Studies on the Autoxidation of Phenylacetylene

Phenylacetylene is oxidized slowly by molecular oxygen at 110°C. The main oxidation products are benzoic acid, benzoic anhydride, and benzaldehyde. Besides the oxidation, thermal dimerization, oligomerization, and polymerization processes also take place. As individual products 1,4-diphenylbut-1-yn-3-ene and 1,3,5-triphenylbenzene were identified. About 80% of the phenylacetylene consumed are converted into products of low volatility which could not be detected by gas chromatography. The autoxidation of acetylenic hydrocarbones [1] preferably yields products of the attack at C H bonds in α-position to the CC triple bond. An attack at the CC riple bond was a first proved in the case of phenylacetylene, which besides polymeric products yielded benzaldehyde, acetophenone, and organic acids [2]. Later, in the causes of the isomeric octynes [3] and of various 1-Phenylalk-1-ynes [4] an attack at the CC triple bond was also proved. As the primary products of the oxidative attack at the CC triple bond short-lived oxirenes or their valence isomers, the corresponding ketocarbenes are to be expected. Indeed, their rearrangement products were found in the oxidation mixtures of both the isomeric ocytnes [3] and the 1-phenylalk-1-ynes [4]. Other products of the oxidative attack at the CC triple bond are lower carboxylic acids, formally produced by oxidative cleavage of the CC triple bond [3, 4].     

Diurnal and seasonal variabilities in surface ozone and its precursor gases at a semi‐arid site Anantapur (14.62°N, 77.65°E, 331 m asl) in India

Measurements of surface ozone and its precursor gases (NO_x and CO) have been made at a semi‐arid site Anantapur (14.62°N, 77.65°E, 331 m asl) in tropical Indian region for the period, 2001–2003. NO_x and CO levels were the highest during morning and late night hours at this site. Diurnal variations of ozone concentrations varied from 25 ppbv to 50 ppbv and were observed to increase gradually after sunrise, attaining a maximum value by the evening and decreasing gradually thereafter. During monsoon months, the diurnal amplitude of ozone was found to be small (20–25 ppbv). Seasonal variation in ozone showed a pronounced maximum (40–50 ppbv) in the winter and summer. Local pollutants were major contributors to the ozone levels during this period. Ozone shows a yearly mean mixing ratio of about 35.9 ± 8.8 ppbv. The daytime concentration of CO and NO_x varied between 200 to 1200 ppbv and 3 to 20 ppbv respectively for the period studied. Annual average mixing ratios of oxides of nitrogen (NO_x) and CO were observed to be 3.9±0.6 ppbv and 436±64 ppbv, respectively.     

Electrical properties and the role of inhomogeneities at the polyvinyl alcohol/n‐inp schottky barrier interface

In this work, we have investigated the electrical properties of Au/n‐InP contacts with a thin layer of polyvinyl alcohol (PVA) as an interlayer. The current–voltage (I–V) and capacitance–voltage (C–V) measurements are carried out in the temperature range of 175–425 K. The Au/PVA/n‐InP Schottky structure show nonideal behaviors and indicates the presence of a nonuniform distribution of interface states. The temperature dependent interface states densities (N_SS), ideality factor and barrier height are obtained. An abnormal decrease in zero‐bias barrier height (BH) and increase in the ideality factor ( ) with decreasing temperature have been explained on the basis of the thermionic emission theory with Gaussian distribution (GD) of the BHs due to the BH inhomogeneities. The experimental I–V characteristics of Au/PVA/n‐InP Schottky diode has revealed the existence of a double GD with mean BH values of ( ) of 1.246 and 0.899 eV and standard deviation ( ) of 0.176 and 0.137 V, respectively. Consequently, the modified conventional activation energy versus plot gives and Richardson constants ( ) and the values are 1.17 and 0.71 eV and 9.9 and 6.9 A/cm² K², respectively, without using the temperature coefficient of the BH. The effective Richardson constant value of 9.9 A/cm² K² is very close to the theoretical value of 9.4 A/cm² K² for n‐InP. The discrepancy between Schottky barrier heights estimated from I–V and C–V measurements is also discussed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39773.     

