Influence of cerium oxide additive and aloe vera biodiesel on a CI engine

Diesel is the main source of world transportation due to higher combustion efficiency, compliance, consistency and cost-economy. It is also a major contributor to the world prosperity since it is used extensively. Diesel engine’s emissions are the serious hazard to the world environment and it is measured to be the major causes of air pollution. The demand in biofuels for years created a scope for aloe vera into biodiesels. Aloe vera, having higher calorific value vnthan other plant sources used as biodiesels, enhanced us in making another alternative biodiesel, which has lesser emissions and better performance. In this research work, four biodiesel blends from aloe vera oil with cerium oxide additive are explored for their performance and emission characteristics. The results proved B30 (30% biodiesel, 68% diesel and 1% cerium oxide) gives good performance when compared to other blends.     

Matching housing supply and demand: an empirical study of Hong Kong's market

This paper has the objective of improving on the issue of forecasting new housing construction, and highlights differences between space demand and investment demand in housing markets. Further, it indicates how these differences will affect construction decisions. The first step is to identify the factors associated with estimating residential property prices in Hong Kong, based on a demand-supply adjustment process. Specifically, this study examines the role of population growth, transaction volume, inflation and interest rate in determining house prices. Second, based on these estimations, a methodology is developed to estimate the investment demand schedule and new construction of residential property.     

Lowering the outdoor temperature in high-rise high-density residential developments of coastal Hong Kong: The vegetation influence

This paper investigates the impact of on-site variables on the influence of vegetation in lowering outdoor temperature. The study uses six critical on-site variables such as surface albedo, sky view factor, altitude, shrub cover, tree cover and average height to floor area ratio to carry out analysis in five data sets. The climatic parameters and physical characteristics were measured and surveyed, respectively in 216 stations in high-rise high-density residential developments of coastal Hong Kong. The data set is mainly categorised into peak summer clear sky days (PSCS-days), peak summer partially cloudy days (PSPC-days) and late summer days to address the issues related to cloudy sky conditions in Hong Kong. The trend analysis shows that at a lower sky view factor, ranging from 0.1 to 0.25, shrub cover as low as 10–15% in a 1000 m² open area is more effective in reducing outdoor temperature than the same level of tree cover in a location with a higher sky view factor (0.4 or above). The regression models used in this study were able to explain the influence of on-site variables on vegetation in lowering the outdoor temperature within the respective urban settings. In high-rise high-density environments, on-site variables such as sky view factor and altitude have a substantial impact on the influence of vegetation in lowering outdoor temperature. However, off-site variables such as high urban density and anthropogenic heat could negate the behaviour of sky view factor and altitude. The study suggests that increasing the tree cover from 25% to 40% in the pocket parks in coastal area residential developments of Hong Kong could reduce daytime urban heat island intensity (UHI) by further 0.5 °C.     

Microstructural study of iron nitride thin films deposited by ion beam sputtering

An amorphous iron nitride thin film was deposited using reactive ion beam sputtering of iron by a beam of argon and nitrogen ions. Nitrogen content in the film as determined from conversion electron Mössbauer spectroscopy (CEMS) and X-ray photoelectron spectroscopy (XPS) was FeN_0.7. The mass density of the film was calculated using energy-dispersive X-ray reflectivity (EDXRR) measurements and is found to be 6.0 gm/cm³. CEMS shows that the film is nonmagnetic in nature. Morphology of the film is obtained from atomic force microscopy (AFM). The surface roughness of the film does not increase appreciably beyond that of the substrate even after a deposition of 131 nm of material with these qualities the film is a good candidate for the multilayer superstructure of a nuclear Bragg monochromator of the type ⁵⁶FeN_0.7/⁵⁷FeN_0.7.     

