Palladium‐nanoparticle intercalated vermiculite for selective hydrogenation of α,β‐unsaturated aldehydes

Palladium nanoparticles were generated in the interlamellar region of swelling 2:1 type vermiculite clay using an adsorption excess isotherm. An adsorption excess isotherm was constructed for vermiculite after exchanging the exchangeable Na⁺ ions in the interlamellar region using a binary liquid mixture (ethanol:toluene). Based on adsorption excess isotherm, 1% w/w palladium was intercalated into the interlamellar space of vermiculite. The Pd‐intercalated vermiculite was characterized by X‐ray diffraction, transmission electron microscopy and atomic absorption spectroscopy. The 1% w/w Pd‐intercalated vermiculite was tested for its catalytic activity towards selective hydrogenation reactions involving some α,β‐unsaturated carbonyl compounds using a pulse reactor and its catalytic activity was compared with commercial 1% Pd/C. The intercalated catalyst was found to be very selective towards the desired product of unsaturated alcohols. Copyright © 2007 Society of Chemical Industry     

Role of transformed martensite in the cracking of stainless steel plumbing lines

Austenitic stainless steel AISI 321 is used to fabricate plumbing lines to transfer cryogens from storage to output collector of propulsion system. Cracks were found in some of such tubes during one of the qualification tests of pipelines. The crack occurred at the bent region of the fuel feed pipeline along its neutral axis. Detailed metallographic investigations revealed presence of numerous longitudinal fine cracks on the inner surface of the tube that resulted from improper extrusion of the tube. Further, deformation induced martensitic transformation occurred, as the tube was bent at liquid nitrogen temperature. The transformed martensite, in presence of fine cracks on inner surface of the tube, due to improper extrusion, resulted in crack opening. This paper highlights the details of investigations carried out.     

Crystallography of solid–liquid interface and evolution of texture during directional solidification of Tb0.3Dy0.7Fe1.95 alloy

The effect of growth texture on the magnetostriction of ternary Tb_0.3Dy_0.7Fe_1.95 was studied by conducting unidirectional solidification experiments using a zoning set-up. Detailed texture evolutions were studied using X-ray diffraction on samples obtained by varying growth rates from 18 to 72 cm/h, under a temperature gradient of 100 °C/cm. The estimated texture co-efficient and pole figures of the samples indicate that during the onset of the solidification, <110> and <331>/‘rotated <110>’ texture components nucleate and grow in all the samples. However, as the solidification progresses, <112> texture component becomes dominant at higher growth rate. This results in an improvement of magnetostriction from 1000 to 1300 microstrains for samples grown at growth rates of 18 and 72 cm/h respectively. The transition of preferred growth direction occurs through intermediate orientations <123>. An attempt has been made in this paper to explain the occurrence of different growth texture by considering the stability of growing interface, its planar packing fraction and atomic stacking sequence of several low index planes.     

Bio-diesel production by alkali catalyzed transesterification of dairy waste scum

The potential of using dairy waste scum as a feed stock for bio-diesel production was investigated. Present study optimized the parameters involved in transesterification process of Dairy Waste Scum Oil. Gas chromatography was used to determine the fatty acid composition of Dairy Waste Scum Oil. Results revealed that the low free fatty acid content was a notorious parameter to determine the viability of alkaline transesterification. The yield of bio-diesel reached 96.7% when 1.2 wt.% of Potassium Hydroxide, reaction temperature of 75 °C, 30 min of time and 6:1 Methanol oil ratio at 350 rpm. Thermo gravimetric analysis followed the evaluation of transesterification process. The present analysis confirms that bio-diesel from dairy waste scum is quit suitable as an alternative to petroleum diesel with recommended fuel properties as per ASTM standards. This new way for using dairy waste scum reduces the cost of production of bio-diesel and the problem related to the disposal of Dairy scum.     

A Novel Narrow Band Red-Emitting Phosphor for White Light Emitting Diodes

Research on down conversion phosphor materials is the key for the development of solid-state lighting (SSL). Especially finding alternative red phosphor for white light emitting diodes (LEDs) based on blue or near ultraviolet (NUV) LEDs is important research task. In this view, we have synthesized a series of Eu³⁺-substituted La₂W_{2− x} Mo _x O₉ ( x =0–2, in step of 0.3) red phosphor and characterized by X-ray diffraction (XRD) and photoluminescence. XRD results reveal a phase transition from triclinic to cubic structure for x >0.2. All the compositions show broad charge transfer (CT) band due to CT from oxygen to tungsten/molybdenum and red emission due to Eu³⁺ ions. Select compositions show high red emission intensity compared with the commercial red phosphor under NUV/blue ray excitation. Hence, this candidate can be a possible red phosphor for white LEDs.     

