‐g‐tartaric acid (PVP‐g‐TA) hydrogels with varying compositions were prepared in the form of rods from ternary mixtures of N‐vinyl 2‐pyrrolidone/tartaric acid/water. The effect of external stimuli, such as the solution pH, ionic strength, and temperature, on uranyl adsorption by these hydrogels was investigated. Uranyl adsorption capacities of the hydrogels were determined to be 53.2–72.2 (mg UO/g dry gel) at pH 1.8, and 35.3–60.7 (mg UO/g dry gel) at pH 3.8, depending on the amount of TA in the hydrogel. The adsorption studies have shown that the temperature and the ionic strength of the swelling solution also influence uranyl ion adsorption by PVP‐g‐TA hydrogels. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 2219–2226, 2000 相似文献
92.
Gulbeyi Dursun John M. Winterbottom 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1998,73(4):389-397
Perovskite oxide structured YBa2Cu3O7-x(YBCO) has been first prepared by carbonate precipitation and then modified with palladium or ruthenium by impregnation on the perovskite oxide, while cobalt was co-precipitated simultaneously in the same pH range with perovskite oxide. After characterization the catalysts were used in the temperature range 300–450°C, in the pressure range 1–9 atmospheres and for H2/CO ratios in the range 1–4 in a differential plug flow reactor for the hydrogenation of carbon monoxide to give hydrocarbons. The perovskite oxide (YBCO) 20% (w/w) and doped 2% (w/w) cobalt oxide catalyst were prepared by the wet chemical method from their nitrate solutions and oxidized at 950°C. Perovskite oxide (Dursun, G. & Winterbottom, J. M., J. Chem. Technol Biotechnol. 63 (1995) 113–16) was also doped with palladium and ruthenium metal by impregnation followed by oxidation at 250°C. The catalysts prepared were characterized by using TemperatureProgrammed Reduction (TPR) to observe the reduction temperature and also to measure total and metal surface area. The modified perovskite oxide on alumina, ruthenium- and cobalt-doped catalysts, has been shown to give a better conversion and also selectivity towards saturated hydrocarbons compared with palladium-doped catalyst. The temperature effect of these catalysts is more consistent, giving a steady increase of conversion with increasing temperature. Although increase of pressure increases the conversion, it causes very little change in product distribution. The activation energy of palladium- and ruthenium-doped, and cobalt co-precipitated catalysts for the reaction has been measured to be 55 kJ mol−1, 75 kJ mol−1 and 50 kJ mol−1 respectively. A general rate equation of the form r=k[H2]m[CO]n has been observed and found to be applicable at the pressures and temperatures used for the catalytic system studied and found to be m≌1·0 for palladium-doped, m≌1·2 for ruthenium-doped and m≌0·95 for cobalt co-precipitated catalysts as n becomes zero or negligibly less than zero. The mechanism of reaction to produce hydrocarbons from syngas has been deduced from the results. It appeared that the carbon monoxide insertion mechanism has been more evident for palladium-doped catalysts whereas the carbide mechanism plays the main role for the ruthenium-doped and cobalt co-precipitated catalysts. © 1998 Society of Chemical Industry 相似文献
93.
Acrylamide/itaconic acid hydrogels (AAm/IA) containing different amounts of itaconic acid prepared by irradiating with γ radiation were used in experiments on swelling, diffusion, and interactions of the pharmaceuticals nicotine, nicotinic acid, nicotinamide, and nikethamide. AAm/IA hydrogel containing 60 mg itaconic acid and irradiated at 4.65 kGy has been used for swelling and diffusion studies in water and aqueous solutions of the pharmaceuticals. For this hydrogel, swelling studies indicated that swelling increased with the following order: water > nicotine > nikethamide > nicotinamide > nicotinic acid. Diffusions of water and the pharmaceuticals within hydrogels were found to be non-Fickian in character. The uptake of the pharmaceuticals to AAm/IA hydrogels was studied by batch adsorption technique at 25°C. In the experiments of the adsorption, C-type adsorption in Giles's classification system was found. Some binding and thermodynamic parameters for AAm/IA hydrogel-pharmaceutical systems were calculated by using the Klotz method. The values of adsorption heat, free energy, and entropy of this system were found as negative values. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 733–739, 1997 相似文献
94.
Eusebio Chiefari Maria Mirabelli Sandro La Vignera Sinan Tanyola Daniela Patrizia Foti Antonio Aversa Antonio Brunetti 《International journal of molecular sciences》2021,22(20)
Insulin resistance (IR) is a condition which refers to individuals whose cells and tissues become insensitive to the peptide hormone, insulin. Over the recent years, a wealth of data has made it clear that a synergistic relationship exists between IR, type 2 diabetes mellitus, and cancer. Although the underlying mechanism(s) for this association remain unclear, it is well established that hyperinsulinemia, a hallmark of IR, may play a role in tumorigenesis. On the other hand, IR is strongly associated with visceral adiposity dysfunction and systemic inflammation, two conditions which favor the establishment of a pro-tumorigenic environment. Similarly, epigenetic modifications, such as DNA methylation, histone modifications, and non-coding RNA, in IR states, have been often associated with tumorigenesis in numerous types of human cancer. In addition to these observations, it is also broadly accepted that gut microbiota may play an intriguing role in the development of IR-related diseases, including type 2 diabetes and cancer, whereas potential chemopreventive properties have been attributed to some of the most commonly used antidiabetic medications. Herein we provide a concise overview of the most recent literature in this field and discuss how different but interrelated molecular pathways may impact on tumor development. 相似文献
95.