Epoxy curing by polyaniline (PANI) – Characterization and self-healing evaluation

Polyaniline (PANI) was synthesized by chemical oxidative polymerization of aniline dissolved in aqueous phosphoric acid. The polymer was characterized by UV–Visible spectroscopy (UV–Vis), thermal gravimetric analysis (TGA) and Fourier transform infrared spectroscopic (FTIR) techniques. Hardener free epoxy coating was formulated with 10% PANI. The curing process of epoxy resin by PANI was analyzed using FTIR and a suitable mechanism of curing was suggested. The corrosion protective performance of conventional polyamide cured epoxy and PANI cured epoxy coating on steel has been assessed in 3% NaCl by electrochemical impedance spectroscopy (EIS). The self-healing property of the PANI cured epoxy coating on steel in 3% NaCl was studied by scanning vibrating electrode technique (SVET).     

Cascode Monolithic DC-DC Converter for Reliable Operation at High Input Voltages

A CMOS OTA-C low-pass notch filter for EEG application is described. The pass-band covers four bands of brain wave and provides more than 65 dB attenuation for the 50 Hz power line interference. The OTA works in the weak inversion region and a low transconductance of 3 nA/V is achieved. The low transconductance enables using small capacitors in the OTA-C filter so that the filter is suitable for the multi-channel EEG integrated circuits. The measured results show the good performance of the filter for filtering the noise in acquired EEG signals. Xinbo Qian received the B.Sc. degree from Beijing Institute of Technology, P.R. China, in 1991 and M.Sc. degree from Institute of Physics, Chinese Academy of Sciences, in 1996. From 1996 to 1999, she was a research engineer in the Institute of Acoustics, Chinese Academy of Sciences, worked on the sonar signal receiving and processing systems. Since 1999, she has been pursuing the Ph.D. degree in Electrical and Computer Engineering department, National University of Singapore, with research direction on on-chip readout circuits for microbolometer focal plane arrays. Now she is employed by Department of Mechanical Engineering and Division of Bioengineering, National University of Singapore as a research fellow. Her research interest is low-noise integrated circuits design and bio-medical sensor electronics, including electroencephalography IC, magnetocardiography IC, low-noise amplifier, filter and data converters etc. Yong Ping Xu graduated from Nanjing University, P.R. China in 1977. He received his Ph.D. from University of New South Wales (UNSW) Australia, in 1994. From 1978 to 1987, he was with Qingdao Semiconductor Research Institute, P.R. China, initially as an IC design engineer, and later the deputy R&D manager and the Director. From 1989 to 1992, he was working on silicon diode based infrared detectors towards his Ph.D. at School of Electrical Engineering, UNSW Australia. From 1993 to 1995, he worked on an industry collaboration project with GEC Marconi, Sydney, Australia, at the same university, involved in design of sigma-delta ADCs. He was a lecturer at University of South Australia, Adelaide, Australia from 1996 to 1998. He has been with the Department of Electrical and Computer Engineering, National University of Singapore since June 1998 and is now an Associate Professor. His general research interests are in the areas of mixed-signal and RF integrated circuits, and integrated MEMS and sensing systems. His current focuses are high-speed wideband ADC, UWB front-end circuits and low-power low-voltage integrated circuits for biomedical applications. He is a Senior Member of IEEE. Xiaoping Li received his Ph.D. degree from Department of Mechanical and Manufacturing Engineering, University of New South Wales, Australia in 1991, and joined the National University of Singapore in 1992, where he is currently an Associate Professor with the Department of Mechanical Engineering and Division of Bioengineering. He was a visiting professor of Tokyo Institute of Technology, Japan in 2000, and visiting professor of Georgia Institute of Technology, USA in 2001. He is a member of American Society of Mechanical Engineers (ASME), a senior member of Society of Manufacturing Engineering (SME) and a senior member of North American Manufacturing Research Institute/SME, and is currently the Chairman of SME Singapore Chapter. His current research interests include neurosensors and nanomachining. He is a guest editor of International Journal of Computer Applications in Technology, USA. He is a regular reviewer of the ASME Journal of Manufacturing Engineering, USA, Transactions of NAMRI/SME, USA, Journal of materials processing technology, UK, International Journal of Machine Tools and Manufacture, UK, and IMechE Journal of Engineering Manufacture, UK.     

