Nanoparticle‐Enhanced Silver‐Nanowire Plasmonic Electrodes for High‐Performance Organic Optoelectronic Devices

Improved performance in plasmonic organic solar cells (OSCs) and organic light‐emitting diodes (OLEDs) via strong plasmon‐coupling effects generated by aligned silver nanowire (AgNW) transparent electrodes decorated with core–shell silver–silica nanoparticles (Ag@SiO₂NPs) is demonstrated. NP‐enhanced plasmonic AgNW (Ag@SiO₂NP–AgNW) electrodes enable substantially enhanced radiative emission and light absorption efficiency due to strong hybridized plasmon coupling between localized surface plasmons (LSPs) and propagating surface plasmon polaritons (SPPs) modes, which leads to improved device performance in organic optoelectronic devices (OODs). The discrete dipole approximation (DDA) calculation of the electric field verifies a strongly enhanced plasmon‐coupling effect caused by decorating core–shell Ag@SiO₂NPs onto the AgNWs. Notably, an electroluminescence efficiency of 25.33 cd A^?1 (at 3.2 V) and a power efficiency of 25.14 lm W^?1 (3.0 V) in OLEDs, as well as a power conversion efficiency (PCE) value of 9.19% in OSCs are achieved using hybrid Ag@SiO₂NP–AgNW films. These are the highest values reported to date for optoelectronic devices based on AgNW electrodes. This work provides a new design platform to fabricate high‐performance OODs, which can be further explored in various plasmonic and optoelectronic devices.     

Overcoming the Trade-Off between Optical Transmittance and Areal Capacitance of Transparent Supercapacitors for Practical Application

It is substantially challenging for transition metal oxide nanoparticle (NP)-based electrodes for supercapacitors to achieve high transparency and large capacity simultaneously due to the inherent trade-off between optical transmittance (T) and areal capacitance (C_A). This study demonstrates how this trade-off limitation can be overcome by replacing some electrode NPs with transparent tin oxide (SnO₂) NPs. Although SnO₂ NPs are non-capacitive, they provide effective paths for charge transport, which simultaneously increase the C_A and T_550nm of the manganese oxide (Mn₃O₄) NP electrode from 11.7 to 13.4 mF cm⁻² and 82.1% to 87.4%, respectively, when 25 wt% of Mn₃O₄ are replaced by SnO₂. The obtained C_A values at a given T are higher than those of the transparent electrodes previously reported. An energy storage window fabricated using the mixed-NP electrodes exhibits the highest energy density among transparent supercapacitors previously reported. The improved energy density enables the window to operate various electronic devices for a considerable amount of time, demonstrating its applicability in constructing a reliable and space-efficient building-integrated power supply system.     

An effective temporal error concealment in H.264 video sequences based on scene change detection-PCA model

This paper proposes a new temporal error concealment algorithm in H.264 video sequences based on scene change detection and PCA model. In order to detect scene change, dynamic threshold and image similarity metric are presented using coding prediction mode and DCT AC energy in H.264 baseline. UPCA (Updated PCA) model is presented by combining the scene change feature with Index transformation-Buffer updating approach. The lost images are concealed by Projection onto Convex Sets algorithm with UPCA model. Experimental results show that the proposed algorithm can achieve better error concealment performance for the higher motion and the frequent scene change, compared with the related method.     

Micromixer as a continuous flow reactor for the synthesis of a pharmaceutical intermediate

A mixing device composed of a micron scale flow channel was applied as a continuous reactor to control exothermic reaction heat and to increase the product yield, in a synthesis of a pharmaceutical intermediate of quinolone antibiotics. The model reaction featured a fast reaction rate, high heat generation, and impurity formation due to a prolonged contact time between reactants and products. Using the micromixer reactor, the reaction heat was efficiently removed so that virtually no impurities were produced during the reaction. A product yield comparable to the theoretical value was achieved in a single micromixer unit. Optimum operating conditions were acquired from a statistical method by using factorial design, which was also verified by a CFD calculation.     