High chrome white cast iron is particularly preferred in the production of machine parts requiring high wear resistance. Although the amount of chrome in these materials provides high wear and corrosion resistances, it makes their machinability difficult. This study presents an application of the grey relational analysis based on the Taguchi method in order to optimize chrome ratio, cutting speed, feed rate, and cutting depth for the resultant cutting force (FR) and surface roughness (Ra) when hard turning high chrome cast iron with a cubic boron nitride (CBN) insert. The effect levels of machining parameters on FR and Ra were examined by an analysis of variance (ANOVA). A grey relational grade (GRG) was calculated to simultaneously minimize FR and Ra. The ANOVA results based on GRG indicated that the feed rate, followed by the cutting depth, was the main parameter and contributed to responses. Optimal levels of parameters were found when the chrome ratio, cutting speed, feed rate, and cutting depth were 12%, 100 m/min, 0.05 mm/r, and 0.1 mm, respectively, based on the multiresponse optimization results obtained by considering the maximum signal to noise (S/N) ratio of GRG. Confirmation results were verified by calculating the confidence level within the interval width.The full text can be downloaded at https://link.springer.com/article/10.1007/s40436-018-0231-z 相似文献
96.
Small scale wind turbines installed within the built environment is classified as micro generation technology. This paper reports the investigation results of wind power application in buildings. First, general information is given for common type of wind turbines are used on buildings. Second, the wind aerodynamics and wind flows over the buildings are investigated based on local meteorological data and local building characteristics. However, to receive the highest potential wind energy resource and avoid turbulent areas, the tool of Computational Fluid Dynamics (CFD) has to be used to model the annual wind flows over buildings to help analyze, locate, and design wind turbines on and around buildings. Three different sample models for buildings and rural residential areas are explained with CFD models. 相似文献
97.
In this study, the case properties and diffusion kinetics of AISI 440C and AISI 52100 steels borided in Ekabor-II powder were investigated by conducting a series of experiments at temperatures of 1123, 1173 and 1223 K for 2, 4 and 8 h.The boride layer was characterized by optical microscopy, X-ray diffraction technique and micro-Vickers hardness tester. X-ray diffraction analysis of boride layers on the surface of the steels revealed the existence of FeB, Fe2B and CrB compounds.The thickness of boride layer increases by increasing boriding time and temperature for all steels. The hardness of the boride compounds formed on the surface of steels AISI 52100 and AISI 440C ranged from 1530 to 2170 HV0.05 and 1620 to 1989 HV0.05, respectively whereas Vickers hardness values of untreated steels AISI 440C and AISI 52100 were 400 HV0.05 and 311 HV0.05, respectively. The activation energies (Q) of borided steels were 340.426 kJ/mol for AISI 440C and 269.638 kJ/mol for AISI 52100. The growth kinetics of the boride layers forming on the AISI 440C and AISI 52100 steels and thickness of boride layers were also investigated. 相似文献
98.
Poly(hydroxyethyl methacrylate) based magnetic nanoparticles for plasmid DNA purification from Escherichia coli lysate 总被引:1,自引:0,他引:1
Işık Perçin Veyis Karakoç Sinan Akgöl Erol Aksöz Adil Denizli 《Materials science & engineering. C, Materials for biological applications》2012,32(5):1133-1140
The aim of this study is to prepare poly(hydroxyethyl methacrylate-N-methacryloyl-(L)-histidine) [PHEMAH] magnetic nanoparticles for plasmid DNA (pDNA) purification from Escherichia coli (E. coli) cell lysate. Magnetic nanoparticles were produced by surfactant free emulsion polymerization. mPHEMAH nanoparticles were characterized by elemental analysis, Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM), vibrating sample magnetometer (VSM), electron spin resonance (ESR), thermogravimetric analyses (TGA) and transmission electron microscopy (TEM). Surface area, average particle size and size distribution were also performed. Specific surface area of the mPHEMAH nanoparticles was found to be 1180 m2/g. Elemental analysis of MAH for nitrogen was estimated as 0.18 mmol/g polymer. The amount of pDNA adsorbed onto the mPHEMAH nanoparticles first increased and then reached a saturation value at around 1.0 mg/mL of pDNA concentration. Compared with the mPHEMA nanoparticles (50 μg/g polymer), the pDNA adsorption capacity of the mPHEMAH nanoparticles (154 mg/g polymer) was improved significantly due to the MAH incorporation into the polymeric matrix. The maximum pDNA adsorption was achieved at 25 °C. The overall recovery of pDNA was calculated as 92%. The mPHEMAH nanoparticles could be used six times without decreasing the pDNA adsorption capacity significantly. The results indicate that the PHEMAH nanoparticles promise high selectivity for pDNA. 相似文献
99.
模块化多电平换流器(Modular Multilevel Converter,MMC)作为一种新型的电压源换流器,被广泛应用于直流输电领域.电容的电压平衡问题在MMC中非常重要,随着MMC子模块个数的增多,电容电压的平衡变得越来越困难.本文提出了一种基于BP-PID的双闭环控制策略,通过控制调制波来控制子模块的工作状态... 相似文献
100.