Multi-mode hydrogen storage in nanocontainers

Hydrogen can be stored in containers or in materials (in molecular or atomic forms). The atomic form can further exist as multiple phases. Molecular hydrogen can be adsorbed on the surface or can be present inside the material. By invoking multiple modes of hydrogen storage, we establish a paradigm shift in the philosophy of hydrogen storage. Using a novel strategy of storage of molecular hydrogen in metal (Pd) nanocontainers, we observe that 18% hydrogen is in molecular form. Interestingly, this is achieved at 25 °C and 1 atm pressure; which is in contrast to storage in MOFs and carbonaceous materials like nanotubes. Enhancement in storage capacity as compared to Pd nanocrystals of the same mass is observed (36% increase at 1 atm & 25 °C), along with fast kinetics (0.5 wt% hydrogen absorption in 5 s). A new mechanism for hydrogen storage involving the dual catalytic role of Pd is established.     

Galactose concentration in pizza cheese prepared by three different culture techniques

A study was conducted to determine the most suitable lactic culture combinations and the techniques for the preparation of low moisture part skim (LMPS) mozzarella cheese (pizza cheese) with a low level of galactose. The cheesemaking time tested for all 12 culture combinations was less than 3 h and hence was found suitable for pizza cheesemaking. The initial accumulated galactose concentration was lower in unstretched curd followed by no-brine curd and stretched curd in ascending order. During storage of the cheese for 7 days, the galactose percentage in the cheeses prepared using cultures comprising galactose-fermenting strains of Lactobacillus helveticus and Streptococcus thermophilus was 0.30 in stretched curd, 0.04 in unstretched curd and 0.03 in no-brine curd. The degree of reduction in the level of galactose in pizza cheese during storage was maximum with the no-brine curd technique followed by the unstretched and stretched curd techniques in that order. This study provides information regarding selection of starter culture combinations and techniques for pizza cheesemaking based on consumer preference for low or moderate browning mozzarella cheese as a result of its galactose concentration.     

Shelf life extension of fresh fruit and vegetables by chitosan treatment

Among alternatives that are currently under investigation to replace the use of synthetic fungicides to control postharvest diseases in fresh produce and to extend their shelf life, chitosan application has shown promising disease control, at both preharvest and postharvest stages. Chitosan shows a dual mode of action, on the pathogen and on the plant, as it reduces the growth of decay-causing fungi and foodborne pathogens and induces resistance responses in the host tissues. Chitosan coating forms a semipermeable film on the surface of fruit and vegetables, thereby delaying the rate of respiration, decreasing weight loss, maintaining the overall quality, and prolonging the shelf life. Moreover, the coating can provide a substrate for incorporation of other functional food additives, such as minerals, vitamins, or other drugs or nutraceutical compounds that can be used to enhance the beneficial properties of fresh commodities, or in some cases the antimicrobial activity of chitosan. Chitosan coating has been approved as GRAS substance by USFDA, and its application is safe for the consumer and the environment. This review summarizes the most relevant and recent knowledge in the application of chitosan in postharvest disease control and maintenance of overall fruit and vegetable quality during postharvest storage.     

Analysis of machining of FRPs using FEM

An initial attempt has been made to develop a mathematical model for machining of FRPs. The anisotropic theory of plasticity has been utilized. The analysis is carried out for four different FRP materials and for four different fibre orientation angles. A total Lagrangian formulation-based transient elasto-plastic finite element analysis has been adopted.     

Planning and management of shared waters: hydropolitics and hydropsychology – two sides of the same coin

Politics and human behaviour play key roles in the planning and management of shared water resources. The interactions between politics and water resources (hydropolitics) have been extensively studied, and the need to study the interactions between human behaviour and water-related activities (hydropsychology) is increasingly recognized. Although both hydropolitics and hydropsychology are useful, neither by itself is adequate across all scales of water resources and human society. This paper reasons that hydropolitics is a top-down view and hydropsychology is bottom-up, and argues for a framework to reconcile the two for a two-way and more balanced approach.     