Rational and Facile Construction of 3D Annular Nanostructures with Tunable Layers by Exploiting the Diffraction and Interference of Light

This paper reports a rational and facile approach to fabricating arrays of 3D annular nanostructures with tunable layers by utilizing the diffraction and interference of UV light. Based on discretized Fresnel bright spots and standing waves formed within a photoresist film, the structures with nanoscale features are realized using simple, conventional photolithography. The 3D annular nanostructures are produced in arrays of single‐, double‐, and triple‐layered ring structures with the height of single layer on a 100 nm scale. The structural formation process and features of the nanostructures are analyzed and explained through 3D modeling that integrates the effects of both UV exposure dose and chemical kinetics. The approach to generating 3D annular nanostructures with tunable layers and discrete heights can be adapted for various applications that require the 3D structures fabricated over a large area with high throughput.     

A STUDY OF CARBIDE GROWTH IN MAR-M247 LC ALLOY BY DIRECTIONAL SOLIDIFICATION METHOD

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A study of the dynamic behavior of dispersion-type tubular reactor models

The dynamic behavior of dispersion-type tubular reactors, referred to as finite and truncated models depending on the boundary condition representations at the reactor exit, was investigated through numerical simulations. It was found that the dynamic behavior of the two models can be identical or different depending on how thePéclet number changes.     

High temperature mechanical properities and creep crack initiation of DS CM186LC for nozzle guide vane

The second generation DS alloy, CM186LC is used in the as-cast and double aged condition which has creep-rupture properities equivalent to the first generation single crystal alloys CMSX-2 and CMSX-3. In production, cast vane components have to be subjected to a brazing treatment for joining into pairs. The effect of the brazing treatment and modified brazing treatment (heat treatment) on mechanical properities at high temperature was studied in accordance with microstructure. Brazing treatments gave no effect on tensile properities and creep failure mode of DS CM186LC, although a small decrease in stress-rupture life was observed. Creep failure was related to the solidified microstructure. Creep cracks began at the grain boundary normal to the applied stress, especially at the γ/γ’ eutectic phase on grain boundaries. Most of γ/γ’ eutectics which had solidified at the last stage of casting, had microporosity which became a crack initiation site during creep. MC carbide reaction with the matrix γ was observed in the creep failed specimens.     

Quantitative models on corrosion fatigue crack growth rates in metals: Part II. application of fatigue crack growth rate modeling for nickel-based superalloys at elevated temperatures

Approaches to predict da/dN-àK for environmental situations; including empirical interpolative equations, linear superposition of mechanical fatigue and time-based environmental cracking, and mechanism-based models; are presented. For several material-environment systems, these models were incorporated in fracture mechanics life prediction methods, and successes have been reported in evaluating the corrosion fatigue contribution. Considerable uncertainties are, however, associated with these models. The linear superposition analysis is emphasized; material-environment systems that are severely environment-sensitive should be adequately described by this method. Direct and indirect methods exist to define time-based crack growth rates for use in linear superposition predictions of da/dN. The linear superposition approach is effective, but only for those cases where K_ISCC is high relative to typical flawed component stress intensity levels. Empirical curve-fit models require an extensive environmental crack growth rate data base, which are costly to develop, and are effective for interpolations but not predictions of fatigue crack growth data. Mechanism-based models for broad predictions of cycle-time dependent da/dN versus àK, and other variables such as frequency or hold time, are in an infant state.     

The effect of crystalline morphology of poly (butylene terephthalate) phases on toughening of poly(butylene terephthalate)/epoxy blends

In an effort to investigate the effect of the crystalline morphology of a poly(butylene terephthalate) (PBT) phase on the toughening of PBT/epoxy blends, the blends, having different degrees of perfectness of the PBT crystalline phase, were prepared by blending PBT and epoxy at various temperatures ranging from 200 to 240 °C. As the blending temperature decreases, the degree of perfectness of the PBT crystalline phase increases as a result of the increase of crystal growth rate. For PBT/epoxy blends, the change in crystalline morphology induced by processing may be the most important cause for the dependency of the fracture energy on blending temperatures. It has been found that PBT phases with a well-developed Maltese cross are most effective for epoxy toughening. This dependency reveals the occurrence of a phase transformation toughening mechanism. Also, the higher relative enhancement of fracture energy of a higher molecular weight epoxy system is further indirect evidence for a phase transformation toughening mechanism. Some other toughening mechanisms observed from the fracture surfaces, such as crack bifurcation, crack bridging, and ductile fracture of PBT phases, have been found to also be affected by the blending temperatures.