Manufacturing cell formation with production data using neural networks

Batch type production strategies need adoption of cellular manufacturing (CM) in order to improve operational effectiveness by reducing manufacturing lead time and costs related to inventory and material handling. CM necessitates that parts are to be grouped into part families based on their similarities in manufacturing and design attributes. Then, machines are allocated into machine cells to produce the identified part families so that productivity and flexibility of the system can be improved. Zero-one part-machine incidence matrix (PMIM) generated from route sheet information is commonly presented as input for clustering of parts and machines. An entry of ‘1’ in PMIM indicates that the part is visiting the machine and zero otherwise. The output is generated in the form of block diagonal structure where each block represents a machine cell having more than one machines and a part family. The major limitations of this approach lies in the fact that important production factors like operation time, sequence of operations, and lot size of the parts are not accounted for. In this paper, an attempt has been made to propose a clustering methodology based on adaptive resonance theory (ART) for addressing these issues. Initially, a methodology considering only the operation sequence of the parts has been proposed. Then, the methodology is suitably modified to deal with combination of operation sequence and operation time of the parts to address generalized cell formation (CF) problem. A new performance measure is proposed to quantify the performance of the proposed methodology. The performance of the proposed algorithm is tested with benchmark problems from open literature and the results are compared with the existing methods. The results clearly indicate that the proposed methodology outperforms the existing methods in most cases.     

Lactic acid fermentation of anthocyanin-rich sweet potato (Ipomoea batatas L.) into lacto-juice

Sweet potato (SP) is an important root crop grown all over the world and consumed as a vegetable, boiled, baked or often fermented into food and beverages. The grated SP roots [non- boiled and fully boiled (boiled in water at 100 °C for 15 min) were treated with 0.05% of commercial pectinase enzyme (Pectinex, Novoenzyme) in order to extract the juice. The fresh juice was inoculated with Lactobacillus plantarum MTCC 1407 culture at 28 ± 2 °C for 48 h to produce lacto-juice (LJ). The anova analysis of analytical data revealed that there was significant effect of boiling conditions (fully boiled and non-boiled) on pH [ F (1, 4) = 220.5, P  < 0.001), TA [ F (1, 4) = 78.89, P  < 0.01], starch [ F (1, 4) = 26.63, P  < 0.01), total sugar [ F (1, 4) = 61.36, P  < 0.01) and anthocyanin [ F (1, 4) = 32.86, P  < 0.01) but not on reducing sugar [ F (1, 4) = 2.48, P  = 0.19). Sensory evaluation rated the SP LJ acceptable based on texture, taste, aroma, flavour and after taste. LJ prepared from fully boiled roots with 10% cane sugar was most preferred by a consumer's panelist based on Linear Discriminant Analysis. Principal component analyses (PCA) reduced the seven original analytical variables to three independent components (factors), which accounted for 99.9% of the total variations. Similarly, six original sensory variables were reduced to two independent components, which accounted for 65.7% of the total variations.     

Vitamin A requirements assessed by plasma response to supplementation during pregnancy

The intestinal parasitic helminth infections of man in Bonny and Isiokpo communities were studied between May 1992 and March 1994. Of the 2008 stool samples examined from Bonny community, 503 (25.0%) were infected. 305 (26.7%) of these infections were males while 198 (22.9%) were females. Ascaris lumbricoides (24.1%) occurred most frequently, followed by Hookworms (18.0%), Trichuris trichiura (17.3%,) Strongyloides stercoralis (10.1%) and Enterobius vermicularis (0.1%). Peak infection (41.7%) was recorded for the males in (10-14) years age bracket. The use of bush as a toilet facility had the highest parasitic infection (38.3%), followed by that of shoreline (35.3%), pit (33.3%), Bucket (27.8%) and of water closet (7.5%). Degree of infection relative to source of drinking water showed that well water was associated with highest infection (43.3%) while the pipe borne water was the lowest (18.0%). From Isiokpo community 2,462 stool samples were examined for intestinal parasites 1,633 (66.3%) people were infected consisting of 862 (64.8%) males and 771 (68.2%) females. Higher parasitic infection of females in this community was attributed to the cultural and occupational factors. Frequency of occurrence of individual helminth was as follows: A-lumbricoides (64.5%), T. trichiura (59.4%), Hookworms (58.8%), S. stercoralis (25.1%), Hymenolepsis nana (2.9%) and E. vermicularis (0.3%). Prevalence of infection was significantly higher in Isiokpo than in Bonny because the climatic and edaphic factors were conducive to larval development and infectivity. On the contrary, the saline soil and surface water of Bonny community constituted harsh environmental conditions inimical to larval development and infectivity. Observations on parasitic infections in relation to toilet facilities and source of drinking water were similar to those made in Bonny. The study therefore demonstrated that the provision of pipe borne water and water closet facilities in rural Niger Delta communities could reduce helminth infections of man.