Manganese–Schiff base complex immobilized silica materials for electrocatalytic oxygen reduction

Curtailment of platinum catalysts loading in fuel cell is a recent central issue. As substitutes, these days several organic metal chelate compounds having featured moieties of M–N₄ or M–N₂O₂ (M = transition metal ion) are being used as cathode catalysts in fuel cells. Here, in this study, we report in detail the electrocatalytic activity of manganese–Schiff base complexes for oxygen reduction reaction in 0·05 M HClO₄ at room temperature. Actually, [Mn(salen)]⁺: [N,N′-bis(salicylaldehyde) ethylenediimino manganese(III)]⁺ and [Mn(salophen)]⁺: [N,N′-bis(salicylaldehyde)-1,2-phenylenediimino manganese(III)]⁺ were introduced into/onto the MCM-41 type silica spheres and used for the electrocatalytic reduction of oxygen. Synthesized materials were characterized by UV–Vis, FT–IR and electrochemical techniques. Significant low overpotential for oxygen reduction in 0·05 M HClO₄ on [Mn(salen)]⁺- and [Mn(salophen)]⁺-incorporated silica-modified glassy carbon electrodes was observed.     

Dielectric properties of DC reactive magnetron sputtered Al2O3 thin films

Alumina (Al₂O₃) thin films were sputter deposited over well-cleaned glass and Si < 100 > substrates by DC reactive magnetron sputtering under various oxygen gas pressures and sputtering powers. The composition of the films was analyzed by X-ray photoelectron spectroscopy and an optimal O/Al atomic ratio of 1.59 was obtained at a reactive gas pressure of 0.03 Pa and sputtering power of 70 W. X-ray diffraction results revealed that the films were amorphous until 550 °C. The surface morphology of the films was studied using scanning electron microscopy and the as-deposited films were found to be smooth. The topography of the as-deposited and annealed films was analyzed by atomic force microscopy and a progressive increase in the rms roughness of the films from 3.2 nm to 4.53 nm was also observed with increase in the annealing temperature. Al-Al₂O₃-Al thin film capacitors were then fabricated on glass substrates to study the effect of temperature and frequency on the dielectric property of the films. Temperature coefficient of capacitance, AC conductivity and activation energy were determined and the results are discussed.     

High temperature tensile properties of 316LN stainless steel investigated using automated ball indentation technique

Type 316LN stainless steel (SS) is the principal structural material for the components of sodium cooled fast reactors operating under elevated temperature conditions. In order to assess the degradation in strength of service exposed components using a small specimen testing technique such as automated ball indentation (ABI), it is necessary to carry out prior detailed ABI studies on the virgin material. In this investigation, the tensile behaviour of as-received 316LN SS were investigated at several temperatures in the range 298–973 K using ABI technique. The load-depth of indentation data measured from ABI tests was analyzed using semi-empirical relationships to obtain the tensile properties. The yield stress and the flow curves were determined by correlating ABI results with corresponding uniaxial tensile test results. Trend curve for tensile strength with temperature, as estimated from ABI tests, exhibited a plateau region in the temperature around 823 K, similar to uniaxial tensile tests. The variations of strength coefficient, strain hardening exponent, yield ratio, hardness and uniform ductility with temperature were evaluated from ABI tests. The ABI technique was found to estimate the influence of temperature on tensile properties sensitively.     

Numerical study of double-diffusive, free convective flow past a moving vertical cylinder

The double-diffusive, free convective flow past a moving semi-infinite vertical cylinder has been studied numerically. The mass, momentum, energy, and species concentration equations have been solved by a finite-difference method using an implicit scheme of Crank-Nicolson type. The finite-difference scheme is unconditionally stable and accurate. Graphical results for the velocity, temperature, concentration, local and average skin friction, and Nusselt and Sherwood numbers are illustrated and discussed for various physical parametric values. The role of temperature stratification in the ambient medium has been analyzed. Published in Inzhenerno-Fizicheskii Zhurnal, Vol. 79, No. 1, pp. 72–76, January–February, 2006.