Novel 1,3,4-oxadiazole derivatives as efficient sensitizers for dye-sensitized solar cells: A combined experimental and computational study

We have synthesized and characterized donor–π–spacer–acceptor type molecules in which 1,3,4-oxadiazoles are π-spacers, triphenylamines are the donors and cyanoacetic acid are the acceptors for use as sensitizers in dye-sensitized solar cells (DSSCs). Detailed absorption, emission, electrochemical, photoelectrochemical and computational studies have been carried out on five novel derivatives. The dyes have an absorption range of 377–388 nm, and an emission in the range of 494–540 nm. There is a large charge transfer from the donor side to the acceptor side on excitation. The propeller shape of the triphenylamine and the bulky substituents on it help in reducing the dye-aggregation on TiO₂ surface. The dyes exhibited good overall conversion efficiency (2.79–3.21%). Plane wave calculations indicate that the dye has a reasonably strong binding to the TiO₂ surface and the generated DOS picture shows an overlap of the molecular orbitals of the dye and the TiO₂ bands. We conclude that the dyes have a promising role as sensitizers in DSSC.     

Close-range blast loading on empty recyclable metal beverage cans for use in sacrificial cladding structure

This article deals with the experimental and numerical blast study on a single empty recyclable metal beverage can. The idea is to make a macro-foam (sacrificial cladding structure) out of these cans to protect the main load bearing members of civil engineering structures from the air blast load. Close-range free air blast tests have been conducted to understand the crushing behaviour and the energy absorption of a single empty beverage can in detail. To conduct such an air blast test a special small-scale test set-up was designed and manufactured. The effect of skin plate surface area and its nature on the blast parameters is studied. Furthermore, the effect of inertia of the skin plate on the crushing performance of the beverage can is evaluated. Tests have been conducted with different plates (made of aluminium and sandwich composite materials) with different masses which represent the skin plate of the proposed sacrificial structure. The measured blast parameters from the experimental tests were compared with ConWep predicted data. Furthermore, the influence of the finite surface area of the skin plate on the clearing of the reflected pressure waves was also studied. The deformation behaviour and the corresponding energy absorption of empty beverage cans were captured. During the experimental blast tests it was observed that a part of the total reflected impulse (∼30%) was lost before it transfers to the non-sacrificial structure. Hence, in order to investigate this phenomenon Eulerian-Lagrangian coupled analyses were conducted using Hydrocodes. The results from these analyses showed that the diffraction and ground reflected pressure wave caused the loss in impulse. The results from the numerical studies have been compared and validated with the experimental results.     

Algorithms for the design of a multi-stage adaptive kanban system

The traditional kanban system with a fixed number of cards does not work satisfactorily in an unstable environment. With the adaptive kanban-type pull control mechanism, the number of kanbans is allowed to change with respect to the inventory and backorder level. It is required to set the threshold values at which cards are added or deleted, which is part of the design. Previous studies used local search and meta-heuristic methods to design an adaptive kanban system for a single stage. In a multi-stage system the cards are circulated within the stage and their presence at designated positions signals to the neighbouring stages details concerning the inventory. In this work, a model of a multi-stage system adapted from a traditional and adaptive kanban system is developed. A genetic and simulated annealing algorithm based search is employed to set the parameters of the system. The results are compared with a traditional kanban system and signs of improvement are found. The numerical results also indicate that the use of a simulated annealing algorithm produces a better solution.     

Analysis and Design of Vibration Isolation System Using Open Trenches

Field vibration tests were carried out at a proposed site for the vibration testing room, and 2D numerical analysis using finite difference tool FLAC 5.0 was performed to suggest effective vibration isolation systems. In the analysis, the numerical model is first calibrated with respect to material properties, damping value, and boundary conditions to obtain the output comparable to the field test results. The calibrated model was further used to perform a parametric study by (1)?providing vibrating input motions from vibrating machines to be operated; (2)?using two depths of cutoff trench; and (3)?providing gravel bed, gravel bed with rubber pad, and gravel bed with rubber pad and cutoff trench to study the isolation effects. Comparing the results from the parametric studies with the human perception level of vibration, a decision on the isolation system was determined.