Multi-objective optimization for optimum tolerance synthesis with process and machine selection using a genetic algorithm

This paper presents a new approach to the tolerance synthesis of the component parts of assemblies by simultaneously optimizing three manufacturing parameters: manufacturing cost, including tolerance cost and quality loss cost; machining time; and machine overhead/idle time cost. A methodology has been developed using the genetic algorithm technique to solve this multi-objective optimization problem. The effectiveness of the proposed methodology has been demonstrated by solving a wheel mounting assembly problem consisting of five components, two subassemblies, two critical dimensions, two functional tolerances, and eight operations. Significant cost saving can be achieved by employing this methodology.     

Influence of in situ formed ZrB2 particles on microstructure and mechanical properties of AA6061 metal matrix composites

Particulate reinforced metal matrix composites (PMMCs) have gained considerable amount of research emphasis and attention in the present era. Research is being carried out across the globe to produce new combination of PMMCs. PMMCs are prepared by adding a variety of ceramic particles with monolithic alloys using several techniques. An attempt has been made to produce aluminium metal matrix composites reinforced with zirconium boride (ZrB₂) particles by the in situ reaction of K₂ZrF₆ and KBF₄ salts with molten aluminium. The influence of in situ formed ZrB₂ particles on the microstructure and mechanical properties of AA6061 alloy was studied in this work. The in situ formed ZrB₂ particles significantly refined the microstructure and enhanced the mechanical properties of AA6061 alloy. The weight percentage of ZrB₂ was varied from 0 to 10 in steps of 2.5. Improvement of hardness, ultimate tensile strength and wear resistance of AA6061 alloy was observed with the increase in ZrB₂ content.     

THERMAL MANAGEMENT OF HIGH TEMPERATURE PULSED ELECTRONICS USING METALLIC PHASE CHANGE MATERIALS

A feasibility study for using metallic solid-liquid phase change materials (PCMs) in periodic power dissipating devices is reported. Thermal enhancement has been studied with PCM enclosed inside microchannels within semiconductor devices. Benchmarking experiments were performed with PCM inside copper microchannels and compared with numerical predictions. PCMs perform well at lower power levels for silicon carbide semiconductor devices, but the use of high thermal conductivity spreaders such as diamond becomes mandatory at the higher power levels projected in future applications. PCM effectiveness and temperature reductions as a function of chip thickness, channel width, and power dissipated are presented. Temperature reductions up to 25°C can be realized with a combination of diamond spreaders and PCM filled microchannels.     

Intelligent agents in electronic markets for information goods: customization, preference revelation and pricing

Electronic commerce has enabled the use of intelligent agent technologies that can evaluate buyers, customize products, and price in real-time. Our model of an electronic market with customizable products analyzes the pricing, profitability and welfare implications of agent-based technologies that price dynamically based on product preference information revealed by consumers. We find that in making the trade-off between better prices and better customization, consumers invariably choose less-than-ideal products. Furthermore, this trade-off has a higher impact on buyers on the higher end of the market and causes a transfer of consumer surplus towards buyers with a lower willingness to pay. As buyers adjust their product choices in response to better demand agent technologies, seller revenues decrease since the gains from better buyer information are dominated by the lowering of the total value created from the transactions. We study the strategic and welfare implications of these findings, and discuss managerial and technology development guidelines.     

Effect of depth on onset of engulfment in rectangular micro-channels

The mixing behavior at different Reynolds numbers is analyzed for different T-shaped micro-channels with a rectangular cross-section. The focus is on analyzing the effect of aspect ratio on the critical Reynolds number at which engulfment occurs. Soleymani et al. (2008) have recently proposed an empirical equation based on extensive numerical simulations to determine this critical Reynolds number. This is valid only when the depth of the channels (C) is lower than the widths of the mixing (A) and inlet (B) channels i.e. when A/C and B/C are both greater than unity. We find that when they are both less than unity there is a delay or even absence of engulfment even when Re is increased. The predictions of these simulations are validated experimentally for two geometries.